重庆大学化学化工学院熊燕

guanshengyuan

熊燕 教授，博士生导师，1975年生。2007年毕业于四川大学有机化学专业，获博士学位，师从中科院院士冯小明教授，从事不对称催化合成研究。2008年爱尔兰都柏林大学CSCB研究中心做博士后，从事超价碘化学与过渡金属催化去对称化研究，爱尔兰政府IRCSET学者，导师Dr. Hasim Ibrahim。 2009年回国，重庆大学任教，从事有机化学的教学科研工作。2014年北京大学做访问学者，导师中科院院士刘忠范教授，主要从事新型骨架构建的碳材料研究。


联系方式
Email：xiong@cqu.edu.cn
研究方向
1. 化学工程与技术。化工新材料，新型骨架碳材料的设计、制备和表征；有机化工工艺路线的设计与开发。
2. 有机化学。不对称合成，从事具有生物活性的手性农药、医药及其中间体的合成。
代表性论文、专著和专利
[1] Hang Shen, Qingfu Deng, Ruojuan Liu, Yangyang Feng, Yan Xiong* Hypervalent Iodine-Promoted Annulative Aminocyanation of Unactivated Alkenes. Org. Chem. Front. 2017, 4, 1806-1811. (IF = 5.0)
[2] Congke Zheng, Xiaohui Zhang, Muhammad Ijaz Hussain, Mingming Huang, Qing Liu, Yan Xiong,* Xiangming Zhu,*One-pot Dichlorinative Deamidation of Primary β-Ketoamides. Tetrahedron Lett. 2017, 58, 574-577.
[3] Jiaqiang Li, Ziqian Xie, Yan Xiong, Zhenzhu Li, Qunxing Huang, Shuqing Zhang, Jingyuan Zhou, Rong Liu, Xin Gao, Changguo Chen, Lianming Tong*, Jin Zhang*, Zhongfan Liu,* Architecture of β-Graphdiyne Contained Thin Film Using Modified Glaser-Hay Coupling Reaction for Enhanced Photocatalytic Property of TiO2. Adv.Mater. 2017, 29, 1700421. (IF = 19.8)
[4] Liangzhen Hu, Jing Pan, Xiaohui Zhang, Wen Hu, Yan Xiong,* Xiangming Zhu, Synthesis of N, O π-Conjugated Boron Complexes and the Reactivity of Suzuki Cross-Coupling. Tetrahedron 2017, 73, 223-229.
[5] Qing Liu, Xiaohui Zhang,* Yang He, Muhammad Ijaz Hussain, Wen Hu, Yan Xiong,* Xiangming Zhu, Oxidative Rearrangement Strategy for Synthesis of 2, 4, 5-Trisubstituted Oxazoles Utilizing Hypervalent Iodine Reagent. Tetrahedron2016, 72, 5749-5753.
[6] Yangyang Feng, Ruofeng Huang, Liangzhen Hu, Vincent Coeffard,* Yan Xiong,* Enantioselective α-Oxytosylation of 1,3-Dicarbonyl Compounds Catalyzed by Chiral C2-Symmetric Iodoarenes. Synthesis 2016, 48,2637-2644.
[7] Mingming Huang, Liangzhen Hu, Hang Shen, Qing Liu, Muhammad Ijaz Hussain, Jing Pan, Yan Xiong,* Metal-Free Strategy for Sulfination of Alcohols with Sodium Sulfinates: An Unexpected Access. Green Chem. 2016, 18, 1874-1879. (IF = 9.2)
[8] Hang Shen,  Liangzhen Hu, Qing Liu, Muhammad Ijaz Hussain, Jing Pan,  Mingming Huang, Yan Xiong,*  Iron-Catalysed Sequential Reaction towards alpha-Aminonitriles from Secondary Amines, Primary Alcohols and Trimethylsilyl Cyanide. Chem. Commun. 2016, 52, 2776-2779. (IF = 6.3)
[9] Yang Li, Ping Deng, Youmao Zeng, Yan Xiong, Hui Zhou,*  anti-Selective Asymmetric Henry Reaction Catalyzed by a Heterobimetallic Cu–Sm–Aminophenol Sulfonamide Complex. Org. Lett. 2016, 18, 1578-1581. (IF = 6.6)
[10] Youmao Zeng, Ping Deng, Shixiong Zhang, Hong Yan, Guojuan Liang, Yan Xiong, Hui Zhou,* An Ni–PyBisulidine Complex for the Asymmetric Hydrophosphonylation of Aldehydes. Org. Biomol. Chem. 2016, 14, 9221-9224.
[11] Hang Shen, Xiaohui Zhang, Qing Liu, Jing Pan, Wen Hu, Yan Xiong,* Xiangming Zhu, Direct Oxidative Cyanation of Tertiary Amines Promoted by in situ Generated Hypervalent Iodine(III)-CN Intermediate. Tetrahedron Lett. 2015, 56, 5628-5631.
[12] Jiaqiang Li, Hang Shen, Qing Liu, Mingming Huang, Congke Zheng, Jing Pan, Yan Xiong,* Changguo Chen,*BF3·OEt2-catalyzed Etherification of Alcohols: a Metal-free Pathway to Diphenylmethyl Ethers. Adv. Synth. Catal. 2015, 357, 3115-3120. (IF = 5.6)
[13] Hang Shen, Jiaqiang Li, Qing Liu, Jing Pan, Ruofeng Huang, Yan Xiong,* Umpolung Strategy for Synthesis of β-Ketonitriles through Hypervalent Iodine-Promoted Cyanation of Silyl Enol Ethers. J. Org. Chem. 2015, 80, 7212-7218. (IF = 4.8)
[14] Jiaqiang Li, Qing Liu, Hang Shen, Ruofeng Huang, Xiaohui Zhang Yan Xiong,* Changguo Chen,* Ethers as Hydrogen Sources in BF3·OEt2 Promoted Reduction of Diphenylmethyl Alcohols, Ethers and Esters to Hydrocarbons. RSC Adv. 2015, 4, 85291-85295.
[15] Jing Pan, Jiaqiang Li, Ruofeng Huang, Xiaohui Zhang, Hang Shen, Yan Xiong,* Xiangming Zhu, Extension Studies on Iron(III)-Promoted Free Radical Oxidation of Anilines. Tetrahedron 2015, 71, 5341-5346.
[16] Jing Pan, Jiaqiang Li, Ruofeng Huang, Xiaohui Zhang, Hang Shen, Xuege Ling, Yan Xiong,* Xiangming Zhu, Direct Metal-Free N-Benzylaiton of Sulfonamides with Benzyl alcohols Promoted by Employing BF3·Et2O. Synthesis 2015, 47, 1101-1108.
[17] Xiaohui Zhang, Ruofeng Huang, Jérôme Marrot, Vincent Coeffard,* Yan Xiong,* Hypervalent Iodine-Mediated Synthesis of Benzoxazoles and Benzimidazoles via an Oxidative Rearrangement. Tetrahedron 2015, 71, 700-708.
[18] Ruofeng Huang, Xuege Ling, Xiaohui Zhang, Jing Pan, Chao He, Yan Xiong,* Benzylation of Arenes with Benzyl Halides Synergistically Promoted by in situ Generated Superacid Boron Trifluoride Monohydrate and Tetrahaloboric Acid. Tetrahedron2015, 71, 1540-1546.
[19] Hang Ma, Yang He, Ruofeng Huang, Xiaohui Zhang, Jing Pan, Jiaqiang Li,  Chao He, Xuege Ling, Xuanlun Wang,Yan Xiong,*  Nucleophilic Imidoesterification of Dicarbonyl Compounds with Cyanatobenzenes through C-C Bond Formation. Chin. Chem. Lett. 2014, 25, 1327-1330.
[20] Shuting Zhang, Xiaohui Zhang, Xuege Ling, Chao He, Ruofeng Huang, Jing Pan, Jiaqiang Li, Yan Xiong,* Superacid BF3-H2O Promoted Benzylation of Arenes with Benzyl Alcohols and Acetates Initiated by Trace Water. RSC Adv. 2014, 4, 30768-30774.
[21] Yajun Liu, Ping Deng, Xiangyang Li, Yan Xiong, Hui Zhou,* Asymmetric Henry Reaction Catalyzed by a Chiral Dinuclear Nickel Complex. Synlett 2014, 25, 1735-1738.
[22] Chao He, Xiaohui Zhang, Ruofeng Huang, Jing Pan, Jiaqiang Li, Xuege Ling, Yan Xiong,* Xiangming Zhu, Synthesis of Structurally Diverse Diarylketones through the Diarylmethyl sp3 C-H Oxidation. Tetrahedron Lett. 2014, 55, 4458-4462.
[23] Yu Li, Yan Xiong,* Xueming Li,* Xuege Ling, Ruofeng Huang, Xiaohui Zhang, Jianchun Yang, Benzylation of Arenes with Benzyl Ethers Promoted by in situ Prepared Superacid BF3-H2O. Green Chem. 2014, 16, 2976-2981. (IF = 9.2)
[24] Zhiyong Wang*, Xiaoxiao Xing, Liun Xue, Yan Xiong, Ling Fang*. Iron(III) Chloride Catalyzed Formation of Aryl Hydrazides from Electron-Rich Arenes and Azodicarboxylates, Synthesis 2014, 757-760.
[25] Xiafei Xu, Yan Xiong,* Xuege Ling, Ximi Xie, Jie Yuan, Shuting Zhang, Zhongrong Song,* A Practical Synthesis of Bis(indolyl)methanes Catalyzed by BF3·OEt2. Chin. Chem. Lett. 2014, 25, 406-410.
[26] Xuege Ling, Yan Xiong,* Ruofeng Huang, Xiaohui Zhang, Shuting Zhang, Changguo Chen,* Synthesis of Benzidine Derivatives via FeCl3·6H2O-Promoted Oxidative Coupling of Anilines. J. Org. Chem. 2013, 78, 5218-5226. (IF = 4.8)
[27] Ramulu Akula, Yan Xiong, Hasim Ibrahim,* Electrophilic α-Cyanation of 1,3-Dicarbonyl Compounds. RSC Adv. 2013, 3, 10731-10735.
[28] Xue-Ge Ling, Yan Xiong,* Shu-Ting Zhang, Ruo-Feng Huang, Xiao-Hui Zhang, Effective Synthesis of Benzyl Halides Triggered by in situ Prepared Hypervalent Halides. Chin. Chem. Lett. 2013, 24, 45-48.
[29] Qixiang Guo,* Wei Wen, Lina Fu, Shunen Zhang, Lanxi Zhang, Yuwan Liu, Biao Xu, Yan Xiong, Organocatalytic Aldol Reaction of Indole-3-Carbaldehydes with Ketones: Synthesis of Chiral 3-Substituted Indoles. Tetrahedron Lett. 2013, 54, 4653-4654.
[30] Yan Xiong,* Shuting zhang, Xuege Ling, Xu Zhang, Jinyue Wang, Theoretical Investigation on Identical Anionic Halide-Exchange SN2 Reaction Processes on N-Haloammonium Cation NH3X+ (X = F, Cl, Br, and I). Int. J. Quantum Chem.2012, 112, 2475-2481.
[31] Xu Zhang, Yan Xiong,* Shuting Zhang,Xuege Ling, Jinyue Wang, Changguo Chen,* Aldol Condensations of Aldehydes and Ketones Catalyzed by Primary Amine on Water. Asian J. Chem. 2012, 24, 751-755.
[32]  Yan Xiong,* Xueqiang Zhang, Significant Heterogeneous Carbonate Salt Catalyzed Acetylation of Alcohols via a Transesterification Process with Carbonate Salt-Activated Alcohol 1H NMR Evidence. Chin. J. Chem. 2011, 29, 1143-1148.
[33]  Shiyuan Zheng, Yan Xiong,* Jinyue Wang, Theoretical Studies on Identity SN2 Reactions of Lithium Halide and Methyl Halide: A Microhydration Model. J. Mol. Model. 2010,16, 1931-1937.
[34]  Fei Wang, Xiaohua Liu, Xin Cui, Yan Xiong, Xin Zhou, Xiaoming Feng,* Asymmetric Hydrophosphonylation of α-Ketoesters Catalyzed by Cinchona-derived Thiourea Organocatalyst. Chem. Eur. J. 2009, 15, 589-592.
[35]  Shiyuan Zheng, Jinyue Wang and Yan Xiong,* Theoretical Investigation on Isomerization of Et2AlCN to Et2AlNC and Cyanation of Aldimine. J. Mol. Struct.: THEOCHEM 2008, 869, 83-88.
[36]  Yan Xiong, Fei Wang, Shunxi Dong, Xiaohua Liu, Xiaoming Feng,* Asymmetric Bisprolinamide-Catalyzed Cross-Aldol of Aldehydes. Synlett 2008, 73-75.
[37]  Yan Xiong, Yuehong Wen, Fei Wang, Bo Gao, Xiao Huang, Xiaohua Liu, Xiaoming Feng,* A Chiral Functionalized Salt-Catalyzed Asymmetric Michael Addition of Ketones to Nitroolefins. Adv. Synth. Catal. 2007, 349, 2156-2166.
[38] Yan Xiong, Fei Wang, Xiao Huang, Yuehong Wen, Xiaoming Feng,* A New Copper(I)-Tetrahydrosalen-Catalyzed Asymmetric Henry Reaction and Its Extension to Synthesis of (S)-Norphenylephrine. Chem. Eur. J. 2007, 13, 829-833.
[39]  Yuehong Wen, Yan Xiong, Lu Chang, Jinglun Huang, Xiaohua Liu, Xiaoming Feng,* Chiral Bisformamide as an Effective Asymmetric Organocatalyst for One-Pot Three-Component Strecker Reaction. J. Org. Chem.2007, 72, 7715-7719.
[40] Fei Wang, Yan Xiong, Xiaohua Liu, Xiaoming Feng,* Asymmetric Direct Aldol Reaction of α-Keto Esters and Acetone Catalyzed by Organocatalyst. Adv. Synth. Catal. 2007, 349, 2665-2668.
[41] Yi Ren,* Jinggang Gai, Yan Xiong, Kuo-Hsing Lee, San-Yan Chu, Theoretical Study on the Identity Ion Pair SN2 Reactions of LiX with CH3SX (X = Cl, Br, and I): Structure, Mechanism, and Potential Energy Surface. J. Phys. Chem. A 2007,111, 6615-6621.
[42]  Yan Xiong, Xiao Huang, Shaohua Gou, Jinglun Huang, Yuehong Wen, Xiaoming Feng,* Enantioselective Cyanosilylation of Ketones Catalyzed by a Nitrogen-Containing Bifunctional Catalyst. Adv. Synth. Catal. 2006, 348, 538-544.
[43] Shaohua Gou, Xiaohong Chen, Yan Xiong, Xiaoming Feng,* Highly Enantioselective Cyanation of Aldehydes Catalyzed by A Multicomponent Titanium Complex. J. Org. Chem. 2006, 71, 5732-5736.
[44] Yuehong Wen, Xiao Huang, Jinglun Huang, Yan Xiong, Bo Qin, Xiaoming Feng,* Asymmetric Cyanosilylation of Aldehydes Catalyzed by Novel Organocatalysts. Synlett 2005, 16, 2445-2448.
[45] Yan Xiong, Hua-jie Zhu, Yi Ren,* A Theoretical Study of The Gas-phase Ion Pair SN2 Reactions of Lithium Halide and Methyl Halide with Inversion and Retention Mechanisms. J. Mol. Struct.: THEOCHEM 2003, 664-665, 279–289.