南昌大学化学学院张华

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姓名 张华

性别 男

职称 教授

学位 博士

专业 有机化学

电子邮箱 huazhang@ncu.edu.cn

研究方向 有机合成方法学，金属有机化学

教育工作经历

2016.03～              南昌大学化学学院，特聘教授，学科方向带头人

2013.08～2015.09   日本名古屋大学JSPS博士后（合作导师：Prof. Kenichiro Itami）

2008.09～2013.06   武汉大学，有机化学专业，博士学位（导师：雷爱文教授）

2004.09～2008.06   武汉大学，应用化学专业，学士学位（导师：雷爱文教授）

教学简介

科研简介

课题组的研究方向主要集中为（1）发展新型成键模式和催化体系，构建重要的官能团化有机物质（2）结合计算化学与反应动力学研究手段对新反应的机理进行深入理解（3）将课题组特色的合成方法应用于药物创新或新型有机材料发展。

课题组实验室位于基础实验中心B2栋的614室，欢迎对本课题组研究方向感兴趣的本科生参观考察，加入课题组从事科研工作，报考研究生。联系方式：张华(基础实验中心B2栋6楼电梯对面最左边办公室) huazhang@ncu.edu.cn

每一个学生就像一个原子，期待未来的你的加入，共同构建实验室这个大分子！我们的口号是：Create Something New and Enjoy Life!

科研项目 南昌大学高层次人才科研启动基金与国家自然科学基金。

社会兼职

获奖情况

教育部研究生国家奖学金（2013年）

武汉大学学术创新特等奖（2013年）

代表性论文及专利

论文

(1) H. Zhang, S.Hagihara, K. Itami*, Making Dimethylamino a Transformable Directing Groupby   Nickel-Catalyzed C-–N Borylation, Chem. Eur. J. 2015, 21, 16796.

(2) H. Zhang, S.Hagihara, K. Itami*, Aromatic C-–H Borylation by Nickel Catalysis,Chem.Lett.2015,44, 779.

(3) Y. Tsuchiya*, M. Yoshimura, Y. Sato, K.Kuwata, S. Toh, D. Holbrock-Smith, H. Zhang, P. McCourt, K.Itami, T. Kinoshita, S. Hagihara*, Probing strigolactone receptors in Strigahermonthica with fluorescence, Science 2015, 349, 864.

(4) R. Shi,[1] H. Zhang,[1] L.Lu, P. Gan, Y. Sha, H. Zhang, Q. Liu, M. Beller*, A. Lei*, (E)-α,β-unsaturatedamides from tertiary amines, olefins and CO via Pd/Cu-catalyzed aerobicoxidative N-dealkylation,Chem. Commun. 2015, 51,3247. ([1]：共同第一作者)

(5) K. Ozaki, H. Zhang,H. Ito, A. Lei*, K. Itami*, One-shot indole-to-carbazole π-extension by a Pd-–Cu-–Agtrimetallic system, Chem. Sci. 2013, 4, 3416.

(6) R. Shi, L. Lu, H. Zhang,B. Chen, Y. Sha, C. Liu, A. Lei*, Palladium/Copper-catalyzed oxidative C-–Halkenylation/N-dealkylative carbonylation of tertiary anilines, Angew.Chem. Int. Ed. 2013, 52, 10776.

(7) H. Zhang, R. Shi, A.Ding, L. Lu, B. Chen, A. Lei*, Transition-metal-free alkoxycarbonylation ofaryl halides, Angew. Chem. Int. Ed. 2012, 51, 12542.

(8)H. Zhang, R.Shi, P. Gan, C. Liu, A. Ding, Q. Wang, A. Lei*, Palladium-Catalyzed OxidativeDouble C–H Functionalization/Carbonylation towards Xanthone Syntheses, Angew.Chem. Int. Ed. 2012, 51,5204.

(9) H. Zhang, D.Liu, C. Chen, C. Liu, A. Lei*, Palladium-Catalyzed Regioselective AerobicOxidative C–H/N–H Carbonylation of Heteroarenes under Base-Free Conditions, Chem.Eur. J. 2011, 17, 9581.

(10) C. Liu, H. Zhang, W.Shi, A. Lei*, Bond Formations between Two Nucleophiles: Transition MetalCatalyzed Oxidative Cross-Coupling Reactions, Chem. Rev. 2011, 111,1780.

(11) Q. Liu, H. Zhang, A.Lei*, Oxidative Carbonylation Reactions: Organometallic Compounds (R–M) orHydrocarbons (R–H) as Nucleophiles Angew. Chem. Int. Ed. 2011, 50,10788.

(12) W. Liu, H. Cao, H.Zhang, H. Zhang, K. Chung, C. He, H. Wang, F.Kwong*, A. Lei*, Organocatalysis in Cross-Coupling: DMEDA-Catalyzed DirectC–H Arylation of Unactivated Benzene,J. Am. Chem. Soc. 2010, 132,16737.

(13) L. Jin, H. Zhang, P.Li, J. Sowa*, A. Lei*, What is the Rate of the Csp(2)-Csp(2)Reductive Elimination Step? Revealing an Unusually Fast Ni-CatalyzedNegishi-Type Oxidative Coupling Reaction, J. Am. Chem. Soc. 2009, 131,9892.

(14) J. Liu, H. Wang, H.Zhang, X. Wu, H. Zhang, Y. Deng, Z. Yang*, A.Lei*, Identification of a Highly Efficient Alkylated PincerThioimido-Palladium(II) Complex as the Active Catalyst in Negishi Coupling,Chem.Eur. J. 2009, 15, 4437.

(15) J. Liu, Y. Deng, H. Wang, H.Zhang, G. Yu, B. Wu, H. Zhang, Q. Li, T.Marder*, Z. Yang*, A. Lei*, Effective Pd-nanoparticle(PdNP)-catalyzed Negishi coupling involving alkylzinc reagents at roomtemperature, Org. Lett. 2008, 10, 2661.

(16) M. Chen, Y. Weng, M.Guo, H. Zhang, A. Lei*, Nickel-catalyzed reductive cyclizationof unactivated 1,6-enynes in the presence of organozinc reagents, Angew.Chem. Int. Ed. 2008, 47, 2279.

书籍

(1) H. Zhang, BondingIncluding Heteroatoms via Oxidative Coupling. In A. Lei (Eds.), OxidativeCross-Coupling Reactions, Wiley, 2016, In Press.

(2) H. Zhang, C.Liu, A. Lei, C-–H Bond Formation by C-–H Carboxylation or Carbonylation. InJ.-Q. Yu (Eds.), Catalytic Transformations via C--–H Activation (C--–C,C--–N, C--–O, C--–Hal and C--–B Bond Formation), Science of SynthesisReference Library, 2015, In press.

(3) A. Lei, H. Zhang, TransitionMetal-Catalysed Direct Arylation of Unactivated Arenes with Aryl Halides. In X.Ribas (Eds.), C-–H and C-–X Bond Functionalization: Transition MetalMediation, RSC Book, 2013, 310-327.

专利

K. Itami, T. Kinoshita, S. Hagihara, K.Takahashi, M. Yoshimura, H. Zhang, The Development of PlantGrowth Regulators with Bulky Substituents, 2013.11.6, Japan, 2013-230516.