四川大学化学学院游劲松

zaotuo · 发表于 2018-3-29 15:48:40

游劲松 博士，四川大学教授，四川大学化学学院院长、化学实验教学中心主任、有机化学教研室主任，曾担任化学学院教授委员会主任，十二五“863”项目“新型纳米能源材料及器件制备关键技术”首席专家。1998年6月于四川大学化学系有机化学专业获博士学位。此后，分别在台湾中兴大学、德国Rostock有机催化研究所、美国依阿华州立大学（ISU）、美国加州大学尔湾分校（UCI）等进行学习和研究工作。2000年7月晋升为四川大学副教授，2004年5月特聘为四川大学教授。2004年入选教育部新世纪优秀人才资助计划，2005年入选四川省杰出青年学科带头人培养计划，2005年获得四川省青年科技奖，2006年获得四川省突出贡献专家称号，2010年获得国家杰出青年科学基金，2012年享受国务院特殊津贴专家，2013年获得四川省学术和技术带头人称号，2014年入选国家中青年科技创新领军人才，2016年入选国家万人计划科技创新领军人才。

游劲松
职称与职务  教授（博导）、院长
专    业  有机化学
电    话
电话：+86-28-85412203 传真：+86-28-85412203
E-Mail  jsyou@scu.edu.cn

学习经历
1985.9-1989.6 ：工学学士，重庆大学应用化学系
1992.9-1995.6 ：理学硕士，四川大学化学系有机化学专业，指导教师：蓝仲薇教授
1995.9-1998.6 ：理学博士，四川大学化学系有机化学专业，指导教师：谢如刚教授
工作与研究经历
1989.7-1992.8 ：成都化肥厂，助理工程师、车间主任
1995.7-2000.6 ：四川大学化学系，讲师
1999.2-2000.7 ：台湾中兴大学化学系，博士后
2000.7-2003.5 ：四川大学化学学院，副教授
2001.3-2002.5 ：德国ROSTOCK有机催化研究所（Institute für Organische Katalyseforschung），Research Scientist
2002.5-2003.5 ：美国爱荷华州立大学 (Iowa State University) 化学系，Postdoctoral
2003.5-2004.4 ：美国加州大学尔湾分校 (University of California, Irvine) 化学系，Research Associate
2004.5 - 至今：四川大学教授，博士生导师
2005.8-2011.6 ：四川大学化学学院教授委员会主任
2011.3 - 至今：四川大学化学学院副院长、四川大学化学基础实验教学中心主任
2017.6- 至今：四川大学化学学院院长

主要研究方向
近年科研项目
1、国家万人计划科技创新领军人才经费，2017-2021年。
2、基于C–H键直接高效高选择性转化构筑有机光电功能分子的化学基础，国家自然科学基金重点项目（批准号：21432005），350万，2015-2019年。
3、 “十二五” 863计划：“新型纳米能源材料及器件制备关键技术”（批准号：2013AA031900），项目首席专家，项目总经费2717万，2013-2015年。
4、基于芳杂环C-H键直接官能化反应的荧光功能材料的构筑：国家杰出青年基金（批准号：21025205），2011-2014年。
5、不饱和烃高效转化中的前沿科学问题：国家重点基础研究发展项目("973") (批准号：2011CB808600)，2011-2015年。
6、高选择性的有机合成新反应与新策略：国家自然科学基金创新群体 (批准号：21321061)，2014-2016年。
7、金属催化的杂芳环与杂芳环之间的C-H/C-H 交叉氧化偶联反应以及若干选择性问题研究：国家自然科学基金（批准号：21272160），2013-2016年。
8、若干企业合作项目
主要研究方向、实验装备与科研成果
1、主要研究方向
（1）C–H键活化的理论和策略
（2）基于C–H键活化策略的天然产物的合成
（3）基于C–H键活化策略构建有机光电功能分子的合成化学基础
（4）有机功能材料：光电转化材料（有机太阳能电池、有机场效应晶体管、有机发光二极管）、生物成像试剂、有机智能材料等
2 、光电器件制备与测试平台（ OEFT 、 OLED 、 DSSC 、 OPV ）
3、主要科研成果
（1）在C–H 键活化领域做出了系统性研究工作，特别是在氧化偶联反应方面取得了重要成果。在利用碳氢键活化构筑有机光电功能分子的化学基础研究方面，发展的“电子差异原则”和“螯合导向构筑稠杂环策略”为构建有机共轭骨架提供了高效高选择性合成途径，受到了国内外同行的关注，并被广泛应用，为开发新型先进性功能材料提供了重要合成基础。首创的杂芳环之间C–H/ C–H交叉氧化偶联反应被工业化学家评为具工业和实践价值的反应。这些简捷有效的合成方法也有助于药物化学家进行快速合成和筛选。
（2）发展了配位活化策略，实现氨基酸α-C(sp 3)–H键与多种亲核试剂或苄位C(sp 3)–H键的交叉氧化偶联反应，可简洁高效地构筑一系列α-季碳α-氨基酸衍生物及α-三级或四级碳-β-芳基-α-氨基酸衍生物。
（3）开发了一系列高性能有机太阳能电池(DSSC、OPV)、有机场效应晶体管（OFET）以及有机发光二极管（OLED）材料、生物成像试剂、有机智能材料等。
（4）迄今发表论文230余篇，包括 Chem. Rev.、 Nature Communication 、 J Am Soc Chem 、 Angew Chem Int Ed 、 Adv Funct Mater，授权国际国内发明专利18项。部分研究成果获得教育部自然科学奖一等奖。现已主持国家杰出青年科学基金以及重点项目等多项国家自然科学基金、教育部新世纪优秀人才资助计划、四川省杰出青年基金、973子课题以及多项企业合作项目等。作为项目首席专家，承担十二五863项目“新型纳米能源材料及器件关键制备技术”，总经费2717万元。
主要工作业绩
2016年万人计划科技创新领军人才
2014年国家中青年科技创新领军人才
2010年获得国家杰出青年科学基金
2013年“新型纳米能源材料及器件关键制备技术”863项目首席专家
2012年获得国务院特殊津贴专家称号
2013年四川省学术和技术带头人
2006年获得四川省突出贡献专家
2006年成都市优秀青年教师称号
2005年入选四川省杰出青年学科带头人培养计划（省杰青）
2004年入选教育部新世纪优秀人才资助计划
2012年四川大学唐立新青年科技之星奖
2010年获得教育部自然科学一等奖：简单金属盐催化的C-C键和C-N键形成反应
2005年获得四川省青年科技奖
2001年获得四川省科技进步三等奖：生物功能体系的分子模拟
代表性成果（获奖成果、专著、论文、专利）
游劲松发表文章及专利清单
一、发表的主要论文 2017 年（到 6 月）
1. Yudong Yang, Jingbo Lan, Jingsong You,* Oxidative C?H/C?H Coupling Reactions between Two (Hetero)arenes. Chem. Rev., 2017, DOI: 10.1021/acs.chemrev.6b00567. (Published: 2017-01-13)
2. Yinsong Zhao, Shiqing Li, Xuesong Zheng, Junbin Tang, Zhijie She, Ge Gao,* Jingsong You,* Rh/Cu-Catalyzed Cascade [4+2] Vinylic C?H O-Annulation and Ring Contraction of α-Aryl Enones with Alkynes in Air. Angew. Chem. Int. Ed., 2017, 56, 4286?4289. (Published: 2017-03-09)
3. Bijin Li, Guoqiang Tang, Linsen Zhou, Di Wu, Jingbo Lan,* Liang Zhou,* Zhiyun Lu, Jingsong You,* Unexpected Sole Enol-Form Emission of 2-(2′-Hydroxyphenyl)oxazoles for Highly Ef?cient Deep-Blue-Emitting Organic Electroluminescent Devices. Adv. Funct. Mater., 2017, 27, 1605245. (Published: 2017-01-12)
4. Guoqiang Tang, Bijin Li, Jingbo Lan,* Jingsong You,* An Effective Strategy to Construct Highly Efficient Deep-Blue Organic Light-Emitting Field-Effect Transistors. Advanced Materials Interfaces, 2017, DOI: admi.201700453R1 (Accepted: 2017-06-01).
5. Jingsheng Huang, Yunlong Yu, Shiyong Zhang*, Jingsong You,* Lipic Acid Based Core Cross-linked Micelles for Multivalent Platform: Design, Synthesis and Application in Bio-imaging and Drug Delivery. Organic & Biomolecular Chemistry, 2017, OB-COM-04-2017-000927.R2.
6. Xiaoyu Li, Shiqing Li, Ge Gao, Di Wu, Jingbo Lan, * Ruilin Wang * and Jingsong You, * High Performance Ruthenium Sensitizers Containing Imidazoliums as Counterions for the Efficient Dye-Sensitization in Water. ChemSusChem, 2017, DOI: 10.1002/cssc.201700579. (Accepted: 2017-06-01)
7. Junbin Tang, Shiqing Li, Zheng Liu, Yinsong Zhao, Zhijie She, Vilas D. Kadam, Ge Gao,* Jingbo Lan and Jingsong You, * Cascade C?H Annulation of Aldoximes with Alkynes Using O 2 as the Sole Oxidant: One-Pot Access to Multisubstituted Protoberberine Skeletons, Org. Lett., 2017, 19, 604?607. (Published: 2017-01-19)
8. Chunxia Wang, Luoqiang Zhang, Jingsong You.* Nickel-Catalyzed Aminoxylation of Inert Aliphatic C(sp 3)?H Bonds with Stable Nitroxyl Radicals Under Air: A One-Pot Route to α-Formyl Acid Derivatives. Org. Lett., 2017, 19, 1690?1693. (Published: 2017-03-23)
9. Shuyou Chen, Boya Feng, Xuesong Zheng, Jiangliang Yin, Shiping Yang, Jingsong You.* Iridium-Catalyzed Direct Regioselective C4-Amidation of Indoles under Mild Conditions. Org. Lett., 2017, 19 (10), 2502–2505 (Publication Date (Web): 2017-05-08).
10. Zhen Long, Zhigang Wang, Danni Zhou, Danyang Wan, and Jingsong You.* Rh(III)-Catalyzed Regio- and Chemoselective [4+1]-Annulation of Azoxy Compounds with Diazoesters for the Synthesis of 2 H-Indazoles: Roles of the Azoxy Oxygen Atom. Org. Lett., 2017, 19 (11), 2777–2780. (Publication Date (Web): 2017-05-17)
11. Zhen Long, Yudong Yang, and Jingsong You.* Rh(III)-Catalyzed [4+1]-Annulation of Azoxy Compounds with Alkynes: A Regioselective Approach to 2 H-Indazoles. Org. Lett., 2017 , 19 (11), 2781–2784. (Publication Date (Web): 2017-05-17)
12. Juan Li, Yudong Yang, Zhigang Wang, Boya Feng, and Jingsong You.* Rhodium(III)-Catalyzed Annulation of Pyridinones with Alkynes via Double C?H Activation: A Route to Functionalized Quinolizinones. Org. Lett., 2017, 19 (12), 3083–3086. (Publication Date (Web): 2017-05-30)
13. Shiqing Li, Junbin Tang, Yinsong Zhao, Ruyong Jiang, Tianbao Wang, Ge Gao* and Jingsong You,* Cu-Catalyzed Controllable C-H Mono-/Di-/Triarylations of Imidazolium Salts for Ionic Functional Materials. Chem. Commun., 2017, 53, 3489?3492. (Published: 2017-03-03)
14. Zhen He, Xiaotian Qi, Zhijie He, Yinsong Zhao, Shiqing Li, Junbin Tang, Ge Gao,* Yu Lan, and Jingsong You.* Room-Temperature Coupling/Decarboxylation Reaction of α-Oxocarboxylates with α-Bromoketones: Solvent-Controlled Regioselectivity for 1,2- and 1,3-Diketones. J. Org. Chem., 2017, 82, 1403?1411. (Published: 2017-01-04)
2016 年
15. Yangyang Cheng, Gaocan Li, Yang Liu, Yang Shi, Ge Gao,* Di Wu, Jingbo Lan, Jingsong You.* Unparalleled Ease of Access to a Library of Biheteroaryl Fluorophores via Oxidative Cross-Coupling Reactions: Discovery of Photostable NIR Probe for Mitochondria. J. Am. Chem Soc., 2016, 138 (14), 4730–4738. (Publication Date (Web): 2016-02-08)
16. Qian Wu, Yi Luo, Aiwen Lei,* Jingsong You.* Aerobic Copper-Promoted Radical-Type Cleavage of Coordinated Cyanide Anion: Nitrogen Transfer to Aldehydes to Form Nitriles. J. Am. Chem Soc., 2016 , 138 (9), 2885–2888. (Publication Date (Web): 2016-02-23)
17.  Jie Wu,  Yangyang Cheng,  Jingbo Lan *,  Di Wu,  Shengyou Qian,  Lipeng Yan,  Zhen He,  Xiaoyu Li,  Kai Wang,  Bo Zou *, Jingsong You .* Molecular Engineering of Mechanochromic Materials by Programmed C–H Arylation: Making a Counterpoint in the Chromism Trend. J. Am. Chem Soc., 2016, 138 (39), 12803–12812. (Publication Date (Web): 2016-09-07)
18. Guangying Tan, Shuang He, Xiaolei Huang, Xingrong Liao, Yangyang Cheng, Jingsong You .* Cobalt-Catalyzed Oxidative C–H/C–H Cross-Coupling between Two Heteroarenes. Angew. Chem. Int. Ed., 2016 , 55 (35), 10414–10418.  (Publication Date (Web): 2016-07-27)
19. Yangyang Cheng, Yimin Wu, Guangyin Tan, Jingsong You.* Nickel Catalysis-Enabled Oxidative C(sp 2)?H/C(sp 2)?H Cross-Coupling Reactions between Two Heteroarenes. Angew. Chem. Int. Ed., 2016, 55 (40), 12275 –12279. (Published: 2016-09-06).
20. Chengming Li, Liang Luo, Di Wu,* Ruyong Jiang, Jingbo Lan, Ruilin Wang,* Luyi Huang, Shengyong Yang, Jingsong You.* Porphyrins with Intense Absorptivity: Highly Efficient Sensitizers with a Photovoltaic Efficiency of up to 10.7% without a Cosensitizer and a Coabsorbate. J. Mater. Chem. A, 2016, 4, 11829–11834. (Accepted: 2016-06-30).
21. Qiang Guo, Di Wu,* Jingsong You.* Oxidative Direct Arylation Polymerization Using Oxygen as the Sole Oxidant: Facile, Green Access to Bithiazole-Based Polymers. ChemSusChem, 2016, 9(19), 2765–2768. (Accepted: 2016-07-11).
22. Wei Li, Xiaolei Huang, Jingsong You .* Ruthenium-Catalyzed Intermolecular Direct Silylation of Unreactive C(sp 3)?H Bonds. Org. Lett., 2016, 18 (4), 666–668. (Publication Date (Web): 2016-02-05).
23. Danyang Wan, Xiaoyu Li, Ruyong Jiang, Boya Feng, Jingbo Lan, Ruilin Wang, Jingsong You.* Palladium-Catalyzed Annulation of Internal Alkynes: Direct Access to π-Conjugated Ullazines. Org. Lett., 2016, 18, 2876?2879. (Published: 2016-05-26)
24.  Yinsong Zhao, Zhen He, Shiqing Li, Junbin Tang, Ge Gao,* Jingbo Lan, Jingsong You .* An Air-Stable Half-Sandwich Ru(II) Complex as an Efficient Catalyst for [3+2] Annulation of 2-Arylcyclo-2-enones with Alkynes. Chem. Commun., 2016, 52, 4613-4616. (Published on web: 2016-01-12).
25. Denan Sun, Bijin Li, Jingbo Lan,* Quan Huang, Jingsong You.* Chelation-Assisted Pd-Catalysed Ortho-Selective Oxidative C–H/C–H Cross-Coupling of Aromatic Carboxylic Acids with Arenes and Intramolecular Friedel–Crafts Acylation: One-Pot Formation of Fluorenones. Chem. Commun., 2016, 52, 3635?3638. (Accepted: 2016-01-28).
26. Yudong Yang, Kaizhi Li, Yangyang Cheng, Danyang Wan, Mingliang Li, Jingsong You.* Rhodium-Catalyzed Annulation of Arenes with Alkynes through Weak Chelation-Assisted C-activation (Feature article). Chem. Commun., 2016, 52, 2872–2884. (Published on web: 2016-01-04).
27. Xiaolei Huang, Wenbo Liang, Yang Shi, Jingsong You.* Rh(III)-Catalyzed Chemoselective C–H Functionalizations of Tertiary Aniline N-Oxides with Alkynes. Chem. Commun., 2016, 52, 6253–6256. (Published on web: 2016-04-05).
28. Zhuang Yang, Taijin Wang, Fang Wang, Ting Niu, Zhuowei Liu, Xiaoxin Chen, Chaofeng Long, Minghai Tang, Dong Cao, Xiaoyan Wang, Wei Xiang, Yuyao Yi, Liang Ma,  Jingsong You,* Lijuan Chen.* Discovery of Selective Histone Deacetylase 6 Inhibitors Using the Quinazoline as the Cap for the Treatment of Cancer.  J. Med. Chem ., 2016, 59 (4), 1455–1470. (Publication Date (Web): 2015-10-06).
29. Yang Liu, Yudong Yang,* Yang Shi, Xiaojie Wang, Luoqiang Zhang, Yangyang Cheng, Jingsong You.* Rhodium-Catalyzed Oxidative Coupling of Benzoic Acids with Terminal Alkynes: An Efficient Access to 3?Ylidenephthalides. Organometallics, 2016, 35, 1350?1353. (Published: 2016-03-24).
30. Qiang Guo, Ruyong Jiang, Di Wu,* Jingsong You.* Rapid Access to 2,2?-Bithiazole-Based Copolymers via Sequential Palladium-Catalyzed C?H/C?X and C–H/C–H Coupling Reactions. Macromol. Rapid Commun., 2016, 37(9), 794-798. (Published online: 2016-03-22).
31. Kaizhi Li, Jingsong You.* Cascade Oxidative Coupling/Cyclization: A Gateway to 3-Amino-2-Polysubstituted Five-Membered Heterocycles. J. Org. Chem., 2016, 81(6), 2327–2339. (Publication Date (Web): 2016-02-25).
32. Di Wu*, Ruyong Jiang, Liang Luo, Zhen He, Jingsong You.* Bromide anion-triggered visible responsive metallogels based on squaramide complexes. Inorg. Chem. Front., 2016,  3, 1597–1603. (published on the web: 2016-10-13)
33.  Fei Wang, Liang Zhao, Jingsong You, Mei-Xiang Wang.* Synthesis of trifluoromethylthiolated azacalix[1]arene[3]pyridines from the Cu(II)-mediated direct trifluoromethylthiolation reaction of arenes  via reactive arylcopper(III) intermediates, Org. Chem. Front., 2016, 3, 880–886. (Published online: 2016-05-20).
34. Danyang Wan, Yudong Yang,* Xingyan Liu, Mingliang Li, Siling Zhao, Jingsong You.* Radical Cyclization of Arenesulfonyl Chlorides and Alkynes: A Rapid Access to π-Conjugated Benzothio-phenes. Eur. J. Org. Chem., 2016, 55–59. (Published Online:  2015-12-09).
35. Boya Feng, Danyang Wan, Lipeng Yan, Vilas D. Kadam,  Jingsong You, Ge Gao.* A Facile Access to substituted cationic 12-azapyrene salts by rhodium(III)-catalyzed C–H annulation of N-arylpyridinium salts. RSC Adv., 2016,  6, 66407–66411. (Published on web: 2016-07-07).
36. Tianjun Liu, Jiawei Wang, Liang Wang, Jing Wang, Jingbo Lan,  Jingsong You, Chao Jiang.* Spiral Growth Mode in DMDPC Organic Thin Film Transistors by Physical Vapor Deposition. RSC Adv., 2016,  6, 50770–50775. (Published on web: 2016-05-19).
2015 年
37. Kaizhi Li, Qian Wu, Jingbo Lan, Jingsong You.* Coordinating activation strategy for C(sp3)-H/C(sp3)-H Cross-Coupling to Access b-Aromatic a-Amino Acids. Nature Commun., 2015, 6, 8404. (Published : 2015-09-29)
38. Zhen He, Xiaotian Qi, Shiqing Li, Yinsong Zhao, Ge Gao,* Yu Lan,* Yiwei Wu, Jingbo Lan, Jingsong You.* Transition-Metal-Free Formal Decarboxylative Coupling of α-Oxocarboxylates with α-Bromoketones under Neutral Conditions: a Simple Access to 1,3-Diketones. Angew. Chem. Int. Ed., 2015, 54(3), 855?859. (Published online : 2014-11-24)
39. Xurong Qin, Xiaoyu Li, Quan Huang, Hu Liu, Di Wu, Qiang Guo, Jingbo Lan,* Ruilin Wang, Jingsong You.* Rhodium(III)-Catalyzed ortho C–H Heteroarylation of (Hetero)aromatic Carboxylic Acids: A Rapid and Concise Access to p-Conjugated Poly-heterocycles. Angew. Chem. Int. Ed., 2015, 54(24), 7167?7170. (Published online: 2015-04-27)
40. Xiaolei Huang, Yan Wang, Jingbo Lan, Jingsong You.* Rhodium(III)-Catalyzed Activation of Csp3-H Bonds and Subsequent Intermolecular Amidation at Room Temperature, Angew. Chem. Int. Ed., 2015, 54(32), 9404?9408. (Published online: 2015-07-14)
41. Bijin Li, Jingbo Lan,* Di Wu, Jingsong You.* Rhodium(III)-Catalyzed ortho-Heteroarylation of Phenols through Internal Oxidative C?H Activation: Rapid Screening of Single-Molecular White-Light-Emitting Materials, Angew. Chem. Int. Ed., 2015, 54(47), 14008?14012 (Published online: 2015-09-25)
42. Qian Wu, Chenglong Du, Yumin Huang, Xingyan Liu, Zhen Long, Feijie Song, Jingsong You.* Stoichiometric to Catalytic Reactivity of the Aryl Cycloaurated Species with Arylboronic Acids: Insight into the Mechanism of Gold-Catalyzed Oxidative C(sp 2)–H Arylation. Chem. Sci., 2015, 6(1), 288?293. (Published on web: 2014-10-09)
43.  Zhijie She, Yangyang Cheng, Luoqiang Zhang, Xiaoyu Li, Di Wu, Qiang Guo, Jingbo Lan, * Ruilin Wang, * Jingsong You . * Novel Ruthenium Sensitizers with a Phenothiazine Conjugated Bipyridyl Ligand for High-Efficiency Dye-Sensitized Solar Cells, ACS Appl. Mater. Interfaces, 2015,  7 (50), 27831–27837. (Publication Date (Web): 2015-12-01)
44. Xurong Qin, Denan Sun, Qiulin You, Yangyang Cheng, Jingbo Lan,* Jingsong You.* Rh(III)-Catalyzed Decarboxylative ortho-Heteroarylation of Aromatic Carboxylic Acids by Using the Carboxylic Acid as a Traceless Directing Group. Org. Lett., 2015, 17(7), 1762?1765. (Publication Date (Web): 2015-03-23)
45. Mingliang Li, Yudong Yang, Danni Zhou, Danyang Wan, Jingsong You.* Nickel-Catalyzed Addition-Type Alkenylation of Unactivated, Aliphatic C?H Bonds with Alkynes: a Concise Route to Polysubstituted γ?Butyrolactones. Org. Lett. 2015 , 17 (10), 2546–2549. (Publication Date (Web): 2015-04-30)
46. Xingyan Liu, Xiaoyu Li, Hu Liu, Qiang Guo, Jingbo Lan, * Ruilin Wang, Jingsong You.* Aldehyde as a Traceless Directing Group for Rh(III)-Catalyzed C–H Activation: A Facile Access to Diverse Indolo[1,2-a]quinolines. Org. Lett., 2015, 17(12), 2936–2939. (Publication Date (Web): 2015-05-29)
47. Jing Wang, Dekun Qin, Jingbo Lan,* Yangyang Cheng, Shuai Zhang, Qiang Guo, Jie Wu, Di Wu, Jingsong You.* Rh-Catalysed Direct Cyclization of 1,4-Naphthoquinone and 9,10-Phenanthraquinone with Alkyne: Facile Access to 1,8-Dioxapyrenes and 1,12-Dioxaperylenes as Orange and Red-Emitting luminophores. Chem. Commun., 2015, 51(29), 6337–6339. (Accepted 2015-03-02)
48. Dekun Qin, Jing Wang, Xurong Qin, Chunxia Wang, Ge Gao,* Jingsong You.* Rh(III)-Catalyzed Oxime Ether-Directed Heteroarylation of Arene Through Oxidative C-H/C-H Cross-Coupling. Chem. Commun., 2015, 51(28), 6190?6193. (Accepted: 2015-03-02)
49. Wei Li, Feijie Song, Jingsong You.* Oxidant-Controlled Catalytic Transformations of Phenols with Unexpected Cleavage of Aromatic Rings. Chem. Eur. J., 2015, 21, 13913–13918. (Published online: 2015-08-18)
50. Chunxia Wang, Yudong Yang,* Dekun Qin, Zhen He, Jingsong You.* Copper-Catalyzed Intramolecular Dehydrogenative Amidation of Unactivated C(sp 3)?H Bonds Using O 2 as the Sole Oxidant, J. Org. Chem., 2015, 80, 8424?8429. (Publication Date (Web): 2015-08-06)
51. Jie Wu, Qiulin You, Jingbo Lan,* Qiang Guo, Xiaoyu Li, Ying Xue, Jingsong You.* Cu-Catalysed Direct C–H (Hetero)arylation of [1,2,4]Triazolo[4,3-a]pyridine to Construct Deep-Blue-Emitting Luminophores. Org. Biomol. Chem., 2015, 13(19), 5372–5375. (Published online: 2015-04-07)
52. Shuai Zhang, Yuanhong Ma, Jingbo Lan, Feijie Song,* Jingsong You.* Gold-Catalyzed Cascade C–H/C–H Cross-Coupling/Cyclization/Alkynylation: an Efficient Access to 3-Alkynylpyrroles, Org. Biomol. Chem., 2015, 13, 5867?5870. (Published online: 2015-04-16)
53. Hu Liu, Xingrong Liao, Xiaoyu Li, Di Wu, Qiang Guo, Jie Wu, Shengyou Qian, Jingbo Lan,* Ruilin Wang,* Jingsong You.* Molecular design of new organic sensitizers based on thieno[1,4]benzothiazine for dye-sensitized solar cells. RSC Adv., 2015, 5(70), 56865?56871. (Accepted: 2015-06-19)
54. Jiaxing Dong, Qian Wu, Jingsong You.* Digest Paper: Stoichiometric Copper or Silver Salt-Mediated Oxidative C–H/C–H Cross-Coupling Reactions, Tetrahedron Lett., 2015, 56(13), 1591?1599. (Available online: 2015-02-07)
55. Xingyi Zhang, Xin-Ming Xu, Liang Zhao, Jingsong You, Jieping Zhu, Mei-Xiang Wang.* Synthesis of Diverse di- to Penta-Substituted 1,2-Dihydropyridine Derivatives from Gold(I)-Catalyzed Intramolecular Addition of Tertiary Enamides to Alkynes, Tetrahedron Lett., 2015, 56(25), 3898?3901. (Available online: 2015-04-30)
56. Xiaolei Huang, Jingsong You.* Rhodium(III)-catalyzed C(sp3)-H Amidation of 8-Methylquinolines with Amides at Room Temperature, Chem. Lett. 2015, 44, 1685–1687 (Editor’s choice) (Available online: 2015-02-07)
57. Yang Shi, Zhen Wang, Yangyang Cheng, Jingbo Lan, Zhijie She and Jingsong You.* Oxygen as an Oxidant in Palladium/Copper-Cocatalyzed Oxidative C–H/C–H Cross-Coupling between Two Heteroarenes, Sci. China Chem., 2015, 58, 1292–1296. (cover story; NSR: national Science Report) (Accepted: 2015-01-07)
2014 年
58. Xingyan Liu, Gaocan Li, Feijie Song, Jingsong You.* Unexpected Regioselective Carbon–Hydrogen Bond Activation/Cyclization of Indolyl Aldehydes or Ketones with Alkynes to Benzo-Fused Oxindoles. Nat. Commun., 2014, 5, 5030. (Accepted: 2014-08-19)
59. Yumin Huang, Di Wu, Jingsheng Huang, Qiang Guo, Juan Li, Jingsong You.* Wilkinson's Catalyst for the ortho-C-H Heteroarylation of Aromatic Amines: A Facile Access to Highly Extended π-Conjugated Heteroacenes for Organic Semiconductors. Angew. Chem. Int. Ed., 2014, 53(45), 12158?12162. (Published online: 2014-09-12)
60. Yuanhong Ma, Shuai Zhang, Shiping Yang, Feijie Song,* Jingsong You.* Gold-Catalyzed Cascade C(sp 3)–H/C(sp)–H Coupling/Cyclization/Oxidative Alkynylation: A Powerful Strategy for the Synthesis of 3-Alkynyl Polysubstituted Furans. Angew. Chem. Int. Ed., 2014, 53(30), 7870–7874. (Published online: 2014-04-11)
61. Gaocan Li, Feijie Song, Di Wu, Jingbo Lan, Xingyan Liu, Jie Wu, Shuaijun Yang, Dan Xiao, Jingsong You.* Cation-Anion Interaction-Directed Molecular Design Strategy for Mechanochromic Luminescence. Adv. Funct. Mater., 2014, 24 (6), 747?753. ( Cover Story; Highlighted by ACS Noteworthy Chemistry). (Published online: 2013-09-03)
62. Gaocan Li , Shiyong Zhang ,* Ningjie Wu , Yangyang Cheng, Jingsong You.*Spontaneous Counterion-Induced Vesicle Formation: Multivalent Binding to Europium(III) for a Wide Range Optical pH Sensor. Adv. Funct. Mater., 2014, 24 (39), 6204?6209. (Published online: 2014-07-29)
63. Jiaxing Dong , Fei Wang , Jingsong You.* Copper-Mediated Tandem Oxidative C(sp 2)–H/C(sp)–H Alkynylation and Annulation of Arenes with Terminal Alkynes. Org. Lett., 2014, 16 (11 ), 2884–2887. (Publication Date (Web):  2014-05-23)
64. Jie Wu, Jingbo Lan,* Siyuan Guo, and Jingsong You.* Pd-Catalyzed C?H Carbonylation of (Hetero)arenes with Formates and Intramolecular Dehydrogenative Coupling: A Shortcut to Indolo[3,2- c]coumarins. Org. Lett., 2014, 16(22), 5862?5865. (Publication Date (Web): 2014-11-03)
65. Liang Luo, Di Wu,* Wei Li, Shuai Zhang, Yuanhong Ma, Su Yan, Jingsong You.* Regioselective Decarboxylative Direct C?H Arylation of Boron Dipyrromethenes (BODIPYs) at 2,6-Positions: A Facile Access to a Diversity-Oriented BODIPY Library. Org. Lett., 2014, 16(23), 6080?6083. (Publication Date (Web): 2014-11-17)
66. Chao Long, Liang Zhao, Jingsong You, Meixiang Wang.* Copper(I)-Catalyzed Halogenation and Acyloxylation of Aryl Triflates through a Copper(I)/Copper(III) Catalytic Cycle. Organometallics, 2014, 33(4 ), 1061–1067. (Publication Date (Web): 2014-02-06)
67. Ningjie Wu, Feijie Song, Lipeng Yan, Juan Li, Jingsong You.* Transition-Metal-Catalyzed C–H Bond Functionalizations: Feasible Access to a Diversity-Oriented β-Carboline Library. Chem. Eur. J., 2014, 20(12 ), 3408–3414. (Published online: 2014-2-12)
68. Mingliang Li, Jiaxing Dong, Xiaolei Huang, Kaizhi Li, Qian Wu, Feijie Song, Jingsong You.* Nickel-Catalyzed Chelation-Assisted Direct Arylation of Unactivated C(sp 3)–H Bonds with Aryl Halides. Chem. Commun., 2014, 50(30), 3944–3946. (Accepted: 2014-02-19)
69. Shiqing Li, Fan Yang, Taiyong Lv, Jingbo Lan, Ge Gao,* Jingsong You.*Synthesis of Unsymmetrical Imidazolium Salts by Direct Quaternization of N-Substituted Imidazoles with Arylboronic Acids. Chem. Commun., 2014, 50(30), 3941–3943. (Accepted: 2014-02-21)
70. Ningjie Wu, Jingbo Lan,* Lipeng Yan, Jingsong You. *A Sensitive Colorimetric and Fluorescent Sensor Based on Imidazolium-Functionalized Squaraines for the Detection of GTP and Alkaline Phosphatase in Aqueous Solution. Chem. Commun., 2014, 50(34), 4438-4441. (Accepted: 2014-03-04)
71. Chao Gao, Ge Gao,* Jingbo Lan, Jingsong You.* An AIE Active Monoimidazolium Skeleton: High Selectivity and Fluorescence Turn-On for H 2PO 4 ? in Acetonitrile and Clo 4 ? in Water. Chem. Commun., 2014, 50(42), 5623–5625. (Accepted: 014-04-04)
72. Lei Yang, Yuanhong Ma, Feijie Song,* Jingsong You.* Silver-Catalyzed One-Pot Cyclization/Fluorination of 2-Alkynylanilines: Highly Efficient Synthesis of Structurally Diverse Fluorinated Indole Derivatives. Chem. Commun., 2014, 50 (23), 3024–3026. (Accepted: 2014-01-28)
73. Quan Huang, Xurong Qin, Bijin Li, Jingbo Lan,* Qiang Guo and Jingsong You.* Cu-Catalysed Oxidative C–H/C–H Coupling Polymerisation of Benzodiimidazoles: an Efficient Approach to Regioregular Polybenzodiimidazoles for Blue-Emitting Materials. Chem. Commun., 2014, 50 (89), 13739?13741. (Accepted: 2014-09-15)
74. Zhijie She, Yang Shi, Yumin Huang, Yangyang Cheng, Feijie Song* and Jingsong You.* Versatile Palladium-Catalyzed C–H Olefination of (Hetero)arenes at Room Temperature. Chem. Commun., 2014, 50 (90), 13914?13916. (Accepted: 2014-09-27)
75. Juan Li, Zhigang Wang, Ningjie Wu, Ge Gao* and Jingsong You.* Radical Cascade Cyanomethylation of Activated Alkenes to Construct Cyano Substituted Oxindoles. Chem. Commun., 2014, 50 (95), 15049?15051. (Accepted: 2014-10-10)
76. Yumin Huang, Gaocan Li, Jingsheng Huang, Jingsong You.* Palladium-Catalyzed Direct ortho-C–H Ethoxycarboxylation of Anilides at Room Temperature. Org. Chem. Front., 2014, 1 (4), 347–350. (Accepted: 2014-01-26)
77. Chengming Li, Chao Gao, Jingbo Lan, Jingsong You and Ge Gao.* An AIE Active Y-shaped Diimidazolylbenzene: Aggregation and Disaggregation for Cd 2+ and Fe 3+ Sensing in Aqueous Solution. Org. Bio. Chem., 2014, 12(47), 9524?9527. (Accepted: 2014-10-10)
78. Guangying Tan, Xiaolei Huang, Qian Wu, Luo-Qiang Zhang, Jingsong You.* Rh(III)-Catalyzed Annulation of N-Methoxybenzamides with Ynesulfonamides at Room Temperature: A Practical And Efficient Route to 4-Aminoisoquinolone Derivatives. RSC Adv., 2014, 4(90), 49186?49189. (Accepted: 2014-09-16)
79. Zhuang Yang, Wenshuang Wu, Jingjing Wang, Li Liu, Luyuan Li, Jianhong Yang, Guangcheng Wang, Dong Cao, Ronghong Zhang, Minghai Tang, Jiaolin Wen, Jun Zhu, Wei Xiang, Fang Wang, Liang Ma, Mingli Xiang, Jingsong You, Lijuan Chen.* Synthesis and Biological Evaluation of Novel Millepachine Derivatives As a New Class of Tubulin Polymerization Inhibitors. J. Med. Chem., 2014, 57, 7977?7989. (Publication Date (Web): 2014-09-10)
2013 年
80. Dongbing Zhao, Gaocan Li, Di Wu, Xurong Qin, Patrik Neuhaus, Yangyang Cheng, Shuaijun Yang, Zhiyun Lu, Xuemei Pu, Chao Long, Jingsong You.* Regiospecific N-Heteroarylation of Amidines for Full-Color-Tunable Boron Difluoride Dyes with Mechanochromic Luminescence. Angew. Chem. Int. Ed., 2013, 52 (51), 13676?13680. (Published online: 2013-11-07)
81. Xiaolei Huang, Jingsheng Huang, Chenglong Du, Xingyi Zhang, Feijie Song, Jingsong You.* N-Oxide as a Traceless Oxidizing Directing Group: Mild Rhodium(III)-Catalyzed C–H Olefination for the Synthesis of ortho-Alkenylated Tertiary Anilines. Angew. Chem. Int. Ed., 2013, 52 (49), 12970?12974. (Published online: 2013-11-12)
82. Kaizhi Li, Guangying Tan, Jingsheng Huang, Feijie Song, Jingsong You.* Iron-Catalyzed Oxidative C–H/C–H Cross-Coupling: An Efficient Route to α-Quaternary α-Amino Acid Derivatives. Angew. Chem. Int. Ed., 2013, 52 (49), 12942–12945. (Published online: 2013-09-25)
83. Hongjun Zhou, Yinsong Zhao, Ge Gao,* Shiqing Li, Jingbo Lan, Jingsong You.* Highly Selective Fluorescent Recognition of Sulfate in Water by Two Rigid Tetrakisimidazolium Macrocycles with Peripheral Chains. J. Am. Chem. Soc., 2013, 135(40), 14908?14911. (Publication Date (Web): 2013-09-06)
84. Gaocan Li, Shengyou Qian, Chunxia Wang, Jingsong You.* Palladium(II)-Catalyzed Dehydrogenative Cross-Coupling between Two Csp3–H Bonds: Unexpected C=C Bond Formation. Angew. Chem. Int. Ed., 2013, 52 (30), 7837–7840. (Published online: 2013-06-18)
85. Jiaxing Dong, Zhen Long, Feijie Song, Ningjie Wu, Qiang Guo, Jingbo Lan, Jingsong You. * Rhodium or Ruthenium-Catalyzed Oxidative C–H/C–H Cross-Coupling: Direct Access to Extended π-Conjugated Systems. Angew. Chem. Int. Ed., 2013, 52 (2), 580–584. (Published online: 2012-11-26)
86. Bo Liu, Yumin Huang, Jingbo Lan, Feijie Song, Jingsong You.* Pd-Catalyzed Oxidative C–H/C–H Cross-Coupling of Pyridines with Heteroarenes. Chem. Sci., 2013, 4(5), 2163–2167. (Accepted: 2013-02-21)
87. Xurong Qin, Hu Liu, Dekun Qin, Qian Wu, Jingsong You,* Dongbing Zhao, Qiang Guo, Xiaolei Huang, Jingbo Lan.* Chelation-Assisted Rh(III)-Catalyzed C2-Selective Oxidative C–H/C–H Cross-Coupling of Indoles/Pyrroles with Heteroarenes. Chem. Sci., 2013, 4 (5), 1964–1969. (Accepted: 2013-01-17)
88. Dongbing Zhao, Qian Wu, Xiaolei Huang, Feijie Song, Taiyong Lv, Jingsong You.* A General Method to Diverse Cinnolines and Cinnolinium Salts. Chem. Eur. J.,2013, 19 (20), 6239–6244. (Published online: 2013-03-28)
89. Yuanhong Ma, Jingsong You,* Feijie Song.* Facile Access to 3-Acylindoles through Palladium-Catalyzed Addition of Indoles to Nitriles: The One-Pot Synthesis of Indenoindolones. Chem. Eur. J., 2013, 19 (4), 1189–1193. (Published online: 2012-12-13)
90. Luoqiang Zhang, Shiping Yang, Xiaolei Huang, Jingsong You, Feijie Song.* Aerobic Ru-Catalyzed Direct C2-Olefination of N-Heteroarenes with Alkenes Directed by a Removable N-Dimethylcarbamoyl group. Chem. Commun., 2013, 49 (78), 8830–8832. (Accepted:2013-07-30)
91. Fan Yang, Zhigang Wang, Feijie Song,* Xingyan Liu, Jingbo Lan, Jingsong You.* One-Step Synthesis of Imidazoline-Containing Macrocycles and Their Complexation with Fullerenes C60 and C70. Chem. Commun., 2013, 49 (53), 5975 – 5977 . (Accepted: 2013-05-13)
92. Shuai Zhang, Feijie Song,* Dongbing Zhao, Jingsong You.* Tandem Oxidation–Oxidative C–H/C–H Cross-Coupling: Synthesis of Arylquinones from Hydroquinones. Chem. Commun.,2013, 49 (40), 4558–4560. (Accepted: 2013-03-26)
93. Hongjun Zhou, Zhi Wang, Chao Gao, Jingsong You, Ge Gao.* Synthesis and Characterization of a Luminescent and Fully Rigid Tetrakisimidazolium Macrocycle. Chem. Commun., 2013, 49 (18), 1832–1834. (Accepted: 2013-01-18)
94. Chao Gao, Hongjun Zhou, Siping Wei, Yinsong Zhao, Jingsong You,Ge Gao.* Novel Bisimidazolium Pincers as Low Loading Ligands for in situ Palladium-Catalyzed Suzuki-Miyaura Reaction in Ambient Atmosphere. Chem. Commun., 2013, 49 (11), 1127–1129. (Accepted: 2012-12-17)
95. Xuefeng Cong, Jingsong You, * Ge Gao, Jingbo Lan. * 2-Pyridylmethyl Ether: A Readily Removable and Efficient Directing Group for Amino Acid Ligand Accelerated ortho-C–H Olefination of Phenols. Chem. Commun., 2013, 49 (7), 662–664. (Accepted: 2013-11-05)
96. Qiang Guo, Jiaxing Dong, Danyang Wan, Di Wu,* Jingsong You.* Modular Establishment of Diketopyrrolopyrrole-Based Polymer Library via Pd-Catalyzed Direct C–H (Hetero)arylation: Highly Efficient Approach to Discover Low-Bandgap Polymers. Macromol. Rapid Commun., 2013, 34 (6), 522?527. (Published online: 2013-01-31)
97. Taiyong Lv, Zhi Wang, Jingsong You,* Jingbo Lan, Ge Gao.* Copper-Catalyzed Direct Aryl Quaternization of N-Substituted Imidazoles to Form Imidazolium Salts. J. Org. Chem., 2013, 78 ( 11 ), 5723– 5730. (Publication Date (Web): 2013-05-03)
98. Lipeng Yan, Dongbing Zhao, Jingbo Lan,* Yangyang Cheng, Qiang Guo, Xiaoyu Li, Ningjie Wu, Jingsong You.* Palladium-Catalyzed Tandem N–H/C–H Arylation: Regioselective Synthesis of N-heterocycle-Fused Phenanthridines as Versatile Blue-Emitting Luminophores. Org. Biomol. Chem., 2013, 11(45), 7966–7977. (Accepted: 2013-09-30)
99. Xiaoyu Li, Bijin Li, Jingsong You, Jingbo Lan.* Copper-Catalysed Oxidative C–H/N–H Cross-Coupling between Formamides and Amides Through Chelation-Assisted N–H Activation. Org. Biomol. Chem., 2013, 11 (12), 1925–1928. (Accepted: 2013-02-01)
100.Bijin Li, Xurong Qin, Jingsong You,* Xuefeng Cong, Jingbo Lan.* Direct Arylation of Phenanthroline Derivatives via Oxidative C–H/C–H Cross-Coupling: Synthesis and Discovery of Excellent Ligands. Org. Biomol. Chem., 2013, 11 (8), 1290–1293. (Accepted: 2012-12-20)
101. Fan Yang, Feijie Song,* Wei Li, Jingbo Lan, Jingsong You.* Palladium-Catalyzed C–H Activation of Anilides at Room Temperature: ortho-Arylation and Acetoxylation. RSC Adv. , 2013, 3 (25), 9649– 9652. (Accepted: 2013-04-29)
102.Junyi Hu, Zhen He, Zhi Wang, Xiaoyu Li, Jingsong You, Ge Gao.* A Simple Approach to Aggregation-Induced Emission in Difluoroboron Dibenzoylmethane Derivatives. Tetrahedron Lett., 2013, 54 (32), 4167–4170 . (Accepted: 2013-05-23)
103. Taiyong Lv, Lei Yang, Yinsong Zhao, Feijie Song, Jingbo Lan, Jingsong You,* Ge Gao.* One-Pot Synthesis of Diarylimidazolium Salts from 1 H-Imidazole. Chin . Chem . Lett ., 2013, 24 (9) , 773 – 776. (Accepted: 2013-05-21)
104.  Li Yang,* Guanjun Chang, Liang Luo, Feng Ding, Jingsong You. Distinct Structures of Inorganic–Organic Supramolecular Assemblies Based on Discrete Metallocyclic Complexes Incorporating Fexible Imidazole Ligands: Syntheses, Crystal Structures and Properties. Inorg. Chim. Acta, 2013, 406, 307–314. (Accepted: 2013-07-19)
105.Zhi Wang, Hongjun Zhou, Junyi Hu, Jingsong You,* Ge Gao .* 十字架型间二咪唑(鎓)苯的合成及对有机酸的识别(Bisimidazole and Bisimidazolium Cruciforms: Synthesis and Discrimination of Organic Acids). Acta Chimica Sinica ( 化学学报 ), 2013, 71 (9), 1257– 1264. (Published: 2013-06-27)
106.周红军，兰静波，高戈，游劲松*。咪唑鎓大环的研究进展。《中国科技论文》, 2013, 8 (6), 587–594. (发布时间：2013-01-08)
107.秦绪荣，兰静波，王镇，游劲松*。过渡金属催化的(杂)芳烃C-H/C-H交叉氧化偶联反应进展。中国科技论文在线，201301-281. (发布时间：2013-01-07)
108.杨帅军，兰静波，高戈，游劲松*。有机固体荧光材料研究进展。中国科技论文在线，201301-357. (发布时间：2013-01-08)
2012 年
109.Shuaijun Yang, Jingsong You,* Jingbo Lan, Ge Gao.* Facile Access to Extremely Efficient Energy-Transfer Pairs via an Unexpected Reaction of Squaraines with Ketones. J. Am. Chem. Soc., 2012, 134 (29), 11868–11871. (Publication Date (Web): 2012-06-29)
110. Siping Wei, Xiyu Li, Zhuang Yang, Jingbo Lan, Ge Gao, Ying Xue, Jingsong You.* Ligand-Switching and Counteranion-Induced Hierarchical Self-Assembly of Silver-NHC Complexes. Chem. Sci., 2012, 3 (2), 359–363. (Accepted: 2011-10-05)
111. Zhen Wang, Feijie Song, Yinsong Zhao, Yumin Huang, Lei Yang, Dongbing Zhao, Jingbo Lan, Jingsong You. * Elements of Regiocontrol in the Direct Heteroarylation of Indoles/Pyrroles: Synthesis of Bi- and Fused Polycyclic Heteroarenes via Twofold or Tandem Fourfold C–H Activation. Chem. Eur. J., 2012, 18 (52), 16616–16620. (Published online: 2012-11-29)
112. Bo Liu, Jian Li, Feijie Song, Jingsong You.* Palladium-Catalyzed Direct Arylation of N-Heteroarenes with Arylsulfonyl Hydrazides. Chem. Eur. J., 2012, 18 (35), 10830–10833. (Published online: 2012-07-16)
113. Jiaxing Dong, Yumin Huang, Xurong Qin, Yangyang Cheng, Jing Hao, Danyang Wan, Wei Li, Xingyan Liu, Jingsong You.* Palladium(II)-Catalyzed Oxidative C–H/C–H Cross-Coupling between Two Structurally Similar Azoles. Chem. Eur. J., 2012, 18 (20), 6158–6162. (Published online: 2012-04-04)
114. Bo Liu, Zhi Wang, Ningjie Wu, Mingliang Li, Jingsong You,* Jingbo Lan.* Discovery of a Full-Color-Tunable Fluorescent Core Framework through Direct C–H (Hetero)arylation of N-Heterocycles. Chem. Eur. J., 2012, 18 (6), 1599–1603. (Published online: 2012-01-13)
115. Yumin Huang, Feijie Song, Zhen Wang, Peihua Xi, Ningjie Wu, Zhigang Wang,  Jingbo Lan, Jingsong You.*  Dehydrogenative Heck Coupling of Biologically Relevant N-Heteroarenesswith Alkenes: Discovery of Fluorescent Core Frameworks. Chem. Commun., 2012, 48 (23), 2864-2866. (Accepted: 2012-01-18)
116. Xurong Qin, Boya Feng, Jiaxing Dong, Xiaoyu Li, Ying Xue, Jingbo Lan,* Jingsong You.* Copper(II)-Catalyzed Dehydrogenative Cross-Coupling between Two Azoles. J. Org. Chem., 2012, 77 (17), 7677?7683. (Publication Date (Web): 2012-08-17)
2011 年
117. Zhen Wang, Kaizhi Li, Dongbing Zhao, Jingbo Lan, Jingsong You.* Palladium-Catalyzed Oxidative C–H/C–H Cross-Coupling of Indoles and Pyrroles with Heteroarenes. Angew. Chem. Int. Ed. 2011, 50 (23), 5365–5369. (Published online: 2011-05-05)
118. Dongbing Zhao, Junyi Hu, Ningjie Wu, Xiaolei Huang, Xurong Qin, Jingbo Lan, Jingsong You.* Regiospecific Synthesis of 1,2-Disubstituted (Hetero)aryl Fused Imidazoles with Tunable Fluorescent Emission. Org. Lett., 2011, 13 (24), 6516–6519. (Publication Date (Web): 2011-11-15)
119. Qian Wu, Dongbing Zhao, Xurong Qin, Jingbo Lan, Jingsong You.* Synthesis of Di(hetero)aryl Sulfides by Directly Using Arylsulfonyl Chlorides as a Sulfur Source. Chem. Commun., 2011, 47 (32), 9188–9190.(Accepted: 2011-07-12)
120.Rongqi Zhou, Bijin Li, Ningjie Wu, Ge Gao, Jingsong You, Jingbo Lan.* Cyclen-Functionalized Perylenebisimides as Sensitive and Selective Fluorescent Sensors for Pb 2+ in Aqueous Solution. Chem. Commun., 2011, 47 (23), 6668–6670. (Accepted: 2011-05-11)
121. Xurong Qin, Xuefeng Cong, Dongbing Zhao, Jingsong You, Jingbo Lan.* One-Pot Synthesis of Benzofused Heteroaryl Azoles via Tandem C-Heteroatom Coupling/C–H Activation of Azoles. Chem. Commun., 2011, 47 (19), 5611–5613. (Accepted: 2011-04-08)
122. Bo Liu, Qiang Guo, Yangyang Cheng, Jingbo Lan, Jingsong You.* Palladium-Catalyzed Desulfitative C?H Arylation of Heteroarenes with Sodium Sulfinates. Chem. Eur. J., 2011, 17 (48) , 13415–13419. (Published online: 2011-11-03)
123. Siping Wei, Xi-Guang Wei, Xiaoyu Su, Jingsong You,* Yi Ren.* Insight into the Role of the Counteranion of an Imidazolium Salt in Organocatalysis: A Combined Experimental and Computational Study. Chem. Eur. J., 2011, 17 (21), 5965–5971. (Published online: 2011-04-19)
124.Dongbing Zhao, Jingsong You,* Changwei Hu.* Recent Progress in Coupling of Two Heteroarenes (Invited Review). Chem. Eur. J., 2011, 17 (20), 5466–5492. (Published online: 2011-04-19)
125. Li Yang,Fei Yang,Jingbo Lan,Ge Gao, Jingsong You,*Xiaoyu Su.*Rational Design of BINOL-Based Diimidazolyl Ligands: Homochiral Channel-Like Mono-Component Organic Frameworks by Hydrogen-Bond-Directed Self-Assembly. Org. Biomol. Chem., 2011, 9 (8), 2618–2621. (Accepted: 2011-02-22)
126.罗亮, 李卫, 高戈, 兰静波,* 游劲松 .* 二咪唑-Ag(I)配位聚合物发光凝胶的设计和制备. 高等学校化学学报, 2011, 32 (9), 2091–2096. [Design and Preparation of Fluorescent Bisimidazole-Ag(I) Coordination Polymeric Gel. Chemical Journal of Chinese Universities, 2011, 32 (9), 2091–2096] (出版日期：2011-09-10)
2010 年
127. Peihua Xi, Fan Yang, Song Qin, Dongbing Zhao, Jingbo Lan, Ge Gao, Changwei Hu,* Jingsong You.* Palladium(II)-Catalyzed Oxidative C–H/C–H Cross-Coupling of Heteroarenes. J. Am. Chem. Soc. 2010, 132 (6), 1822–1824. (2010-01-26)
128.Dongbing Zhao, Chao Gao, Xiaoyu Su, Yunqing He, Jingsong You,* Ying Xue.* Copper-Catalyzed Decarboxylative Cross-Coupling of Alkynyl Carboxylic Acids with Aryl Halides. Chem. Commun., 2010, 46 (47), 9049–9051. (2010-11-04)
129.Bo Liu, Xurong Qin, Kaizhi Li, Xiyu Li, Qiang Guo, Jingbo Lan, Jingsong You.* A Palladium/Copper Bimetallic Catalytic System: Dramatic Improvement for Suzuki–Miyaura-Type Direct C–H Arylation of Azoles with Arylboronic Acids. Chem. Eur. J. 2010, 16 (39) , 11836–11839. (2010-09-06)
130. Liwei Yan, Ying Xue, Ge Gao, Jingbo Lan, Fan Yang, Xiaoyu Su, Jingsong You.* Self-Assembly of Discrete Homochiral, Helical, Hydrogen-Bonded Nanocages: From Vesicles to Microspheres and Tubules Capable of Gelating Solvents. Chem. Eur. J. 2010, 16 (7) , 2250–2257 . (2010-01-11)
131. Wenhai Wang, Afu Fu, Jingbo Lan, Ge Gao, Jingsong You,* Lijuan Chen.* Rational Design of Fluorescent Bioimaging Probes by Controlling the Aggregation Behavior of Squaraines: A Special Effect of Ionic Liquid Pendants. Chem. Eur. J., 2010, 16 (17) , 5129–5137 . (2010-03-26)
132. Liang Cheng, Jiaxing Dong, Jingsong You, Ge Gao,* Jingbo Lan.* A Highly syn-Selective Nitroaldol Reaction Catalyzed by CuII-Bisimidazoline. Chem. Eur. J., 2010, 16 (23), 6761–6765. (2010-05-12)
133. Li Yang, Liang Luo, Shuai Zhang, Xiaoyu Su, Jingbo Lan, Chi-Tien Chen, Jingsong You.* Self-assembly From Metal–Organic Vesicles to Globular Networks: Metallogel-Mediated Phenylation of Indole with Phenyl Boronic Acid. Chem. Commun. , 2010, 46 (22), 3938–3940. (2010-04-27)
134. Li Yang, Song Qin, Xiaoyu Su, Fei Yang, Jingsong You,* Changwei Hu, Rugang Xie, Jingbo Lan.* 1,1'-Binaphthyl-Based Imidazolium Chemosensors for Highly Selective Recognition of Tryptophan in Aqueous Solutions. Org. Biomol. Chem., 2010, 8 (2), 339–348. (2009-11-17)
135. Weida Wang, Afu Fu, Jingsong You, Ge Gao, Jingbo Lan,* Lijuan Chen.* Squaraine-Based Colorimetric and Fluorescent Sensors for Cu 2 +-Specific Detection and Fluorescence Imaging in Living Cells. Tetrahedron, 2010, 66 (21), 3695–3701. (2010-03-27)
2009 年
136. Dongbing Zhao, Ningjie Wu, Shuai Zhang, Peihua Xi, Xiaoyu Su, Jingbo Lan, Jingsong You.* Synthesis of Phenol, Aromatic Ether, and Benzofuran Derivatives by Copper-Catalyzed Hydroxylation of Aryl Halides. Angew. Chem. Int. Ed. 2009, 48 (46), 8729?8732. (2009-09-22)
137. Dongbing Zhao, Wenhai Wang, Fei Yang, Jingbo Lan, Li Yang, Ge Gao, Jingsong You.*Copper-Catalyzed Direct C Arylation of Heterocycles with Aryl Bromides: Discovery of Fluorescent Core Frameworks. Angew. Chem. Int. Ed. 2009, 48 (18), 3296?3300. (2009-03-31)
138. Shiyong Zhang, Shuaijun Yang, Jingbo Lan, Yurong Tang, Ying Xue, Jingsong You.* Ultrasound-Induced Switching of Sheetlike Coordination Polymer Microparticles to Nanofibers Capable of Gelating Solvents. J. Am. Chem. Soc. 2009, 131 (5), 1689?1691. (2009-01-21)
139. Dongbing Zhao, Weida Wang, Shuang Lian, Fei Yang, Jingbo Lan, Jingsong You. * Phosphine-Free Palladium-Catalyzed Arylation of Heterocycles through C?H Bond Activation with Pivalic Acid as a Cocatalyst. Chem. Eur. J. 2009 , 15 (6), 1337?1340 . (2008-12-29)
140.Liangbo Zhu, Gaocan Li, Liang Luo, Peng Guo, Jingbo Lan, Jingsong You. * Highly Functional Group Tolerance in Copper-Catalyzed N-Arylation of Nitrogen-Containing Heterocycles under Mild Conditions. J. Org. Chem. 2009, 74 (5), 2200?2202. (2009-02-05)
141. Siping Wei, Bo Liu, Dongbing Zhao, Zhen Wang, Jie Wu, Jingbo Lan, Jingsong You. * Pyrido[1,2- c][1,2,4]triazol-3-ylidene: Reactivity and its Application in Organocatalysis and Organometallic Catalysis. Org. Biomol. Chem. 2009, 7 (20), 4241?4247. (2009-08-07)
142.Yuanyuan Zhang, Xiang Chen, Jingbo Lan, Jingsong You, * Lijuan Chen. * Synthesis and Biological Applications of Imidazolium-Based Polymerized Ionic Liquid as a Gene Delivery Vector. Chem Biol Drug Des 2009, 74 (3), 282?288. (2009-08-17)
143. Shiyong Zhang, Yurong Tang, Ying Su, Jingbo Lan, Rugang Xie, Jingsong You. * Discrete Metallocyclic Complexes Based on Rigid Pyrazole-Containing Ligands as Building Blocks to Construct Inorganic-Organic Supramolecular Assemblies through the Second Interactions. Inorg. Chim Acta 2009, 362 (5), 1511?1518. (2008-07-23)
144.Liwei Yan, Li Yang, Jingbo Lan, Jingsong You. * A New Perylene Diimide-Based Colorimetric and Fluorescent Sensor for Selective Detection of Cu 2+ Cation. Science in China Series B: Chemistry 2009 , 52 (4) , 518?522 . (2008-12-17)
2008 年
145.Fei Yang, Dongbing Zhao, Jingbo Lan, Peihua Xi, Li Yang, Shuhuai Xiang, Jingsong You.* Self-Assembled Bifunctional Catalysis Induced by Metal Coordination Interactions: An Exceptionally Efficient Approach to Enantioselective Hydrophosphonylation. Angew. Chem. Int. Ed. 2008, 47 (30), 5646?5649. (2008-06-20)
146.Liwei Yan, Zhen Wang, Ming-Tsz Chen, Ningjie Wu, Jingbo Lan, Xin Gao, Jingsong You, * Han-Mou Gau, Chi-Tien Chen. Preferential Formation of Homochiral Helical Sandwich-Shaped Architectures through Metal-Mediated Assembly of Tris(imidazoline) Ligands with a Set of d 3-d 10 Transition-Metal Ions. Chem. Eur. J. 2008, 14 (36), 11601?11609. (2008-11-14)
147.Shiyong Zhang, Shengyong Yang, Jingbo Lan, Shuaijun Yang, Jingsong You. * Helical Nonracemic Tubular Coordination Polymer Gelators from Simple Achiral Molecules. Chem. Commun. 2008, (46), 6170?6172. (2008-10-16)
148.Guangtu Wang, Lanlan Li, Jingbo Lan, Lijuan Chen, Jingsong You. * Biomimetic Crystallization of Calcium Carbonate Spherules Controlled by Hyperbranched Polyglycerols. J. Mater. Chem. 2008, 18 (24), 2789?2797. (2008-04-14)
149.Fei Yang, Siping Wei, Chien-An Chen, Peihua Xi, Li Yang, Jingbo Lan, Han-Mou Gau, * Jingsong You. * A New Strategy for Designing Non-C 2-Symmetric Monometallic Bifunctional Catalysts and Their Application in Enantioselective Cyanation of Aldehydes. Chem. Eur. J. 2008, 14 (7), 2223?2231. (2008-01-09)
150.Shiyong Zhang, Jingbo Lan, Zhihua Mao, Rugang Xie, Jingsong You. * Crystal Water-Dependent Formation of One-Dimensional Channel Structure Based on 4,4'-Bis(1-imidazolyl)biphenyl. Cryst. Growth Des. 2008, 8 (9), 3134?3136 . (2008-08-19)
151. Yajun Ma, Siping Wei, Jingbo Lan, Jingzhi Wang, Rugang Xie, Jingsong You. * Pyrido[1,2-a][1,2,4]triazol-3-ylidenes as a New Family of Stable Annulated N-Heterocyclic Carbenes: Synthesis, Reactivity and Their Application in Coordination Chemistry and Organocatalysis. J. Org. Chem. 2008, 73 (21), 8256?8264. (2008-10-10)
152. Yajun Ma, Siping Wei, Jie Wu, Fei Yang, Bo Liu, Jingbo Lan, Shengyong Yang, Jingsong You. * From Mono-Triazolium Salt to Bis-triazolium Salt: Improvement of the Asymmetric Intermolecular Benzoin Condensation. Adv. Syn. Catal. 2008, 350 (16), 2645?2651. (2008-10-16)
153. Jihong Li, Wenhai Wang, Jingbo Lan,* Jingsong You. ( S)- N-(1-Hydroxymethyl-2-methylprop-yl)-2-methoxybenzamide. Acta Cryst. 2008, E64 (6), o1052. (2008-05-10)
2007 年
154. Wen Chen, Yuanyuan Zhang, Liangbo Zhu, Jingbo Lan, Rugang Xie, Jingsong You.* A Concept of Supported Amino Acid Ionic Liquids and Their Application in Metal Scavenging and Heterogeneous Catalysis. J. Am. Chem. Soc. 2007, 129 (45), 13879–13886. (2007-10-17)
155. Liangbo Zhu, Peng Guo, Gaocan Li, Jingbo Lan, Rugang Xie, Jingsong You. * Simple Copper Salt-Catalyzed N-Arylation of Nitrogen-Containing Heterocycles with Aryl and Heteroaryl Halides. J. Org. Chem. 2007, 72 (22), 8535–8538. (2007-09-29)
156.Fei Yang, Peihua Xi, Li Yang, Jingbo Lan, Rugang Xie, Jingsong You. * Facile, Mild and Highly Enantioselective Alkynylzinc Addition to Aromatic Aldehydes by BINOL/N-Methylimidazole Dual Catalysis. J. Org. Chem. 2007, 72 (14), 5457–5460. (2007-06-08)
157. Kuoyan Ma, Jingsong You. * Rational Design of Sterically and Electronically Easily Tunable Chiral Bis-imidazolines and Their Applications in Dual Lewis Acid/Brφsted Base Catalysis for Highly Enantioselective Nitroaldol (Henry) Reactions. Chem. Eur. J. 2007, 13 (6), 1863–1871. (2006-11-22)
158. Liangbo Zhu, Liang Cheng, Yuxi Zhang, Rugang Xie, Jingsong You. * Highly Efficient Copper-Catalyzed N-Arylation of Nitrogen-Containing Heterocycles with Aryl and Heteroaryl halides. J. Org. Chem. 2007, 72 (8), 2737–2743 . (2007-03-10)
159. Wen-Hai Wang, Pei-Hua Xi, Xiao-Yu Su, Jingbo Lan, Zhi-Hua Mao, Jingsong You, * Ru-Gang Xie. Supramolecular Assemblies of Multifunctional Diimidazole and Dicarboxylic Acids via Various Hydrogen Bonds and X???π (X = π, CH) Interactions. Cryst. Growth Des. 2007, 7 (4), 741–746 . (2007-01-14)
160. Qing-Xiang Xiang,* Xiao-Qi, Yu, Li-Quna, Zhang, Jing-Song You, Ru-Gang Xie. 新型两亲性大环多胺的合成(Synthesis of Novel Amphipathic Macrocyclic Polyamines).《有机化学》, 2007, 27 (7), 890–892. (2007-02-02)
2006 年
161. Fei Yang, Liwei Yan, Kuoyan Ma, Li Yang, Jihong Li, Jingsong You.* Efficient Synthesis of a Variety of New Functionalized Oxacalixarenes Promoted by Ullmann Coupling Reactions. Eur. J. Org. Chem., 2006, 1109–1112. (2006-01-12)
162.Min Yang, Qianrong Peng, Guangfu Song, Jingbo Lan, Dongshan Wang, Jingsong You, Rugang Xie.* The Allylic Oxidation of Ionone-Like Dienes by Nanoscale Copper Catalyst in Imidazolium Ionic Liquids. Lett. Org. Chem., 2006, 3 (12), 926–931. (2006-12-01)
163. Kui Luo, He-yan Jiang, Jin-song You, Qin-xiang Xiang, Sheng-jin Guo, Jing-bo Lan, Ru-gang Xie.* Chiral Di-imidazolium Molecular Tweezers: Synthesis and Enantioselective Recognition for Amino Acid Derivatives. Lett. Org. Chem. , 2006, 3 (5), 363–367. (2006-05-01)
164.Wenhai Wang, Xiaoyu Su, Zhihua Mao, Jingsong You, Rugang Xie. Hexakis(1-methyl-1H-imidazole-κN3)nickel(II) Dichloride Dihydrate. Acta Crystallogr. Sect. E: Struct. Rep. Online, 2006, 62 (3), m445–m447.
165.Kuoyan Ma, Liang Cheng, Han-Mou Gau*, Jingsong You*, A New Chiral Ligand: 2,6-Bis[4(S)-isopropyl-1-phenyl-4,5-dihydro-1H-imidazol-2-yl]- pyridine. Acta Crystallogr. Sect. E: Struct. Rep. Online,2006.  62 (4), o1595–o1597. (2006-3-16)
2005 年
166. Lijian Ma, Guolin Zhang, Shanyong Chen, Bo Wu, Jingsong You, Chuanqin Xia, Xiaoqi Yu.* The First Synthesis of Chiral PNA Monomer-cyclen Conjugates. J. Peptide. Sci., 2005, 11 (12), 812–817. (2005-3-1)
167. Li Sun, Canping Du, Jie Qin, Jingsong You*, Meng Yang, Xiaoqi Yu.* Highly Diastereoselective Epoxidation of Protected α-Amino Alkenes Catalyzed by Ruthenium Porphyrin/Cl 2PyNO System. J. Mol. Catal. A: Chem.,2005, 234, 29–34. (2005-2-19)
168. Haihua Zou, Jian Hu, Ji Zhang, Jingsong You, Dan Ma, Ding Lü,* Rugang Xie.* Asymmetric Reduction of Prochiral Ketones with Borane Using Chiral Squaric Amino Alcohols Derived from Camphor as Catalysts. J. Mol. Catal. A: Chem., 2005, 242, 57–61. (2005-7-19)
169. Shiyong Zhang, Jingbo Lan, Xiaoyu Su, Shengjin Guo, Li Chen, Jingsong You, Rugang Xie. Aerobic oxidative coupling of 2-naphthols by simple copper salts. A Highly Efficient Catalytic System in The Absence of Ligand or Carrier. J. Chem. Res., 2005, (7), 418–419.
2004 年
170. Jingbo Lan, Li Chen, Xiaoqi Yu,* Jingsong You, Rugang Xie.* A Simple Copper Salt Catalysed The Coupling of Imidazole with Arylboronic Acids in Protic Solvent. Chem. Commun., 2004, (2), 188–189. (2003-11-11)
171. Jingbo Lan, Guolin Zhang, Xiaoqi Yu*, Jingsong You, Li Chen, Mei Yan, Rugang Xie.* A Simple Copper Salt Catalyzed N-Arylation of Amines, Amides, Imides, and Sulfonamides with Arylboronic Acids. Synlett, 2004, (6), 1095–1097. (2004-03-25)
172. Jingsong You, Andrzej E. Wróblewski, John G. Verkade.* P[( S,S,S)-CH 3NCH(CH 2Ph)CH 2] 3N: a New C3-Symmetric Enantiomerically Pure Proazaphosphatrane. Tetrahedron, 2004, 60 (36), 7877–7883. (2004-06-10)
173. Runhua Li, Yuancong Zhao, Jiang Wu,* Jingsong You, Xiaoqi Yu.* Octopus Manganese Porphyrin with Polyglycol Chains as A Catalyst for The β-Selective Epoxidation of Cholesterol Derivatives. Chin. Chem. Lett., 2004, 15 (8), 915–918. (2003-09-23)
174. 兰静波，苏晓渝，游劲松，余孝其*，谢如刚*。简单铜盐催化的芳基二硼酸与咪唑的偶联反应。《有机化学》, 2004, 24, 243–254.
175. 兰静波，王涛，向清祥，游劲松，余孝其*，谢如刚*。手性联二萘咪唑鎓环番的对映选择性识别性能研究。《有机化学》, 2004, 24, 255–256.
2003 年
176. Jingsong You, John G. Verkade.* A General Method for the Direct α-Arylation of Nitriles with Aryl Chlorides. Angew. Chem. Int. Ed., 2003, 42, 5051–5053. (2003-05-22)
177. Jingsong You, Hans-Joachim Drexler, Songlin Zhang, Christine Fischer, Detlef Heller.* Preparation and Asymmetric Hydrogenation of β-Aryl-Substituted β-Acylaminoacrylates. Angew. Chem. Int. Ed., 2003, 42 (8), 913–916. (2002-09-20)
178. Jingsong You, Juhua Xu, and John G. Verkade.* A Highly Active and Selective Catalyst System for the Baylis–Hillman Reaction. Angew. Chem. Int. Ed. 2003, 42, 5054–5056. (2003-06-26)
179. Jingsong You, John G. Verkade.* P( i-BuNCH 2CH 2) 3N: An Efficient Ligand for the Direct α–Arylation of Nitriles with Aryl Bromides. J. Org. Chem., 2003, 68 (21), 8003–8007. (2003-06-06)
180. Barbara Heller,* Bernd Sundermann, Christine Fischer, Jingsong You, Waiqiang Chen, Hans-Joachim Drexler, Paul Knochel, Werner Bonrath, Andrey Gutnov. Facile and Racemization-Free Conversion of Chiral Nitriles into Pyridine Derivatives. J. Org. Chem., 2003, 68 (24), 9221–9225. (2003-06-23)
181. Jens Holz,* Axel Monsees, Haijun Jiao, Jinsong You, Igor V. Komarov, Christine Fischer, Karlheinz Drauz, and Armin Börner.* Synthesis of a new chiral bisphospholane ligand for the Rh(I)-catalyzed enantioselective hydrogenation of isomeric beta-acylamido acrylates. J. Org. Chem., 2003, 68(5), 1701-1707. (2003-03-07)
182. Jingsong You, Xiaoqi Yu*, Xiaoyu Su, Tao Wang, Qingxiang Xiang, Meng Yang, Rugang Xie.* Hydrolytic Metalloenzyme Models. Enantioselective Hydrolysis of Long Chain α-Amino Acid Esters by Chiral Metallomicelles Composed of Lipophilic L-Histidinol. J. Mol. Cataly. A: Chem., 2003, 202, 17–22. (2003-01-13)
183. Canping Du, Jingsong You, Xiaoqi Yu, Changlu Liu, Jingbo Lan, Rugang Xie.* Homochiral Molecular Tweezers as Hosts for The Highly Enantioselective Recognition of Amino Acid Derivatives. Tetrahedron: Asymmetry, 2003, 14 (23), 3651–3656. (2003-09-04)
184. Hans-Joachim Drexler, Jingsong You, Songlin Zhang, Christine Fischer, Wolfgang Baumann, Anke Spannenberg, Detlef Heller.* Chiral α-Amino Acid Derivatives via Asymmetric Hydrogenation. Org. Process Res. Dev., 2003, 7 (3), 355–361. (2003-01-13)
185. 兰静波，陈丽，游劲松，余孝其，谢如刚*。咪唑自催化的与芳基硼酸的氧化偶联反应。《有机化学》, 2003, 23, 225.
186. 陈丽，兰静波，游劲松，余孝其，谢如刚*。一种新型2-萘酚氧化偶联合成联萘酚的催化体系。《有机化学》, 2003, 23, 227.
2002 年
187. Detlef Heller*, Hans-Joachim Drexler, Anke Spannenberg, Barbara Heller, Jingsong You, Wolfgang Baumann.* The Inhibiting Influence of Aromatic Solvents on the Activity of Asymmetric Hydrogenations. Angew. Chem. Int. Ed., 2002, 41 (5), 777–780. (2001-10-19)
188. Detlef Heller,* Hans-Joachim Drexler, Jingsong You, Wolfgang Baumann, Karlheinz Drauz, Hans-Peter Krimmer, Armin Börner.* On the Enantioselective Hydrogenation of Isomeric Methyl 3-Acetamidobutenoates with Rh I Complexes. Chem. Eur. J., 2002, 8 (22), 5196–5203. (2002-03-14)
189. Barbara Heller,* Bernd Sundermann, Helmut Buschmann, Hans-Joachim Drexler, Jingsong You, Ulrike Holzgrabe, Eberhard Heller, Günther Oehme. Photocatalyzed [2+2+2]-Cycloaddition of Nitriles with Acetylene: An Effective Method for the Synthesis of 2-Pyridines under Mild Conditions. J. Org. Chem., 2002, 67 (13), 4414–4422. (2001-10-26)
190. Qingxiang Xiang, Xiaoqi Yu*, Xiaoyu Su, Qianshun Yan, Tao Wang, Jingsong You, Rugang Xie.* Phosphodiester Hydrolysis by Metal Ion Macrocyclic Dioxotetraamine Complexes Bearing Alcohol Pendant in Comicellar Solution. J. Mol. Catal. A: Chem., 2002, 187 (2), 195–200. (2002-04-30)
191. Detlef Heller,* Jens Holz, Igor Komarov, Hans-Joachim Drexler, Jingsong You, Karheinz Drauzb, Armin Börner.* On The Enantioselective Hydrogenation of Isomeric β-Acylamido β-Alkylacrylates with Chiral Rh(I) Complexes–Comparison of Phosphine Ligands and Substrates. Tetrahedron: Asymmetry, 2002, 13, 2735–2741. (2002-11-04)
192. Yi Yuan, Ge Gao, Zong-Lin Jiang, Jin-Song You, Zhong-Yuan Zhou, De-Qi Yuan, Ru-Gang Xie.* Synthesis and Selective Anion Recognition of Imidazolium Cyclophanes. Tetrahedron, 2002, 58(44), 8993-8999. (2002-10-28)
193. Yi Yuan, Zonglin Jiang, Ge Gao, Guolin Zhang, Jingsong You, Rugang Xie.* New Host Molecules with Imidazoliums as Functional Arms: Syntheses and Anion Recognition. Chin. J. Chem., 2002, 20 (5), 447–452. (2001-12-17)
194. Ge Gao, Rong Xiao, Yi Yuan, Chenghe Zhou, Jingsong You, Rugang Xie. Efficient Imidazolium Catalysts for The Benzoin Condensation. J. Chem. Res., Synop., 2002, 2002 (6), 262–263. (2002-06-01)
195. Yi Yuan, Rong Xiao, Ge Gao, Xiaoyu Su, Hua Yu, Jingsong You, Rugang Xie. A Direct Synthetic Approach to Tripodal Imidazole Compounds. J. Chem. Res., 2002 , 2002 (6), 267–269.
196. Tao Wang, Qingxiang Xiang, Zhengkai Li, Jingsong You, Xiaoqi Yu,* Qianshun Yan, Rugang Xie. 环肽研究新进展(Progress in Cyclopeptides Research). 《化学研究与应用》, 2002, 14 (1), 3–8. (2001-03-02)
2001 年
197.  Jingsong You, Xiaoqi Yu, Guolin Zhang, Qingxiang Xiang, Jingbo Lan, Rugang Xie.* Novel Chiral Imidazole Cyclophane Receptors: Synthesis and Enantioselective Recognition for Amino Acid Derivatives. Chem. Commun., 2001, (18), 1816–1817. (2001-07-31)
198.  Jingsong You, Sheng-Hsiang Hsieh, Han-Mou Gau.* Asymmetric Trialkylaluminum Addition to Aldehydes Catalyzed by Titanium Complexes of N-Sulfonylated Amino Alcohols with Two Stereogenic Centers., Chem. Commun., 2001, (17), 1546–1547. (2001-06-20)
199.  Jingsong You, Mingyuan Shao, Han-Mou Gau.* Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Titanium(IV) Complexes of N-Sulfonylated Amino Alcohols with Two Stereogenic Centers. Tetrahedron: Asymmetry, 2001, 12 (21), 2971–2975. (2001-11-10)
200. Qingxiang Xiang, Xiaoqi Yu,* Jingsong You, Qianshun Yan, Rugang Xie.* Catalytic Hydrolysis of Phosphate Diester with Metal Complexes of Macrocyclic Tetraamine in Comicellar Solution. Chin. J. Chem. 2001, 19 (2), 158–163. (2000-9-19)
201. Xiaoqi Yu,* Qingxiang Xiang, Xiaoyu Su, Jingsong You, Rugang Xie.* 金属胶束超分子体系研究新进展(Recent Advances in Metallomicellar Supramolecular Systems). 《有机化学》, 2001, 21 (11), 1029–1039. (2001-9-17)
202. Qingxiang Xiang, Jingsong You, Li Liu, Xiaoqi Yu, Rugang Xie.* 大环多胺的超分子识别作用(Supramolecular Recognition Action in Macrocyclic Polyamine). 《有机化学》, 2001, 21 (8), 557–563. (2001-2-15)
203. Qianshun Yan, Jingsong You,* Qingxiang Xiang, Xiaoqi Yu, Rugang Xie. 新型手性脂质性酰胺型大环多胺配体的合成(Synthesis of New Chiral Lipophilic Macrocyclic Oxo Polyamines). 《化学研究与应用》, 2001, 13 (2), 189–191. (2001-3-1)
204. Yi Liu, Qingxiang Xiang, Jingsong You, Xiaoqi Yu,* Rugang Xie.* 双核配合物作为人工酶的新进展(Advances in The Artificial Hydrolysis Enzyme Model of Dinunclear Complexes). 《化学研究与应用》, 2001, 13 (6), 605–610. (2000-11-15)
2000 年
205. Jingsong You, Han-Mou Gau,* Michael C. K. Choi*, Development of A Family of β-Amino Alcohol Ligands with Two Stereocenters for Highly Efficient Enantioselective Trimethylsilylcyanation of Aldehydes. Chem. Commun., 2000, (19), 1963–1964. (2000-8-30)
206. Jingsong You, Mingyuan Shao, Han-Mou Gau.* Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Titanium(IV) Complexes of Diol Derivatives of D-Mannitol and the Spectroscopic Study of the Catalytic System, Organometallics, 2000, 19 (17), 3368–3373. (2000-3-28)
207. Qianshun Yan, Qingxiang Xiang, Jingsong You, Xiaoqi Yu.* 手性N-长链脂肪酰基氨基酸对硝基酚酯的合成(Synthesis of Chiral N-Long Liphophilic Amine-Acid- p-Nitrophenyl Esters).《化学研究与应用》, 2000, 12 (6), 658–660. (2000-7-7)
208. Jui-Feng Lu, Jing-Song You, Han-Mou Gau.* Enantioselective Addition of AlEt3 to Aldehydes Catalyzed by Titanium(IV)-TADDOLate Complex. Tetrahedron-asymmetry, 2000, 11(12), 2531-2535. (2000-6-30)
1999 年
209. Jingsong You, Xiaoqi Yu, Ke Liu, Lin Tao, Qingxiang Xiang, Rugang Xie.* Synthesis of Novel Chiral Lipophilic Pyridyl-Containing β-Amino Alcohol Ligands and Enantioselective Hydrolysis of α-Amino acid Esters by Chiral Metallomicelles. Tetrahedron: Asymmetry, 1999, 10, 243–254. (1998-12-17)
210. Jingsong You, Xiaoqi Yu, Changlu Liu, Rugang Xie.* Synthesis of New Cheral Macrocyclic Tetraoxo Polyamines Containing Pyridine Ring and Functional Arms. Synthetic Commun., 1999, 29 (14), 2447–2455. (2007-9-17)
211. Qingxiang Xiang, Xiaoqi Yu,* Jingsong You, Qianshun Yan, Rugang Xie. 化学核酸酶研究新进展(Advances in Chemical Nuclease). 《化学研究与应用》, 1999, 11 (1), 1–7. (1998-9-15)
212. Rugang Xie, Xiaoyu Su, Jingsong You. 咪唑环番仿生新体系研究进展 (Progress on Biomimetic System of Novel Imidazole Cyclophane). 《化学研究与应用》, 1999, 11 (5), 449–451.
213. 向清祥，余孝其，游劲松，谢如刚*。含吡啶环单功能臂大环多胺的合成。《厦门大学学报（自然科学版）》，1999, 38, 447.
1998 年
214. Jingsong You, Xiaoqi Yu, Xingshu Li, Qianshun Yan, Rugang Xie.* Enantioselective Hydrolysis of Long Chain α-Amino Acid Esters by Chiral Sulfur-Containing Macrocyclic Metallomicelles. Tetrahedron: Asymmetry, 1998, 9, 1197–1203. (1998-02-20)
215. Jingsong You, Xiaoqi Yu, Xiaoling Zhang, Rugang Xie.* Enantioselective Hydrolysis of α-Amino Acid Ester by Chiral Metallomicelles. Chin. Chem. Lett. 1998, 9 (4), 335–337. (1997-11-11)
216. Xiaoqi Yu,* Jingsong You, Qingxiang Xiang, Qianshun Yan, Rugang Xie. Catalytic Hydrolysis of Lipophilic Amino Acid Esters by Metallomicelles as Carboxypeptidase A Models. Chin. Chem. Lett. 1998, 9 (8), 731–732. (1998-05-12)
217. Guangrong Kuang, Xingshu Li, Yucai Zhen, Lianhong Chen, Chunhua Li, Rugang Xie, Jingsong You. 硒酵母制备中添加不同硒化物对酵母中硒含量的影响 (Effect of Different Selenium Compounds on the Content of Selenium in Yeast). 《西南民族学院学报 · 自然科学版》, 1998, 24 (3), 280–282. (1998-05-04)
1997 年
218. Xiaoling Zhang, Jingsong You, Xingshu Li, Rugang Xie.* Synthesis of New Sulfur-containing Chiral Macrocyclic Ligands. Chin. Chem. Lett. 1997, 8 (10), 853–854. (1997-06-23)
219. Xiaoqi Yu,* Jingsong You, Ying Li, Youfa Xiao, Zhongwei Lan. 疏水性金属卟啉的合成及催化性能研究(Synthesis and Catalytic Performance of Hydrophobic Metalloporphyrins). 《有机化学》, 1997, 17 (2), 153–158. (1996-01-30)
220. 游劲松，余孝其，闫乾顺，谢如刚。手性金属胶束仿酶研究（II）两亲性手性酰胺型大环多胺的合成。《合成化学》, 1997, 716 . (1996-07-15)
221. Xiaoqi Yu, Jingsong You, Youfa Xiao, Zhongwei Lan, Rugang Xie. 金属胶束(Metallomicelles)——一类新的金属酶模型 (Metallomicelles—A New Type of Metalloenzyme Models). 《化学研究与应用》, 1997, 9 (3), 219–225. (1996-09-28)
1996 年
222. Jingsong You,* Youfa Xiao, Xiaoqi Yu, Aixia Cheng, Zhongwei Lan. Epoxidation of Styrene Catalyzed by Manganese(III) Porphyrins Supported on Chloromethylated Polystyrene Resin Bearing Crown Ether Groups. Chin. J. Chem., 1996, 14 (4), 303–309. (1995-12-18)
223. Jingsong You,* Xiaoqi Yu, Youfa Xiao, Yiliang Wu, Zhongwei Lan. Epoxidation of Olefins with Iodosylbenzene Catalyzed by Polymer-supported Manganese Porphyrins. Chin. Chem. Lett,. 1996, 7 (4), 329–332. (1994-10-17)
224. 游劲松，蓝仲薇，余孝其。负载化金属卟啉研究进展。《石油化工》, 1996, 25 (1), 56–61. (1996-01-28)
225. Jingsong You, Xiaoqi Yu,* Youfa Xiao, Zhongwei Lan. 高分子负载Mn(Ⅲ)卟啉/PhIO体系催化烯烃环氧化反应研究(Epoxidation of Olefin with Iodosylbenzene Catalyzed by Polymer-supported Manganese(Ⅲ) Porphyrins). 《分子催化》, 1996, 10 (3), 165–170. (1995-10-20)
226. Youfa Xiao, Jingsong You, Xiaoqi Yu, Xiaohua Yu, Zhongwei Lan. 长链烷氧基取代金属卟啉/H 2O 2体系催化烯烃环氧化反应研究(Epoxidation of Styrene with Hydrogen Peroxide Catalyzed by Long Chain Alkoxyl-Substituted Metalloporphyrins). 《化学研究与应用》, 1996, 8 (2), 270–272. (1995-08-10)
227. Youfa Xiao, Jingsong You, Xiaoqi Yu, Yiliang Wu, Zhongwei Lan. 高分子负载锰卟啉的合成及其催化烯烃环氧化反应研究 (Study on Synthesis of Polymer-supported Manganese(Ⅲ) Porphyrins and Catalyzed Olefin Epoxidation). 《化学研究与应用》, 1996, 8 (3), 376–380. (1995-08-15)
1995 年
228. Xiaoqi Yu,* Zhongwei Lan, Tingxian Wei, Jingsong You, Huaming Zhao. Epoxidation of Styrene Catalyzed by Polymer-supported Metalloporphyrins. Chinese Chem. Lett., 1995, 6 (2), 149–152. (1994-09-23)
229. Zhongwei Lan,* Jiangtao Chen, Jingsong You, Huaming Zhao. 长链烷氧取代金属卟啉的合成及催化性能研究(Synthesis and Catalytic Efficiency of Long Chain Alkoxyl-substitued Metalloporphyrins). 《有机化学》 , 1995, 15 (1), 47–51. (1994-07-11)
230. Xiaoqi Yu,* Tingxian Wei, Zhongwei Lan, Jingsong You, Huaming Zhao. 键联聚乙二醇高分子担载锰(Ⅲ)卟啉的合成及催化烯烃环氧化反应性能研究(Synthesis and Catalytic Performance of Polymer-Supported Metalloporphyrins Bearing Polyglycol Chains). 《分子催化》, 1995, 9 (4), 244–250. (1995-03-14)
231. Zhongwei Lan, Jiangtao Chen, Xiaoqi Yu, Jingsong You.冠醚-卟啉锰催化剂的制备及其催化性能研究(Study on the Synthesis and Catalytic Activity of Mn(Ⅲ) Complexes of New “Crowned” Porphyrins). 《分子催化》, 1995, 9 (4), 291–297. (1995-01-10)
二、授权专利
1. 胡国宜、胡雪明、周国平、游劲松、兰静波：2,4,4'-三硝基苯甲酰苯胺的制备方法，中国，专利号：CN102633674B，授权日期: 2014-05-07, 申请日期2012-03-27. IPC 分类号 : C07C231/02; C07C233/66.
2.  游劲松、闵雪锋、胡国宜、李开治、兰静波、丁志伟：吲哚-4-甲醛的制备方法, 中国，专利号：CN102351774A，授权日期: 2014-01-17。申请日期2011-08-31. IPC 分类号 :  C07D209/08.
3.  游劲松、闵雪锋、吴建华、胡国宜、兰静波、屈季春、吴宁捷：双（对氨基苯氧基）烷烃的制备方法，中国，专利号CN102381985B，授权日期：2014-03-26, 申请日期 2011-08-31。 IPC 分类号 : C07C217/84; C07C213/02
4.  游劲松、闵雪锋、胡国宜、兰静波、吴建华、杨状、杨磊：2-苯基-4,4’-二氨基二苯醚的制备方法，中国，专利号：CN102276484B (ZL201110254946.7)，授权日期：2013-12-18, 申请日期 2011-08-31. IPC 分类号 : C07C213/02; C07C217/90.
5. 胡国宜、薛建伟、闵雪锋、缪文宏、杨飞、游劲松、兰静波：2,2’-双(三氟甲基)-4,4’-二氨基联苯的制备方法，中国，专利号CN101525294B (ZL20091 0029005.6)，授权日期: 2013-02-27。申请日期2009-01-20. IPC 分类号 : C07C209/54; C07C211/52.
6. 胡国宜、薛建伟、闵雪锋、缪文宏、杨莉、杨飞、游劲松、兰静波：N,N’ –二(4-乙氧基羰基苯基)-N’-苄基甲脒的制备方法，中国，专利号CN101481331B (ZL200910029007.5)，授权日期: 2013-2-13。申请日期2009-01-20. IPC 分类号 : C07C249/00; C07C257/12.
7. 胡国宜、丁志伟、缪文宏、闵雪峰、周国平、丛雪丰、游劲松、兰静波：制备4,4’-二苯醚二甲酸的方法，中国，专利号CN101774909B (ZL201010113376.5)，授权公告日2012-10-3。申请日期2010-02-24. IPC 分类号 : C07C51/265; C07C65/24.
8. Heller, D.; Drexler, H.-J.; You, J.; Zhang, S: E-isomeric b-Aromatic or Heteroaromatic Substituted b-Acylamino-Acrylates and Methods of Preparing the Same: WO 2004011414 A1, 授权日期2004-02-05. 申请日期2002-07-26. IPC: C07C229/34; C07C233/47; (IPC1-7): C07C231/02.
9. 吴迪、郭强、游劲松、董嘉兴：一类双噻吩基吡咯并[3,4-c]吡咯-1,4-二酮与（杂）芳烃共聚物的制备方法，中国，专利号：CN103012751A (ZL201210502479.X)，授权日期: 2015-05-20。申请日期 2012-11-30。IPC分类号: C08G61/12.
10.  游劲松、李开治、吴迪、郭强、兰静波、高戈：基于非贵金属催化的C–H/C–H氧化偶联反应高效制备β-(杂)芳基丙氨酸衍生物的方法，中国，专利号: CN104788331A；公开（公告）号 : CN104788331B；公开（公告）日 : 2016-05-04；专利号：ZL 201510189661.8，授权日期 :2016-07-22，申请日期2015-04-21. IPC 分类号 : C07C229/36; C07C269/00; C07C271/22; C07C227/20.
11. 胡国宜、胡雪明、周国平、游劲松、兰静波：2-(对氨基苯基)-5-氨基苯并咪唑的精制方法，中国，公开号CN102603648B，授权日期 2016-04-13，申请日期 2012-03-27。 IPC 分类号 : C07D235/18
12. 王镇, 赵东兵, 王韦达, 兰静波, 游劲松: (6R)-四氢生物喋呤盐酸盐的制备方法， PCT（国际），WO2010CN01836, 申请日期2010-11-15, 授权日期2012-04-19. IPC: C07D475/04
13. 胡国宜、金晓贤、闵雪锋、胡雪明、李高参、董嘉兴、游劲松、兰静波：N-(4-乙氧基羰基苯基)-N’-甲基-N’-苯基甲脒的制备方法，中国，公开号 : CN102060734A，授权日期2015-05-20，申请日期 2011-01-14。 IPC 分类号 : C07C257/12
14.  游劲松、郭强、秦绪荣、兰静波、吴迪、高戈：基于铑催化的C–H/C–H氧化偶联反应高效制备双(杂)芳环并吡喃酮/环戊酮衍生物的方法，中国，专利公开号-: CN201410503476；专利号：ZL 201410503476.7，授权日期 2016-08-17，申请日期: 2014-09-28。 IPC 分类号 : C07D493/04; C07D333/78; C07D495/04; C07D495/14.
15.  游劲松、李必进、兰静波、吴迪、高戈：基于过渡金属催化的C–H/C–H氧化偶联反应高效制备邻羟基苯基杂环类衍生物的方法，中国，专利申请号: 201510217606.5，申请日期:2015-05-04；公开（公告）号 : CN104829550A；公开（公告）日 : 2015.08.12；授权号：ZL 201510217606.5；授权日期 2016-10-05。IPC分类号: C07D263/57; C07J43/00; C07D413/04
16. 高戈、李世清、杨帆、游劲松、兰静波、宋飞杰：由硼酸制备咪唑类鎓盐的新方法，中国，专利申请号201410026715.4，申请日期 2014-01-21；公开（公告）号 : CN103755638A；公开（公告）日 : 2014-04-30；授权号：证书尚未到手；授权日期 :2016-9-14。 IPC 分类号 : C07D233/58; C07D409/14; C07D487/04; C07D471/04; C07D235/06
17. 胡锦平、胡国宜、吴建华、游劲松、兰静波、高戈、吴迪、李娟：4-羟基邻苯二甲酸的制备方法，中国，申请号 : CN201410516726.0；申请日期: 2014-09-30；授权公开号-: CN201410516726，授权日期： 2016-09-21。 IPC 分类号 : C07C51/02; C07C65/03。四川大学为第二申请人
18.  游劲松、李必进、兰静波、吴迪、高戈：有机单分子白光材料双三苯胺取代邻羟基苯基唑类衍生物的制备及应用，中国，申请号: 201510219515.5，申请日期:2015-05-04；公开（公告）号 : CN104962277；公开（公告）日 : 2015-10-07；授权公告号-: CN104962277B，专利号：ZL 2015 1 0219515.5, 授权日期： 2017-05-24。 IPC 分类号 : C07D263/32(2006.01)I; C07D277/28(2006.01)I; H01L33/50(2010.01)I
专著
1.谢如刚主编，2007，《现代有机合成化学》（“十一五”国家重点图书），游劲松完成“绪论”、“有机合成设计与评价”和“有机合成中的网络资源和原料”三章，华东理工大学出版社。
2.胡跃飞、林国强主编，2008，《现代有机反应》，游劲松完成“斯泰特反应”一章（第四卷：碳-碳键的生成反应），化学工业出版社。
3.胡跃飞、林国强主编，2012，《现代有机反应》，游劲松完成“金属催化的芳环直接芳基化反应”一章（第六卷：金属催化反应），化学工业出版社。
4.Yudong Yang; Jingsong You, Chapter 3, Pd-Catalyzed Synthesis of Oxygen-Containing Heterocycles, p65-90, Transition Metal-Catalyzed Heterocycle Synthesis via C-H Activation, Edited by Xiao-Feng Wu, 2016, Wiley-VCH Verlag Gmgh & Co., Germany (ISBN 978-3-527-33888-7)

liangxi · 发表于 2022-6-10 18:42:13

近年来，有机发光二极管（OLED）的研究和应用备受关注。目前，高性能蓝光OLED的研究仍面临巨大挑战。相比于蓝光发光材料的快速发展及其结构多样性，适用于蓝光OLED的主体材料发展相对缓慢。因此，发展结构新颖的蓝光主体材料用于制备高性能蓝光OLED对于其进一步发展和应用具有重要意义。
四川大学游劲松教授、宾正杨副研究员团队致力于利用C−H活化策略构筑非传统结构的OLED新材料，以突破OLED材料结构和性能瓶颈。近期，游劲松教授和宾正杨副研究员等基于“翻转环金属化”策略发展了一种铱催化的分子内氧化C−H/C−H偶联反应，高效构筑了吡啶并杂芳环类分子骨架，为蓝光OLED主体材料的开发提供了丰富的分子库。作为一个例子，作者开发了一系列基于吡啶并苯并噻吩结构的双极性主体材料（DCz-BTP，3-Cz-BTP和6-Cz-BTP），其中吡啶环的引入有利于形成强的分子间氢键相互作用，从而显著改善主体材料的传输性能，进而降低器件驱动电压，提高器件效率。

      基于“伪”对称结构的双咔唑类DCz-BTP主体材料的蓝光OLED展现出更为优异的器件性能。将DCz-BTP用作主体，作者成功制备了低电压、高效率的蓝光热活化延迟荧光OLED（TADF-OLED：Von = 2.8 V, V1000 = 4.2 V, EQEmax = 29.0%, PEmax = 48.2 lm W-1）和蓝光超敏荧光OLED（TSF-OLED：Von = 2.8 V, V1000 = 4.2 V, EQEmax = 20.5%, PEmax = 34.7 lm W-1)，揭示了吡啶并苯并噻吩结构在构筑蓝光OLED主体材料方面的巨大潜力。
   该研究以“Intramolecular C−H Activation as an Easy Toolbox to Synthesize Pyridine-Fused Bipolar Hosts for Blue Organic Light-Emitting Diodes”为题目发表在Angewandte Chemie International Edition上，四川大学为第一单位，化学学院宾正杨副研究员和游劲松教授为该论文通讯作者，王菲博士研究生为论文的第一作者。特别感谢国家自然科学基金委、四川省科技厅、四川大学的经费支持。
      文章链接: https://onlinelibrary.wiley.com/doi/10.1002/anie.202205380

taipingyang · 发表于 2023-4-12 08:21:58

硼氮稠杂的多重共振型热活化延迟荧光分子（MR-TADF），其具有窄的半峰宽（FWHM）和较大的辐射跃迁速率（kR），因此基于该类发光分子的OLED能够实现较好的色纯度和较高的外量子效率（EQE），有望成为下一代OLED发光材料的突破点。然而，目前该类材料分子通常存在反系间窜越速率（kRISC）较低以及分子较为平面所导致的聚集诱导淬灭（ACQ）的问题，从而造成器件效率滚降比较严重。因此，如何提高kRISC和抑制ACQ效应，对改善OLED效率滚降具有重要的研究和产业化意义。
近日，四川大学游劲松教授和宾正杨教授团队发展了一种“中环”策略以抑制MR-TADF分子堆积，并进一步提高MR-TADF分子的kRISC。在保持窄发光半峰宽的前提下，该团队成功发展了一种兼具高kRISC(＞106 s-1)和高kR(＞108 s-1)的蓝光MR-TADF分子DTBA-B2N3，有效抑制分子聚集产生的光谱展宽和发光淬灭，从而获得高效率和低效率滚降的蓝光窄光谱OLED。
在MR-TADF材料BCz-BN的基础上，基于“中环”策略发展了新型MR-TADF分子DTBA-BN2和DTBA-B2N3。理论计算研究表明，通过引入七元环受体基团，DTBA-BN2的S1态跃迁特征与其T2态的跃迁特征有较大的差异，因此具有更高的自旋轨道耦合系数（SOCS1-T2 = 0.87 cm-1），有利于其反系间窜越过程。随后，进一步拓展共振骨架，双硼类MR-TADF分子DTBA-B2N3的自旋轨道耦合系数得到进一步提高（SOCS1-T2 = 1.22 cm-1，SOCS1-T3 = 0.82 cm-1），使得激子从T2或T3态的反系间窜越过程更加高效，最终将kRISC从BCz-BN的104 s-1提升到DTBA-B2N3的106 s-1数量级。此外，BCz-BN的核心发光骨架较为平面，具有强烈的分子间π-π相互作用，ACQ效应十分严重。通过引入七元环受体，MR-TADF分子DTBA-BN2和DTBA-B2N3具有高度扭曲的分子构型，其核心骨架不存在明显的π-π相互作用，极大程度上抑制了ACQ效应，有利于改善器件效率滚降。

      OLED测试结果表明，相比于基于BCz-BN的OLED，基于DTBA-BN2的OLED展现出了明显更加优异的器件性能以及更好的ACQ抑制作用，实现了31.2%的最大外量子效率、更小的效率滚降（EQE1000 = 25.6%）。此外，中环结构的引入可以有效保护发光中心，抑制分子聚集产生的光谱展宽和发光淬灭，使得在1~20%的浓度窗口下保持高效率和窄光谱。相比于基于对比分子B2的OLED，基于DTBA-B2N3的OLED展现出了明显更加优异的器件性能以及更窄的半峰宽，实现了30.9%的最大外量子效率、更小的效率滚降（EQE1000 = 20.5%）。这项工作为开发可产业化的高性能MR-TADF分子提供了一个新的分子设计思路。
      该研究以“ Medium-Ring Strategy Enables Multiple Resonance Emitters with Twisted Geometry and Fast Spin-Flip to Suppress Efficiency Roll-Off”为题目发表在Angewandte Chemie International Edition上，四川大学为第一单位，化学学院宾正杨教授和游劲松教授为该论文通讯作者，雷搏文博士研究生为论文的第一作者。特别感谢国家自然科学基金委、四川省科技厅、四川大学的经费支持。同时感谢化学学院测试平台李静老师对于化合物表征等提供的帮助和支持。
      文章链接: https://doi.org/10.1002/anie.202218405

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[学者专家] 四川大学化学学院游劲松

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