南开大学化学学院程津培

chao500

程津培，有机化学家，中国科学院院士（2001），第三世界科学院院士（TWAS，2001）。1975年毕业于天津师范学院，1981年获南开大学硕士，1987年获美国西北大学博士，1988年到南开大学工作（1995-2000年任副校长），2000-2008年担任国家科技部副部长。现任全国人大常委、教科文卫委员会副主任、致公党中央副主席、国家教育咨询委员会委员、国家科技奖励委员会委员、欧美同学会副会长等职。


姓　　名        程津培        
性　　别        男
出生年月        1948-06        
籍　　贯        江苏灌云
学　　历        博士        
毕业院校        美国西北大学
职　　称        教授        
系所单位        化学系
特殊人才称号        中国科学院院士
        
研究领域        
物理有机化学
有机能量学
化学键键能的测定与计算

荣誉和奖励        
2005年，获香港何梁何利基金会“何梁何利奖”。
2013年，获中国化学会“物理有机化学成就奖”。


科研成果与代表作        SELECTED PUBLICATIONS
The Essential Role of Bond Energetics in C-H Activation/Functionalization, X.-S. Xue, P. Ji, B. Zhou, J.-P. Cheng, Chem. Rev. 2017, DOI: 10.1021/acs.chemrev.6b00664.
Asymmetric Conjugate Addition of Benzofuran-2-ones to Alkyl 2-Phthalimidoacrylates: Modeling Structure-Stereoselectivity Relationships with Steric and Electronic Parameters, C. Yang, E.-G. Zhang, X. Li, J.-P. Cheng, Angew. Chem. Int. Ed. 2016, 55, 6506-6510.
Phosphoric Acid Catalyzed Asymmetric 1,6-Conjugate Addition of Thioacetic Acid to para-Quinone Methides, N. Dong, Z.-P. Zhang, X.-S. Xue, X. Li, J.-P. Cheng, Angew. Chem. Int. Ed. 2016, 55, 1460-1464.
Weakly Polar Aprotic Ionic Liquids Acting as Strong Dissociating Solvent: A Typical “Ionic Liquid Effect” Revealed by Accurate Measurement of Absolute pKa of Ylide Precursor Salts. Mao, C.; Wang, Z.-D.; Wang, Z.; Ji, P.; Cheng, J.-P. J. Am. Chem. Soc. 2016, 138, 5523-5526.
Mechanism and Selectivity of Bioinspired Cinchona Alkaloid Derivatives Catalyzed Asymmetric Olefin Isomerization: A Computational Study, X.-S. Xue, X. Li, A. Yu, C. Yang, C. Song, J. P. Cheng, J. Am. Chem. Soc. 2013, 135, 7462-7473.
Asymmetric Supramolecular Primary Amine Catalysis in Aqueous Buffer: Connections of Selective Recognition and Asymmetric Catalysis,?S. S. Hu, J. Y. Li, J. F. Xiang, J. Pan, S. Z. Luo, J. –P. Cheng, J. Am. Chem. Soc. 2010, 20, 7216–7228.
Hydride, Hydrogen Atom, Proton, and Electron Transfer Driving Forces of Various Five-Membered Heterocyclic Organic Hydrides and Their Reaction Intermediates in Acetonitrile, X. Q. Zhu, M. T. Zhang, A. Yu, C. H. Wang, J. –P. Cheng,?J. Am. Chem. Soc., 2008, 130, 2501–2516.
A simple primary-tertiary Diamine-Bronsted acid catalyst for asymmetric direct aldol reactions of linear aliphatic ketones,?S. Z. Luo, H. Xu, J. Y. Li, L. Zhang, J. –P. Cheng, , J. Am. Chem. Soc. 2007, 129, 3074-3075.
A facile experimental method to determine the hydride affinity of polarized olefins in acetonitrile,?X. Q. Zhu, M. Zhang, Q. Y. Liu, X. X. Wang, J. Y. Zhang, J. –P. Cheng, Angew. Chem. Int. Ed. 2006, 45, 3954-3957.
Functionalized chiral ionic liquids as highly efficient asymmetric organocatalysts for michael addition to nitroolefins,?S. Z. Luo, X. L. Mi, L. Zhang, S. Liu, H. Xu, J. –P. Cheng, Angew. Chem. Int. Ed. 2006, 45, 3093-3097.
Determination of N-NO bond dissociation energies of N-methyl-N-nitrosobenzenesulfonamides in acetonitrile and application in the mechanism analyses on NO transfer,?X. Q. Zhu, W. F. Hao, H. Tang, C. H. Wang, J. –P. Cheng, J. Am. Chem. Soc. 2005, 127, 2696-2708.
First estimation of C4-H bond dissociation energies of NADH and its radical cation in aqueous solution,?X. Q. Zhu, Y. Yang, M. Zhang, J. –P. Cheng, J. Am. Chem. Soc. 2003, 125, 15298-15299.
Dissociation energies and charge distribution of CO-NO bond for nitrosyl-alpha, beta, gamma, deta-tetraphenylporphinatocobalt (II) and nitrosyl-alpha, beta, gamma, deta-tetraphenylporphinatocobalt (III) in benzonitrile solution,?X. Q. Zhu, Q. Li, W. F. Hao, J. -P. Cheng, J. Am. Chem. Soc. 2002, 124, 9887-9893.
NO affinities of S-nitrosothiols: A direct experimental and computational investigation of RS-NO bond dissociation energies,?J. Lu, K. Wang, J. M. Wittbrodt, Z. Wen, H. B. Schlegel, P. G. Wang, J. –P. Cheng, J. Am. Chem. Soc. 2001, 123, 2903-2904.
Homolytic cleavage energies of R-H bonds centered on carbon atoms of high electronegativity: the first general observations of O-type variation on C-H BDEs and its implication for the governing factors leading to the distinct O/S Patterns of radical subst,?J. –P. Cheng, B. Liu, Y. Zhao, Z. Wen, Y. Sun, J. Am. Chem. Soc. 2000, 122, 9987-9992.

zixia