中国科学技术大学材料科学与工程系朱彦武

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朱彦武，中国科学技术大学教授，博导。生于1978年，中国科学技术大学化学与材料科学学院材料科学与工程系教授，博士生导师，教育部“新世纪优秀人才支持计划”，获2011年度Scopus“青年科学之星”奖（材料类第五）。2000年在国防科技大学理学院取得应用物理学士学位，2003年在北京大学物理学院取得凝聚态物理硕士学位，2007年在新加坡国立大学物理系取得物理学博士学位，期间获新加坡国立大学校长奖学金和中国教育部优秀自费留学生奖。自2006年8月起在新加坡国立大学纳米科学启动项目任博士后研究员，2008年5月起在美国德克萨斯大学奥斯丁分校Ruoff课题组进行博士后研究。自2000年以来开始从事纳米材料的制备、表征和性质研究等工作， 在Science 、Advanced Materials、Nano Letters等期刊发表论文超过80篇，共被引用6000余次，单篇最高引用超过1100次，H因子为33。



姓 名：朱彦武 教授 博导
电 话： 0551－63607670
电子邮件：zhuyanwu@ustc.edu.cn
　
个人简历　
2011年8月至今：教授，博导，中国科学技术大学
2008年5月－2011年7月：博士后，美国德州大学奥斯丁分校
2006年8月－2008年5月：研究员，新加坡国立大学
2003年8月－2006年8月：博士，新加坡国立大学物理系
2000年9月－2003年7月：硕士，北京大学物理学院
1996年9月－2000年7月：学士，国防科技大学物理系

主要研究方向
• 石墨烯及其他新型碳材料的制备和表征• 纳米材料的光电转换特性
• 高性能能量转换和存储器件研究

文章及专著
http://www.researcherid.com/rid/

2019

Ni K., Wang X., Tao Z., Yang J., Shu N., Ye J., Pan F., Xie J., Tan Z., Sun X., Liu J., Qi Z., Chen Y., Wu X., Zhu Y.* In-operando Probing Lithium Ion Storage on Single Layer Graphene.[J]. Advanced Materials 1808091. 2019

2018

J. Ye, K. Ni, J. Liu, G. Chen, M. Ikram, Y. Zhu,* Oxygen‐Rich Carbon Quantum Dots as Catalysts for Selective Oxidation of Amines and Alcohols. ChemCatChem 2018

T. Cheng, J. Xu, Z. Tan, J. Ye, Z. Tao, Z. Du, Y. Wu, S. Wu, H. Ji, Y. Yu, Y. Zhu,* A spray-freezing approach to reduced graphene oxide/MoS2 hybrids for superior energy storage. Energy Storage Materials 10, 282-290. 2018

J. Ye, H. Tan, S. Wu, K. Ni, F. Pan, J. Liu, Z. Tao, Y. Qu, H. Ji, P. Simon, Y. Zhu,* Direct Laser Writing of Graphene Made from Chemical Vapor Deposition for Flexible, Integratable Micro‐Supercapacitors with Ultrahigh Power Output[J]. Advanced Materials 1801384. 2018

D. Liu, K. Ni, J. Ye, J. Xie,Y. Zhu,*Li Song,* Tailoring the Structure of Carbon Nanomaterials toward High-End Energy Applications. Advanced Materials 1802104. 2018

X. Wang, Z. Yan, Z. Tao, Z. Tan, J. Ye, F. Pan, H. Xu, Y. Zhang, S. Deng, Y. Zhu,* Field emission characteristics of basal plane and cross-sectional edges of graphite made from graphite oxide. Mater.Chem.Phys 60-64, 2018

F. Pan, S. Cheng, Y. Li, Z. Tao, J. Ye, K. Ni, H. Yu, B. Xiang, Y. Ren, F. Qin, S. Yu, Y. Zhu,* 3D Graphene Films Enable Simutaneously High Sensitivity and Large Stretchability for Strain Sensors[J]. Advanced Functional Materials 1803221, 2018.

X. Sun, J. Ye, F. Pan et al, Y. Zhu,* Hierarchical Porous Carbon Obtained from Frozen Tofu for Efficient Energy Storage[J]. New J. Chemistry 42, 12421, 2018.

J. Liu, J. Ye, F. Pan et al. Y. Zhu,* Solid-state yet flexible supercapacitors made by inkjet-printing hybrid ink of carbon quantum dots/graphene oxide platelets on paper[J]. Science China Materials 1-10, 2018.

J. Xie, J. Ye, F. Pan et al. Y. Zhu* Incorporating Flexibility into Stiffness: Self-Grown Carbon Nanotubes in Melamine Sponges Enable A Lithium-Metal-Anode Capacity of 15 mA h cm−2 Cyclable at 15 mA cm−2[J]. Advanced Materials 1-7, 2018.

Y. Du, J. Xiang, K. Ni, G. Su et al.Y. Zhu*, M. Zhu* Design of atomically precise Au2Pd6 nanoclusters for boosting electrocatalytic hydrogen evolution on MoS2[J]. INORGANIC CHEMISTRY 1-7, 2018.

Z. Sun, S. Jin, H. Jin, Z. Du, Y. Zhu, A. Cao, L. Wan. H. Ji* Robust Expandable Carbon Nanotube Scaffold for Ultrahigh-Capacity Lithium-Metal Anodes[J]. Advanced Materials 1-7, 2018.

Y. Du, K. Ni,Q. Zhai, Y. Zhu et al. M. Zhu* Facile air oxidative induced dealloying of hierarchical branched PtCu nanodendrites with enhanced activity for hydrogen evolution[J]. Applied Catalysis A, General 1-7, 2018.

Xiong Liu, Kun Ni, Bo Wen, Jiashen Meng, Ruiting Guo, Qi Li, Jiantao Li, Yanwu Zhu, Dongyuan Zhao.Chaojiang Niu,* Xiaojun Wu,* Liqiang Mai* Polyoxomolybdate-derived carbon-encapsulated multicomponent electrocatalysts for synergistically boosting hydrogen evolution[J]. Journal of Materials Chemistry A 1-8, 2018.

Guangsheng Fu, Jianglin Ye, JunJian Han, Jiaqi Wang, Lei Zhai. Qiang Li,*Y. Zhu* Hierarchical porous carbon with high nitrogen content derived from plant waste (pomelo peel) for supercapacitor[J]. Journal of Materials Science 1-7, 2018.

Zhuchen Tao1, Wei Chen, Jing Yang, Xiangyang Wang, Ziqi Tan, Jianglin Ye. Yanxia Chen,* Y. Zhu* Ultrathin yet transferrable Pt- or PtRu-decorated graphene films as efficient electrocatalyst for methanol oxidation reaction[J]. SCIENCE CHINA Materials 1-10, 2018.

Junjian Han,Jiaqi Wang, Jianglin Ye, Guangsheng Fu, Lei Zhai, Yanwu Zhu. Qiang Li* Heteroatoms (O, N)-doped porous carbon derived from bamboo shoots shells for high performance supercapacitors[J]. Journal of Materials Science 1-11, 2018.

2017

S. Wu, Y. Zhu,* Highly Densified Carbon Electrode Materials towards Practical Supercapacitor Devices. Science China-Materials 60, 25, 2017.

J. Ye, S. Wu, K. Ni, Z. Tan, J. Xu, Z. Tao, Y. Zhu,* Diameter‐Sensitive Breakdown of Single‐Walled Carbon Nanotubes upon KOH Activation. ChemPhysChem 18(14), 1929-1936, 2017.

S. Jin, Z Sun, Y. Guo, Z. Qi, C. Guo, X. Kong, Y. Zhu*, H. Ji,* High Areal Capacity and Lithium Utilization in Anodes Made of Covalently Connected Graphite Microtubes. Advanced Materials 29(38), 2017.

Y. Zhu*, H. Ji*, C. Cheng*, Rodney. Ruoff*, Mass production and industrial applications of graphene materials. National Science Review 2017.

T. Cheng, X. Wang, X. Wang, Y. Zhu,* Light weight and highly stable graphite paper as anode current collectors for lithium ion batteries. Journal of USTC 2017.

J. Ye, Y. Zhu,*Porous Carbon Materials Produced by KOH Activation for Supercapacitor Electrodes. Journal of ElectroChemistry 2017.

Z. Du, J. Xu, S. Jin, Y. Shi, C. Guo, X. Kong, Y. Zhu,* H. Ji,*The correlation between carbon structures and electrochemical properties of sulfur/carbon composites for Li-S batteries. Journal of Power Sources 2017.

G. Li, Q. Li, J. Ye, G. Fu, J. Han Y. Zhu,* Activated carbon from the waste water purifier for supercapacitor application. J Solid State Electrochem 2017.

Z. Tan, H. Xu, B. Zhou, Z. Qi, Y. Qu Y. Zhu,* Planar lighting from optimized graphite papers made of graphite oxide. APPLIED PHYSICS LETTERS 2017.

2016

Z. Tan, K. Ni, G. Chen, W. Zeng, Z. Tao, M. Ikram, Q. Zhang, H. Wang, L. Sun, X. Zhu, X. Wu, H. Ji, R. S. Ruoff,* Y. Zhu,* Incorporating Pyrrolic and Pyridinic Nitrogen into a Porous Carbon made from C60 Molecules to Obtain Superior Energy Storage. Advanced materials 2016.

H. Elim, Y. Zhu, C. Sow,* Length Dependence of Ultrafast Optical Nonlinearities in Vertically Aligned Multiwalled Carbon Nanotube Films. Journal of Physical Chemistry C 120, 17733, 2016.

J. Xu, Z. Tan, W. Zeng, G. Chen, S. Wu, Y. Zhao, K. Ni, Z. Tao, M. Ikram, H. Ji, Y. Zhu,* A Hierarchical Carbon Derived from Sponge-Templated Activation of Graphene Oxide for High-Performance Supercapacitor Electrodes. Advanced materials 28, 5222, 2016.

X. Zhu, L. Zuo, S. Wu, X. Qu, M, Wei, L. He, Y. Zhong, Y. Zhu,* Porous Three-Dimensional Activated Microwave Exfoliated Graphite Oxide as an Anode Material for Lithium Ion Batteries. Rsc Advances 6, 55176, 2016.

S. Wu, G. Chen, N. Kim, K. Ni, W. Zeng, Y. Zhao, Z. Tao, H. Ji, Z. Lee, Y. Zhu,* Creating Pores on Graphene Platelets by Low-Temperature KOH Activation for Enhanced Electrochemical Performance. Small 12, 2376, 2016.

W. Zeng, Y. Zhao, K. Ni, Y. Zhu,* Fast Pseudocapacitive Reactions of Three-Dimensional Manganese Dioxide Structures Synthesized via Self-Limited Redox Deposition on Microwave-Expanded Graphite Oxide. Rsc Advances 6, 8339, 2016.

L. Hui, J. Huang, G. Chen, Y. Zhu, L. Yang,* Antibacterial Property of Graphene Quantum Dots (Both Source Material and Bacterial Shape Matter). Acs Applied Materials & Interfaces 8, 20, 2016.

G. Chen, S. Wu, L. Hui, Y. Zhao, J. Ye, Z. Tan, W. Zeng, Z. Tao, L. Yang, Y. Zhu,* Assembling Carbon Quantum Dots to a Layered Carbon for High-Density Supercapacitor Electrodes. Scientific reports 6, 19028, 2016.

2015

G. Chen, Z. Zhuo, K. Ni, N. Kim, Y. Zhao, Z. Chen, B. Xiang, L. Yang, Q. Zhang, Z. Lee, X. Wu, R.S. Ruoff, Y. Zhu,* Rupturing C-60 Molecules into Graphene-Oxide-like Quantum Dots: Structure, Photoluminescence, and Catalytic Application. Small 11, 5296, 2015.

Y. Yao, W. Chen, Y. Du, Z. Tao, Y. Zhu, Y. Chen,* An Electrochemical in Situ Infrared Spectroscopic Study of Graphene/Electrolyte Interface under Attenuated Total Reflection Configuration. Journal of Physical Chemistry C 119, 22452, 2015.

X. Zhao, Y. Du, L. Jin, Y. Yang, S. Wu, W. Li, Y. Yu, Y. Zhu,* Q. Zhang,* Membranes of MnO Beading in Carbon Nanofibers as Flexible Anodes for High-Performance Lithium-Ion Batteries. Scientific reports 5, 14146, 2015.

Y. Du, Z. Tao, J. Guan, Z. Sun, W. Zeng, P. Wen, K. Ni, J. Ye, S. Yang, P. Du, Y. Zhu,* Microwave-Assisted Synthesis of Hematite/Activated Graphene Composites with Superior Performance for Photocatalytic Reduction of Cr(VI). Rsc Advances 5, 81438, 2015.

J. Ji, J. Liu, L. Lai, X. Zhao, Y. Zhen, J. Lin, Y. Zhu, H. Ji, L. Zhang,* R.S. Ruoff, In Situ Activation of Nitrogen-Doped Graphene Anchored on Graphite Foam for a High-Capacity Anode. Acs Nano 9, 8609, 2015.

Y. Zhao, Y. Zhu,* Graphene-Based Hybrid Films for Plasmonic Sensing. Nanoscale 7, 14561, 2015.

P. Zong, X. Chen, Y. Zhu, Z. Liu, Y. Zeng, L. Chen,* Construction of a 3D-RGO Network-Wrapping Architecture in a YbyCo4Sb12/RGO Composite for Enhancing the Thermoelectric Performance. Journal of Materials Chemistry A 3, 8643, 2015.

L. Zeng, W. Zeng, Y. Jiang, X. Wei, W. Li, C. Yang, Y. Zhu,* Y. Yu,* A Flexible Porous Carbon Nanofibers-Selenium Cathode with Superior Electrochemical Performance for Both Li-Se and Na-Se Batteries. Advanced Energy Materials 5, 1401377, 2015.

Y. You, W. Zeng, Y. Yin, J. Zhang, C. Yang, Y. Zhu,* Y. Guo,* Hierarchically Micro/Mesoporous Activated Graphene with a Large Surface Area for High Sulfur Loading in Li-S Batteries. Journal of Materials Chemistry A 3, 4799, 2015.

Z. Tan, G. Chen, Y. Zhu,* Carbon-Based Supercapacitors Produced by the Activation of Graphene. Nanocarbons for Advanced Energy Storage 1, 211, 2015.

Y. Zhao, W. Zeng, Z. Tao, P. Xiong, Y. Qu, Y. Zhu,* Highly Sensitive Surface-Enhanced Raman Scattering Based on Multi-Dimensional Plasmonic Coupling in Au-Graphene-Ag Hybrids. Chem Commun 51, 866, 2015.

L. Chen, Z. Yu, J. Wang, Q. Li, Z. Tan, Y. Zhu, S. Yu,* Metal-like Fluorine-Doped Beta-FeOOH Nanorods Grown on Carbon Cloth for Scalable High-Performance Supercapacitors. Nano Energy 11, 119, 2015.

2014

X. Zhu, Z. Yan, W. Wu, W. Zeng, Y. Du, Y. Zhong, H. Zhai, H. Ji, Y. Zhu,* Manipulating size of Li3V2(PO4)3 with Reduced Graphene Oxide: Towards High-performance Composite Cathode for Lithium Ion Batteries. Scientific reports 4, 5768, 2014.

X. Zhu, J. Hu, W. Wu, W. Zeng, H. Dai, Y. Du, Z. Liu, L. Li, H. Ji*, Y. Zhu,* LiFePO4/reduced Graphene Oxide Hybrid Cathode for Lithium Ion Battery with Outstanding Rate Performance. Journal of Materials Chemistry A 2, 7812, 2014.

Y. Zhao, X. Li, Y. Du, G. Chen, Y. Qu, J. Jiang, Y. Zhu,* Strong Light-matter Interactions in Sub-nanometer Gaps Defined by Monolayer Graphene: Toward Highly Sensitive SERS Substrates. Nanoscale 6, 11112, 2014.

Y. Zhao, G. X. Chen, Z. Tao, C. Zhang, Y. Zhu,* High Q-factor Plasmonic Resonators in Continuous Graphene Excited by Insulator-covered Silicon Gratings. Rsc Advances 4, 26535, 2014.

Y. Zhao, G. Chen, Y. Du, J. Xu, S. Wu, Y. Qu, Y. Zhu,* Plasmonic-Enhanced Raman Scattering of Graphene on Growth Substrates and Its Application in SERS. Nanoscale 6, 13754, 2014.

Y. Zhang, J. Mark, Y. Zhu, R. Ruoff, D. Schaefer,* Mechanical Properties of Polybutadiene Reinforced with Octadecylamine Modified Graphene Oxide. Polymer 55, 5389, 2014.

H. Ji, X. Zhao, Z. Qiao, J. Jung, Y. Zhu, Y. Lu, L. Zhang, A. MacDonald, R. Ruoff,* Capacitance of Carbon-Based Electrical Double-Layer Capacitors. Nature communications 5, 3317, 2014.

L. Hui, J. Piao, J. Auletta, K. Hu, Y. Zhu, T. Meyer, H. Liu,* L. Yang,* Availability of the Basal Planes of Graphene Oxide Determines Whether It Is Antibacterial. ACS applied materials & interfaces 6, 13183,2014.

Y. Du, Y. Zhao, Y. Qu, C. Chen, C. Chen, C. Chuang, Y. Zhu,* Enhanced Light-matter Interaction of Graphene-gold Nanoparticle Hybrid Films for High-performance SERS Detection. Journal of Materials Chemistry C 2, 4683, 2014.

2013

Y. Zhao, X. Hu, G. Chen, X. Zhang, Z. Tan, J. Chen, R. Ruoff, Y. Zhu,* Y. Lu,* Infrared Biosensors Based on Graphene Plasmonics: Modeling. Physical chemistry chemical physics : PCCP 15, 17118, 2013.

Y. Zhang, Y. Zhu, G. Lin, R. Ruoff, N. Hu, D. Schaefer,* J. Mark,* What Factors Control the Mechanical Properties of Poly (dimethylsiloxane) Reinforced with Nanosheets of 3-aminopropyltriethoxysilane Modified Graphene Oxide? Polymer 54, 3605, 2013.

B. Ni, F. Li, X. Li, Z. Fu,* Y. Zhu, Y. Lu,* Ethanol Assisted Synthesis of Anatase Nanobelts with Improved Cystallinity and Photocatalytic Activity. Applied Surface Science 283, 175, 2013.

S. Murali, N. Quarles, L. Zhang, J. Potts, Z. Tan, Y. Lu, Y. Zhu,* R. Ruoff,* Volumetric Capacitance of Compressed Activated Microwave-expanded Graphite Oxide (a-MEGO) Electrodes. Nano Energy 2, 764, 2013.

2012

X. Zhao, L. Zhang, S. Murali, M. Stoller, Q. Zhang, Y. Zhu,* R. Ruoff,* Incorporation of Manganese Dioxide within Ultraporous Activated Graphene for High-performance Electrochemical Capacitors. ACS Nano 6, 5404, 2012.

Y. Zhang, Y. Zhu, R. Ruoff, J. Mark,* Mechanical Properties of Poly (butadiene) (PBD) Reinforced with Nanosheets of Octadecylamine Modified Graphene Oxide (OMGO). Abstracts Papers of the American Chemical Society 244, 2012.

L. Zhang, X. Zhao, M. Stoller, Y. Zhu, H. Ji, S. Murali, Y. Wu, S. Perales, B. Clevenger, R. Ruoff,* Highly Conductive and Porous Activated Rduced Graphene Oxide Films for High-power Supercapacitors. Nano letters 12, 1806, 2012.

M. Stoller, S. Murali, N. Quarles, Y. Zhu, J. Potts, X. Zhu, H. Ha, R. Ruoff,* Activated Graphene as a Cathode Material for Li-ion Hybrid Supercapacitors. Physical chemistry chemical physics : PCCP 14, 3388, 2012.

S. Murali, J. Potts, S. Stoller, J. Park, M. Stoner, L. Zhang, Y. Zhu, R. Ruoff,* Preparation of Activated Graphene and Effect of Activation Parameters on Electrochemical Capacitance. Carbon 50, 3482, 2012.

X. Lim, Y. Zhu, B. Varghese, X. Gao, A. Wee, C. Sow,* Re-grown Aligned Carbon Nanotubes with Improved Field Emission. Journal of Nanoscience and Nanotechnology 12, 258, 2012.

2011

H. Ji, Y. Hao, Y. Ren, M. Charlton, W. Lee, Q. Wu, H. Li, Y. Zhu, Y. Wu, R. Piner, R. Ruoff,* Graphene Growth Using a Solid Carbon Feedstock and Hydrogen. ACS Nano5, 7656, 2011.

D. Dreyer, S. Murali, Y. Zhu, R. Ruoff, C. Bielawski,* Reduction of Graphite Oxide Using Alcohols. Journal of Materials Chemistry 21, 3443, 2011.

X. Zhu, Y. Zhu, S. Murali, M. Stoller, R. Ruoff,* Nanostructured Reduced Graphene Oxide/Fe2O3 Composite As a High-Performance Anode Material for Lithium Ion Batteries. ACS Nano 5, 3333, 2011.

X. Zhu, Y. Zhu, S. Murali, M. Stoller, R. Ruoff,* Reduced Graphene Oxide/Tin Oxide Composite as an Enhanced Anode Material for Lithium Ion Batteries Prepared by Homogenous Coprecipitation. Journal of Power Sources 196, 6473, 2011.

Y. Xie, F. Cheong, B. Varghese, Y. Zhu, R. Mahendiran, C. Sow,* Wavelength Sensitive Photo-Sensing from Discrete Crystalline Tungsten Oxide Nanowires. Sensors and Actuators B: Chemical 151, 320, 2011.

Y. Zhang, G. Lin, Y. Zhu, R. Ruoff,* J. Mark, In Mechanical property of poly (dimethylsiloxane)(PDMS) reinforced with nanosheets of modified graphene oxide (MGO), Abstracts of Papers of American Chemical Society 242, 2011.

K. Yu, Z. Bo, G. Lu, S. Mao, S. Cui, Y. Zhu, X. Chen, R. Ruoff, J. Chen,* Growth of Carbon Nanowalls at Atmospheric Pressure for One-Step Gas Sensor Fabrication. Nanoscale research letters 6, 202, 2011.

Y. Zhu, S. Murali, M. Stoller, K. Ganesh, W. Cai, P. Ferreira, A. Pirkle, R. Wallace, K. Cychosz, M. Thommes, D. Su, E. Stach, R. Ruoff,* Carbon-Based Supercapacitors Produced by Activation of Graphene. Science 332, 1537, 2011.

S. Murali, D. Dreyer, P. Valle-Vigón, M. Stoller, Y. Zhu, C. Morales, A. Fuertes, C. Bielawski,* R. Ruoff,* Mesoporous Carbon Capsules as Eectrode Materials in Electrochemical Double Layer Capacitors. Physical Chemistry Chemical Physics 13, 2652, 2011.

J. Potts, S. Murali, Y. Zhu, X. Zhao. R. Ruoff,* Microwave-Exfoliated Graphite Oxide/Polycarbonate Composites. Macromolecules 44, 6488, 2011.

M. Stoller, C. Magnuson, Y. Zhu, S. Murali, J. Suk, R. Piner, R. Ruoff,* Interfacial Capacitance of Single Layer Graphene. Energy & Environmental Science 4, 4685, 2011.

M. Stoller, S. Stoller, N. Quarles, J. Suk, S. Murali, Y. Zhu, X. Zhu, R. Ruoff,* Using Coin Cells for Ultracapacitor Electrode Material Testing. Journal of Applied Electrochemistry 41, 681, 2011.

2010

S. An, Y. Zhu, S. Lee, M. Stoller, T. Emilsson, S. Park, A. Velamakanni, J. An and R. Ruoff,* Thin Film Fabrication and Simultaneous Anodic Reduction of Deposited Graphene Oxide Platelets by Electrophoretic Deposition. The Journal of Physical Chemistry Letters 1, 1259, 2010 .

W. Cai, A. Moore, Y. Zhu, X. Li, S. Chen, L. Shi,* R. Ruoff,* Thermal Transport in Suspended and Supported Monolayer Graphene Grown by Chemical Vapor Deposition. Nano Letters 10, 1645, 2010.

S. Chen, W. Cai,* D. Chen, Y. Ren, X. Li, Y. Zhu, J. Kang, R. Ruoff,* Adsorption/desorption and Electrically Controlled Flipping of Ammonia Molecules on Graphene. New Journal of Physics 12, 125011, 2010.

S. Lee, D. Dreyer, J. An, A. Velamakanni, R. Piner, S. Park, Y. Zhu, S. Kim, C. Bielawski,* R. Ruoff,* Polymer Brushes via Controlled, Surface-Initiated Atom Transfer Radical Polymerization (ATRP) from Graphene Oxide. Macromolecular Rapid Communications 31, 281, 2010.

X. Li, C. Magnuson, A. Venugopal, J. An, J. Suk, B. Han, M. Borysiak, W. Cai, A. Velamakanni, Y. Zhu, L. Fu, E. Vogel, E. Voelkl, L. Colombo,* R. Ruoff,* Graphene Films with Large Domain Size by a Two-Step Chemical Vapor Deposition Process. Nano Letters 10, 4328, 2010.

Z. Lim, A. Lee, K. Lim, Y. Zhu, C. Sow,* Systematic Investigation of Sustained Laser-induced Incandescence in Carbon Nanotubes. Journal of Applied Physics 107, 7, 2010.

A. Velamakanni, C. Magnuson, K. Ganesh, Y. Zhu, J. An, P. Ferreira, R. Ruoff,* Site-Specific Deposition of Au Nanoparticles in CNT Films by Chemical Bonding. ACS Nano 4, 540, 2010.

Y. Zhang, G. Lin, Y. Zhu, R. Ruoff,* J. Mark, In Nanocomposites of Poly (dimethylsiloxane) and modified graphene oxide platelets, Abstracts of Papers of American Chemical Society, 239, 2010.

Y. Zhu, S. Murali, W. Cai, X. Li, J. W. Suk, J. R. Potts, R. Ruoff,* Graphene and Graphene Oxide: Synthesis, Properties, and Applications. Advanced Materials 22, 3906, 2010.

Y. Zhu, S. Murali, M. Stoller, A. Velamakanni, R. Piner, R. Ruoff,* Microwave Assisted Exfoliation and Reduction of Graphite Oxide for Ultracapacitors. Carbon 48, 2118, 2010.

Y. Zhu, M. Stoller, W. Cai, A. Velamakanni, R. Piner, D. Chen, R. Ruoff,* Exfoliation of Graphite Oxide in Propylene Carbonate and Thermal Reduction of the Resulting Graphene Oxide Platelets. ACS Nano 4, 1227, 2010.

Y. Zhu, Y. Zhang, L. Dai, F. Cheong, V. Tan, C. Sow,* C. Lim, Mechanical Characterization of Hotplate Synthesized Vanadium Oxide Nanobelts. Acta Materialia 58, 415, 2010.

Y. Ren, S. Chen, W. Cai,* Y. Zhu, C. Zhu. R. Ruoff,* Controlling the Electrical Transport Properties of Graphene by in Situ Metal Deposition. Applied Physics Letters 97, 053107, 2010.

G. Srinivas,* Y. Zhu, R. Piner, N. Skipper, M. Ellerby, R. Ruoff, Synthesis of Graphene-Like Nanosheets and Their Hydrogen Adsorption Capacity. Carbon 48, 630, 2010.

2009

X. Li, Y. Zhu, W. Cai, M. Borysiak, B. Han, D. Chen, R. Piner, L. Colombo,* R. Ruoff,* Transfer of Large-Area Graphene Films for High-Performance Transparent Conductive Electrodes. Nano Letters 9, 4359, 2009.

W. Cai, Y. Zhu, X. Li, R. Piner, R. Ruoff,* Large Area Few-layer Graphene/graphite Films as Transparent Thin Conducting Electrodes. Applied Physics Letters 95, 123115, 2009.

I. Jung, D. Field, N. Clark, Y. Zhu, D. Yang, R. Piner, S. Stankovich, D. Dikin, H. Geisler, C. Ventrice,* R. Ruoff,* Reduction Kinetics of Graphene Oxide Determined by Electrical Transport Measurements and Temperature Programmed Desorption. Journal of Physical Chemistry C 113, 18480, 2009.

W. Cai,* R. Piner, Y. Zhu, X. Li, Z. Tan, H. Floresca, C. Yang, L. Lu, M. Kim, R. Ruoff,* Synthesis of Isotopically-labeled Graphite Films by Cold-wall Chemical Vapor Deposition and Electronic Properties of Graphene Obtained from Such Films. Nano Research 2, 851, 2009.

Y. Zhu, W. Cai, R. Piner, A. Velamakanni, R. Ruoff,* Transparent Self-assembled Films of Reduced Graphene Oxide Platelets. Applied Physics Letters 95, 103104, 2009.

Y. Xie, F. Cheong, Y. Zhu, B. Varghese, R. Tamang, A. Bettiol, C. Sow,* Rainbow-like MoO3 Nanobelts Fashioned via AFM Micromachining. The Journal of Physical Chemistry C 114, 120, 2009.

Y. Zhu, E. Tan, C. Sow,* C. T. Lim, Synthesis of Nanowires. Materials Science Foundations (monograph series) 54, 271, 2009.

Z. Lim, A. Lee, Y. Zhu, K. Lim, C. Sow,* Sustained Laser Induced Incandescence in Carbon Nanotubes for Rapid Localized Heating. Applied Physics Letters 94, 073106, 2009.

A. Velamakanni, K. Ganesh, Y. Zhu, P. Ferreira, R. Ruoff,* Catalyst‐Free Synthesis and Characterization of Metastable Boron Carbide Nanowires. Advanced Functional Materials 19, 3926, 2009.

2008

F. Fan,* S. Park, Y. Zhu, R. Ruoff, A. Bard,* Electrogenerated Chemiluminescence of Partially Oxidized Highly Oriented Pyrolytic Graphite Surfaces and of Graphene Oxide Nanoparticles. Journal of the American Chemical Society 131,937, 2008.

X. Lim, Y. Zhu, F. Cheong, N. Hanafiah, S. Valiyaveettil, C. Sow,* Multicolored Carbon Nanotubes: Decorating Patterned Carbon Nanotube Microstructures with Quantum Dots. ACS Nano 2, 1389, 2008.

Y. Zhu, X. Lim, M. C. Sim, C. T. Lim, C. Sow,* Versatile Transfer of Aligned Carbon Nanotubes with Polydimethylsiloxane as the Intermediate. Nanotechnology 19, 325304, 2008.

Y. Zhu, Y. Zhang, F. Cheong, C. Sow,* C. Lim, Annealing Effects on the Elastic Modulus of Tungsten Oxide Nanowires. Journal of Materials Research 23, 2149, 2008.

D. K. Ng, M. Hong,* L. Tan, Y. Zhu, C. Sow, PLD Synthesis of GaN Nanowires and Nanodots on Patterned Catalyst Surface for Field Emission Study. Applied Physics A: Materials Science & Processing 93, 685, 2008.

H. Pan,* C. Poh, Y. Zhu, G. Xing, K. Chin, Y. Feng, J. Lin, C. Sow, W. Ji, A. Wee, Novel CdS Nanostructures: Synthesis and Field Emission. The Journal of Physical Chemistry C 112, 11227, 2008.

C. Teo, Y. Zhu, X. Gao, A. Wee, C. Sow,* Field Emission from Hybrid CuO and CuCO 3 Nanosystems. Solid State Communications 145 , 241, 2008.

M. Stoller, S. Park, Y. Zhu, J. An, R. Ruoff,* Graphene-Based Ultracapacitors. Nano letters 8, 3498, 2008.

B. Varghese, M. Reddy, Y. Zhu, C. Lit, T. Hoong, G. Subba Rao, B. Chowdari, A. Wee, C. Lim, C. Sow,* Fabrication of NiO Nanowall Electrodes for High Performance Lithium Ion Battery. Chemistry of Materials 20, 3360, 2008.

2007

F. Cheong, B. Varghese, Y. Zhu, E. Tan, L. Dai, V. Tan, B. Vincent, C. Lim, C. Sow,* WO3-x Nanorods Synthesized on a Thermal Hot Plate. The Journal of Physical Chemistry C 111, 17193, 2007.

C. Chuang, C. Chen, Y. Chang, C. Peng , S. Wong, S. Tzeng, S. Gwo, Y. Zhu, C. Sow, M. Lin,* Enhanced Chemical Shift of Carbon Nanotube from Laser Assisted Gas Incorporation. Applied Physics Letters 91, 183101,2007.

P. Li, X. Lim, Y. Zhu, T. Yu, C. Ong, Z. Shen, A. Wee, C. Sow,* Tailoring Wettability Change on Aligned and Patterned Carbon Nanotube Films for Selective Assembly. Journal of Physical Chemistry B 111, 1672, 2007.

H. Zhou, S. Chua,* H. Pan, Y. Zhu, T. Osipowicz, W. Liu, K. Zang, Y. Feng, C. Sow, Morphology Controllable ZnO Growth on Facet-Controlled Epitaxial Lateral Overgrown GaN/Sapphire Templates. The Journal of Physical Chemistry C 111, 6405, 2007.

H. Zhou,* S. Chua,* S. Chow, H. Pan, Y. Zhu, Y. Feng, L. Wang, K. Zang, W. Liu, S. Tripathy, Characteristics of Threading Dislocations in ZnO Grown on Facet-Controlled Epitaxial Overgrown GaN Templates. Journal of Physics: Condensed Matter 19, 356203, 2007.

Y. Zhu, C. Sow,* M. Sim, G. Sharma, V. Kripesh, Scanning Localized Arc Discharge Lithography for the Fabrication of Microstructures made of Carbon Nanotubes. Nanotechnology 18, 385304, 2007.

Y. Zhu, C. Sow,* J. Thong, Enhanced Field Emission from CuO Nanowire Arrays by in Situ Laser Irradiation. Journal of Applied Physics 102, 114302, 2007.

Y. Zhu, C. Teo, X. Xu, T. Yu, C. Lim, C. Ong, J. Thong, C. Sow,* In Effects of O2 and Ar Reactive Ion Etching on the Field Emission Properties of Aligned CuO Nanowire Films, Solid State Phenomena, Trans Tech Publ, 121, 793, 2007.

D. Ng, M. Hong,* L. Tan, Y. Zhu, C. Sow, Field Emission Enhancement from Patterned Gallium Nitride Nanowires. Nanotechnology 18, 375707, 2007.

E. Tan, Y. Zhu, T. Yu, L. Dai, C. Sow, V. Tan, C. Lim,* Crystallinity and Surface Effects on Young’s Modulus of CuO Nanowires. Applied Physics Letters 90, 163112, 2007.

B. Varghese, C. Teo, Y. Zhu, M. Reddy, B. Chowdari, A. Wee, V. Tan, C. Lim,* C. Sow, Co3O4 Nanostructures with Different Morphologies and Their Field‐Emission Properties. Advanced Functional Materials 17, 1932, 2007.

T. Yu, C. Sow,* X. Xu, Y. Zhu, C. Lim, J. Thong, Formation of Alpha-Fe2O3 Nanoflakes by Heating Fe in Air. Solid State Phenomena 45, 121, 2007.

2006

S. Lim, J. Lin,* Y. Zhu, C. Sow, W. Ji, Synthesis, Characterizations, and Field Emission Studies of Crystalline Na2V6O16 Nanobelt Paper. Journal of Applied Physics 100, 3, 2006.

P. Li, Y. Qu, X. Xu, Y. Zhu, T. Yu, K. Chin, J. Mi, X. Gao, C. Lim, Z. Shen, A. Wee, W. Ji, C. Sow,* Synthesis of "Cactus" Top-corated Aligned Carbon Nanotubes and their Third-order Nonlinear Optical Properties. Journal of Nanoscience and Nanotechnology 6, 990, 2006.

Q. Zhao, S. Feng, Y. Zhu, X. Xu, X. Zhang, X. Song, J. Xu, L. Chen, D. Yu,* Annealing Effects on the Field Emission Properties of AlN Nanorods. Nanotechnology 17, S351, 2006.

T. Yu, Y. Zhu, X. Xu, K. Yeong, Z. Shen, P. Chen, C. Lim, J. Thong, C. Sow,* Substrate-Friendly Synthesis of Metal Oxide Nanostructures Using a Hotplate. Small 2, 80, 2006.

Y. Zhu, H. I. Elim, Y. L. Foo, T. Yu, Y. Liu, W. Ji, J. Y. Lee, Z. Shen, A. T.-S. Wee, J. T.-L. Thong, C. Sow,*Multiwalled Carbon Nanotubes Beaded with ZnO Nanoparticles for Ultrafast Nonlinear Optical Switching. Advanced Materials 18, 587, 2006.

Y. Zhu, A. Moo, T. Yu, X. Xu, X. Gao, Y. Liu, C. Lim, Z. Shen, C. Ong, A. Wee, J. T.-L. Thong, C. Sow,*Enhanced Field Emission from O2 and CF4 Plasma-treated CuO Nanowires. Chemical physics letters 419, 458, 2006.

Y. Zhu, C. Sow,* T. Yu, Q. Zhao, P. Li, Z. Shen, D. Yu, J. Thong, Co‐synthesis of ZnO–CuO Nanostructures by Directly Heating Brass in Air. Advanced Functional Materials 16, 2415, 2006.

H. Pan, Y. Zhu, H. Sun, Y. Feng, C. Sow,* J. Lin, Electroluminescence and Field Emission of Mg-Doped ZnO Tetrapods. Nanotechnology 17, 5096, 2006.

2005

A. Gohel, K. Chin, Y. Zhu, C. Sow, A. Wee,* Field Emission Properties of N2 and Ar Plasma-treated Multi-wall Carbon Nanotubes. Carbon 43, 2530, 2005.

T. Yu, C. Sow,* A. Gantimahapatruni, F. Cheong, Y. Zhu, K. Chin, X. Xu, C. Lim, Z. Shen, J. Thong, Patterning and Fusion of CuO Nanorods with a Focused Laser Beam. Nanotechnology 16, 1238, 2005.

Q. Zhao, H. Zhang, Y. Zhu, S. Feng, X. Sun, J. Xu, D. Yu,* Morphological Effects on the Field Emission of ZnO Nanorod Arrays. Applied Physics Letters 86, 203115, 2005.

T. Yu, C. Sow,* A. Gantimahapatruni, F. Cheong, Y. Zhu, K. Chin, X. Xu, C. Lim, Z. Shen, J. Thong, Patterning and Fusion of CuO Nanorods with a Focused Laser Beam. Nanotechnology 16, 1238, 2005.

T. Yu, Y. Zhu, X. Xu, Z. Shen, P. Chen, C.Lim, J. Thong, C. Sow,* Controlled Growth and Field-Emission Properties of Cobalt Oxide Nanowalls. Advanced Materials 17, 1595, 2005.

Y. Zhu, F. Cheong, T. Yu, X. Xu, C. Lim, J. Thong, Z. Shen, C. Ong, Y. Liu, A. Wee, C. Sow,* Effects of  CF4 Plasma on the Field Emission Properties of Aligned Multi-wall Carbon Nanotube Films. Carbon 43, 395, 2005.

malingshu

中科大朱彦武Adv. Mater. ：直接激光写入石墨烯用于微柔性超高功率超级电容器

高性能柔性储能器件的研究对于柔性、可穿戴电子器件的发展尤为重要。目前主要依赖于薄膜锂离子电池（LTF）、微电池和微超电容器（MSC）。固态的MSCs可以和其他电子器件组装。传统的超级电容器通常采用石墨烯或者石墨烯衍生物提高器件的性能。MSCs电极的制备方法通常是旋涂、真空镀膜、激光涂敷、喷墨打印、丝网印刷和光刻制作等方法。目前报道的大多数基于石墨烯的薄膜电极都是基于还原的氧化石墨烯（rGO）。然而通过高温、等离子体或还原剂处理的还原过程，不适用于可扩展和集成的应用，而且由于石墨烯之间的范德瓦尔斯相互作用而重新堆积。直接激光写入（DLW）技术提供了一种有效制备MSC的方法。无论柔性基板和刚性基板上，在室温和大面积区域都有很好的应用潜力。

近日，中国科技大学的朱彦武等人，发现高性能的、柔性的微型超级电容器（MSCs），作为集成电子设备的电源非常有潜力。本文采用化学气相沉积（CVD）的方法，结合直接激光写入（DLW），制备多层石墨烯基MSC（MG-MSC）。结合多层CVD石墨烯薄膜的干转移，DLW可以高效地制造大面积的MSC。这种方法具有灵活性、多样的平面几何形状和设计集成的能力。在离子凝胶电解质中，MG-MSC表现出23 mWh cm-3的超高能量密度和1860 W cm-3的功率密度。值得注意的是，在聚（乙烯醇）（PVA）/H2SO4水凝胶电解质中，MG-MSC表现出优异的柔性的交流电振荡性能。在120 Hz时，相角为-76.2°，阻容常数为0.54 ms。在PVA/H2SO4水凝胶电解质中，采用DLW制备的MG-聚苯胺（MG-PANI）混合型MSC，显示优化的电容为3.8 mF cm-2，展示了由MG-MSCs线颤动，MG-PANI MSC和压力/气体传感器组成的集成设备。相关成果以“Direct Laser Writing of Graphene Made from Chemical Vapor Deposition for Flexible, Integratable Micro-Supercapacitors with Ultrahigh Power Output”为题发表在Acta Materialia上。

mianyang

中科大宋礼和朱彦武Adv Mater综述：面向高效能源应用的纳米碳结构调控

推进清洁可再生能源的广泛利用是解决当下能源枯竭和环境恶化问题的有效途径，其中涉及电化学过程的存储与转换装置有着十分重要的地位。纳米碳材料由于其构型丰富（具有sp，sp2以及sp3杂化形式）、导电/导热性能突出、机械性能良好、比表面积大等优势被广泛用作这些装置的电极/催化材料。为了更进一步地提升器件性能，近年来研究人员结合纳米碳材料表面性质易于调控的特点发展了以下几种调控策略：（1）本征缺陷调控以期暴露更多的活性位点；（2）异质原子掺杂以期改变纳米碳材料的局域电子结构；（3）纳米颗粒-碳基底间的强耦合作用以期加快电子转移和防止颗粒团聚；（4）微观结构调控（优化孔结构分布和多维度纳米碳材料复合）以期促进离子迁移和电子转移。

近日，中国科学技术大学宋礼教授课题组和朱彦武教授课题组在Adv. Mater.上发表题为“Tailoring the Structure of Carbon Nanomaterials toward High-End Energy Applications”的综述文章。立足于纳米碳材料在电催化和超级电容器领域的应用，全面总结了基于上述四种调控策略裁剪纳米碳材料结构优化器件装置性能的最新进展，囊括了所涉及的纳米碳材料的合成表征、性能评估和构效关系建立等。针对其在能源应用过程中面临的一些挑战和结构裁剪策略中所存在的一些问题，作者进行了详细的讨论并给出了一些可行的改进方案。最后，作者指出利用目前一些先进的表征手段（例如X-射线精细结构吸收谱、球差校正透射电子显微镜等）精细识别纳米碳材料的结构特征，为后续构建可靠性高的结构模型和实施理论模拟提供更多有效的信息，有助于建立更为清晰的纳米碳材料的构效关系。同时，近年来逐步发展起来的一些动态原位表征方法能够实时监测纳米碳材料在电化学反应过程中发生的结构演变，也成为了理解纳米碳材料构效关系和指导高效能源储存与转换系统理性设计中不可或缺的一环。

该工作得到了国家重点研发计划、973项目、国家自然科学基金等项目的资助，以及合肥物质科学技术中心、国家同步辐射实验室、上海光源和北京同步辐射装置的支持。谨以此文献以给即将到来的中国科学技术大学60周年校庆。

全文链接：https://onlinelibrary.wiley.com/doi/abs/10.1002/adma.201802104

erdingxi

报告题目：新型碳材料制备与界面构建
报  告  人：中国科学技术大学  朱彦武教授
报告时间：2020年1月6日（周一）上午8:30
报告地点：子良A220会议室
邀  请  人：新能源材料与技术研究所 陶新永 教授


报告人简介：
中国科学技术大学材料科学与工程系教授,博士生导师。2000年国防科技大学应用物理系获学士学位；2003年北京大学物理学院获凝聚态物理硕士学位； 2007年新加坡国立大学获物理学博士学位。曾在新加坡国立大学和美国得克萨斯大学奥斯汀分校进行博士后研究。近年来在新型碳材料制备及其能源存储与转换应用展开了较为系统的研究，在Science、Advanced Materials等学术刊物发表论文130余篇，引用28000余次，其中单篇引用最高4000余次。2013年获国家自然科学基金委优秀青年基金资助。获得奖励包括SCOPUS青年科学之星铜奖、国际材联-新加坡材料协会青年科学家奖、亚太经合组织创新、研究与教育科学奖等，入选2014-2019年Elsevier中国材料科学家高被引榜单和2018-2019年科睿唯安高被引科学家（跨学科领域）。


报告摘要：
以石墨烯为代表的新型碳材料引起了巨大关注，实现其规模化制备、精准结构调控和高效应用是碳材料研究领域进一步发展的重要动力。本报告从石墨烯材料的规模化制备技术开始，总结其制备产业化进展和相关工业应用，及其中的关键科学与技术问题。在此基础上，通过低成本、可控的方法将现有纳米碳材料进行组装与重构，得到新型三维碳材料，可具有更多有优异特性，特别是可作为高性能电化学储能电极材料使用。为更加深入理解碳材料在能量存储与转换中的关键作用，本报告也将总结为优化碳材料性能而进行的结构、组份和界面调控相关结果，尤其是利用单层石墨烯作为模型材料构建的“单原子层实验室”最新研究进展。

xiayu

高比表面积碳负极中锂碳相互作用机理与界面原位研究
批准号        51972299       
学科分类        无机非金属能量存储材料 ( E021002 )
项目负责人        朱彦武       
依托单位        中国科学技术大学
资助金额        60.00万元       
项目类别        面上项目       
研究期限        2020 年 01 月 01 日 至2023 年 12 月 31 日