中国科学院长春应用化学研究所生态环境高分子材料重点实验室王献红

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王献红,中国科学院长春应用化学研究所研究员。1988年以优异成绩考入长春应化所，师从王佛松院士和景遐斌研究员，从事导电高分子的合成、结构和性能的研究。1993年获得高分子化学与物理的理学博士学位后留所从事导电高分子研究，1994年至1996年在韩国化学研究所做博士后工作，从事导电高分子的溶液与熔融加工研究。1996年回到长春应化所后继续开展导电高分子的应用基础研究，1997年被破格评为研究员，1999年被聘为博士生导师，2002年获得国家自然基金委杰出青年科学基金。2010年度国家自然科学基金委创新群体“生物降解高分子材料的基本科学问题”学术带头人。


王献红 博士
研究员 博士生导师 高分子化学专业
中科院生态环境高分子材料重点实验室主任
二氧化碳基塑料研究组 组长
办公室：合成楼527房间
电　话：+86-431-85262250
传　真：+86-431-85689095
E-mail：xhwang@ciac.ac.cn
教育和工作经历
1993.12－1994.09 中国科学院长春应用化学研究所，助理研究员  
1994.09－1996.04 韩国化学研究所，博士后  
1996.04－1996.12 中国科学院长春应用化学研究所，助理研究员  
1996.12－1997.12 中国科学院长春应用化学研究所，副研究员，研究员  
1999.12－至今 中国科学院长春应用化学研究所，研究员，博士生导师  
2009.12-至今 中国科学院生态环境高分子材料重点实验室主任  
学术任职
目前担任“高分子学报”副主编、 “Chinese Journal of Polymer Science”、“功能高分子学报”、“功能材料”、“Science China Materials”等杂志编委，以及“Journal of Renewable Materials” 编委，同时担任中国材料研究学会常务理事，中国化学会高分子学科委员会委员。
获奖及荣誉
2014    吉林省高级专家   
2010    国家自然基金委创新团队负责人  
2002    国家自然基金委杰出青年科学基金  
2001　中国化学会青年化学奖  
2000　吉林省有突出贡献的中青年专家 　
1998    吉林省“五一”劳动奖章
研究资助
长期从事导电聚苯胺和二氧化碳共聚物的应用基础，目前作为项目负责人承担的项目主要有:
1.国家科技支撑计划“CO2化工利用关键技术研发与示范”（2013-2015）  
2.“二氧化碳共聚物的基本问题研究”（2007－2009）
3.国家自然基金委创新团队项目“生物降解高分子材料的基本科学问题”（2014-2016）  
4.中科院重点部署项目“面向战略新兴产业的关键材料技术”（2013-2015）
研究领域和现状
研究工作主要集中在二氧化碳的固定和利用、聚苯胺的功能化和应用、二氧化碳基聚氨酯等领域，具体如下：  
1）二氧化碳的固定和利用研究：二氧化碳共聚物的催化剂设计、聚合方法、聚合物结构控制及其成型加工等。  
2）导电聚苯胺的应用基础研究：聚苯胺的水系加工及其在金属防腐蚀、抗静电、锂硫电池等领域的应用基础研究。  
3）二氧化碳基聚氨酯的应用基础研究：二氧化碳基多元醇的设计和可控合成、水性聚氨酯树脂胶粘剂、紫外光固化树脂的制备及其在汽车、家具等领域的应用研究。
主要代表性论文
在导电高分子、二氧化碳共聚物等方向发表学术论文150余篇，专著1部，获权美国专利2项，日本专利1项，中国发明专利40余项。近5年发表论文及著作如下：  
  1. Wang Yong, Qin Yusheng, Wang Xianhong**, Wang Fosong. Trivalent Titanium Salen Complex: Thermally Robust and Highly Active Catalyst for Copolymerization of CO2 and Cyclohexene Oxide. Acs Catalysis, 2015, 5(1):393-396.  
  2. Sheng Xingfeng, Wu Wei, Qin Yusheng, Wang Xianhong*, Wang Fosong. Efficient Synthesis and Stabilization of Poly-(Propylene Carbonate) from Delicately Designed Bifunctional Aluminum Porphyrin Complexes. Polymer Chemistry, 2015, 6(26):4719-4724.  
  3. Sheng Xingfeng, Ren Guanjie, Qin Yusheng, Chen Xuesi, Wang Xianhong*, Wang Fosong. Quantitative Synthesis of Bis(Cyclic Carbonate) S by Iron Catalyst for Non-Isocyanate Polyurethane Synthesis. Green Chem, 2015, 17(1):373-379.  
  4. Sheng Xingfeng, Guo Hongchen, Qin Yusheng, Wang Xianhong*, Wang Fosong. A Novel Metalloporphyrin-Based Conjugated Microporous Polymer for Capture and Conversion of CO2. RSC Advances, 2015, 5(40):31664-31669.
  5. Ren Guanjie, Miao Yuyang, Qiao Lijun, Qin Yusheng, Wang Xianhong*, Wang Fosong. Toughening of Amorphous Poly(Propylene Carbonate) by Rubbery CO2-Based Polyurethane: Transition from Brittle to Ductile. Rsc Advances, 2015, 5(62):49979-49986.  
  6. Qin Yusheng, Guo Hongchen, Sheng Xingfeng, Wang Xianhong*, Wang Fosong. An Aluminum Porphyrin Complex with High Activity and Selectivity for Cyclic Carbonate Synthesis. Green Chem, 2015.
　7. Luo Yizhong, Sun Yang, Lv Jinlong, Wang Xianhong*, Li Ji, Wang Fosong. Transition of Interface Oxide Layer from Porous Mg(Oh)(2) to Dense Mgo Induced by Polyaniline and Corrosion Resistance of Mg Alloy Therefrom. Appl Surf Sci, 2015, 328:247-254.  
　8. Gao Hong, Lu Qi, Liu Nianjiang, Wang Xianhong*, Wang Fosong. Facile Preparation of an Ultrathin Sulfur-Wrapped Polyaniline Nanofiber Composite with a Core-Shell Structure as a High Performance Cathode Material for Lithium-Sulfur Batteries. Journal of Materials Chemistry A, 2015, 3(14):7215-7218.  
　9. Yao Chuan, Lu Qi, Wang Xian-hong, Wang Fo-song. Charge Transport Mechanism of Oligo(P-Phenylene Vinylene)S Based Molecualr Wires. Acta Polymerica Sinica, 2014, (12):1659-1668.
　10. Yao Chuan, Lu Qi, Wang Xianhong*, Wang Fosong. Reversible Sol-Gel Transition of Oligo(P-Phenylenevinylene)S by Pi-Pi Stacking and Dissociation. J Phys Chem B, 2014, 118(17):4661-4668.
　11. Wu Wei, Sheng Xingfeng, Qin Yusheng, Qiao Lijun, Miao Yuyang, Wang Xianhong*, Wang Fosong. Bifunctional Aluminum Porphyrin Complex: Soil Tolerant Catalyst for Copolymerization of CO2 and Propylene Oxide. Journal of Polymer Science Part a-Polymer Chemistry, 2014, 52(16):2346-2355.  
　12. Wu Wei, Qin Yu-sheng, Wang Xian-hong, Wang Fo-song. Bifunctional Aluminum Porphyrin Catalysts for Copolymerization of CO2 and Epoxides. Acta Polymerica Sinica, 2014, (7):1017-1022.  
　13. Wang Yong, Qin Yusheng, Wang Xianhong*, Wang Fosong. Coupling Reaction between CO2 and Cyclohexene Oxide: Selective Control from Cyclic Carbonate to Polycarbonate by Ligand Design of Salen/Salalen Titanium Complexes. Catalysis Science & Technology, 2014, 4(11):3964-3972.  
　14. Sheng Xingfeng, Wang Yong, Qin Yusheng, Wang Xianhong*, Wang Fosong. Aluminum Porphyrin Complexes Via Delicate Ligand Design: Emerging Efficient Catalysts for High Molecular Weight Poly(Propylene Carbonate). Rsc Advances, 2014, 4(96):54043-54050.  
　15. Sheng Xingfeng, Ren Guanjie, Qin Yusheng, Chen Xuesi, Wang Xianhong*, Wang Fosong. Quantitative Synthesis of Bis(Cyclic Carbonate)S by Iron Catalyst for Non-Isocyanate Polyurethane Synthesis. Green Chem, 2014.
　16. Sheng Xingfeng, Qiao Lijun, Qin Yusheng, Wang Xianhong*, Wang Fosong. Highly Efficient and Quantitative Synthesis of a Cyclic Carbonate by Iron Complex Catalysts. Polyhedron, 2014, 74:129-133.  
　17. Ren Guanjie, Sheng Xingfeng, Qin Yusheng, Chen Xuesi, Wang Xianhong*, Wang Fosong. Toughening of Poly(Propylene Carbonate) Using Rubbery Non-Isocyanate Polyurethane: Transition from Brittle to Marginally Tough. Polymer, 2014, 55(21):5460-5468.  
　18. Liu Shunjie, Qin Yusheng, Chen Xuesi, Wang Xianhong*, Wang Fosong. One-Pot Controllable Synthesis of Oligo(Carbonate-Ether) Triol Using a Zn-Co-Dmc Catalyst: The Special Role of Trimesic Acid as an Initiation-Transfer Agent. Polymer Chemistry, 2014, 5(21):6171-6179.  
　19. Ju Hong-yan, Zhan Lei, Fu Da-guang, Li Ji, Wang Xian-hong, Wang Fo-song. Preparation of Polyaniline Films with High Infrared Emissivity and High Electrical Conductivity. Acta Polymerica Sinica, 2014, (4):557-564.  
　20. Ju Hong-yan, Fu Da-guang, Zhan Lei, Li Ji, Wang Xian-hong, Wang Fo-song. Influence of Humidity on Ammonia Sensibility of Polyaniline. Acta Polymerica Sinica, 2014, (1):156-163.  
　21. Zhou Shuiping, Zhang Hongming, Zhao Qiang, Wang Xianhong*, Li Ji, Wang Fosong. Graphene-Wrapped Polyaniline Nanofibers as Electrode Materials for Organic Supercapacitors. Carbon, 2013, 52:440-450.  
　22. Zhou Shuiping, Zhang Hongming, Wang Xianhong*, Li Ji, Wang Fosong. Sandwich Nanocomposites of Polyaniline Embedded between Graphene Layers and Multi-Walled Carbon Nanotubes for Cycle-Stable Electrode Materials of Organic Supercapacitors. Rsc Advances, 2013, 3(6):1797-1807.  
　23. Zhou Qinghai, Gu Lin, Gao Yonggang, Qin Yusheng, Wang Xianhong*, Wang Fosong. Biodegradable CO2-Based Polycarbonates with Rapid and Reversible Thermal Response at Body Temperature. Journal of Polymer Science Part a-Polymer Chemistry, 2013, 51(9):1893-1898.  
　24. Wu Wei, Qin Yusheng, Wang Xianhong*, Wang Fosong. New Bifunctional Catalyst Based on Cobalt-Porphyrin Complex for the Copolymerization of Propylene Oxide and CO2. Journal of Polymer Science Part a-Polymer Chemistry, 2013, 51(3):493-498.  
　25. Lu Qi, Zhao Qiang, Zhang Hong-ming, Li Ji, Wang Xian-hong, Wang Fo-song. Hollow Microspherical Polyaniline as Cathode Materials in Rechargeable Lithium-Oxygen Battery. Acta Polymerica Sinica, 2013, (8):1080-1084.  
　26. Lu Qi, Zhao Qiang, Zhang Hongming, Li Ji, Wang Xianhong*, Wang Fosong. Water Dispersed Conducting Polyaniline Nanofibers for High-Capacity Rechargeable Lithium-Oxygen Battery. Acs Macro Letters, 2013, 2(2):92-95.  
　27. Lu Qi, Gao Yonggang, Zhao Qiang, Li Ji, Wang Xianhong*, Wang Fosong. Novel Polymer Electrolyte from Poly(Carbonate-Ether) and Lithium Tetrafluoroborate for Lithium-Oxygen Battery. Journal of Power Sources, 2013, 242:677-682.  
　28. Gu Lin, Qin Yusheng, Gao Yonggang, Wang Xianhong*, Wang Fosong. Hydrophilic CO2-Based Biodegradable Polycarbonates: Synthesis and Rapid Thermo-Responsive Behavior. Journal of Polymer Science Part a-Polymer Chemistry, 2013, 51(13):2834-2840.  
　29. Gu Lin, Gao Yonggang, Qin Yusheng, Chen Xuesi, Wang Xianhong*, Wang Fosong. Biodegradable Poly(Carbonate-Ether)S with Thermoresponsive Feature at Body Temperature. Journal of Polymer Science Part a-Polymer Chemistry, 2013, 51(2):282-289.  
　30. Zhang Hong-ming, Chen Yu, Wang Xian-hong, Li Ji, Wang Fo-song. Aqueous Dispersed Polyaniline Nano Wires for Electrode Material of Supercapacitor. Acta Polymerica Sinica, 2012, (5):498-502.  
　31. Su Riting, Qin Yusheng, Qiao Lijun, Li Ji, Zhao Xiaojiang, Wang Pixin, Wang Xianhong*, Wang Fosong. Synthesis and Properties of Regio-Regular Poly(2-Furyloxirane) Using Tri-Isobutyl Aluminium as Catalyst. Journal of Polymer Research, 2012, 19(1).  
　32. Lu Qi, Yao Chuan, Wang Xianhong*, Wang Fosong. Enhancing Molecular Conductance of Oligo(P-Phenylene Ethynylene)S by Incorporating Ferrocene into Their Backbones. Journal of Physical Chemistry C, 2012, 116(33):17853-17861.  
　33. Lu Hong-wei, Qin Yu-sheng, Wang Xian-hong, Zhao Xiao-jiang, Wang Fo-song. Copolymerization of Carbon Dioxide and Propylene Oxide under in Situ Supported Rare Earth Ternary Catalyst. Acta Polymerica Sinica, 2012, (4):446-452.  
　34. Gu Lin, Qin Yusheng, Gao Yonggang, Wang Xianhong*, Wang Fosong. One-Pot Terpolymerization of Co2, Propylene Oxide and Lactide Using Rare-Earth Ternary Catalyst. Chinese Journal of Chemistry, 2012, 30(9):2121-2125.  
　35. Gao Yonggang, Qin Yusheng, Zhao Xiaojiang, Wang Fosong, Wang Xianhong*. Selective Synthesis of Oligo(Carbonate-Ether) Diols from Copolymerization of CO2 and Propylene Oxide under Zinc-Cobalt Double Metal Cyanide Complex. Journal of Polymer Research, 2012, 19(5).  
　36. Gao Yonggang, Gu Lin, Qin Yusheng, Wang Xianhong*, Wang Fosong. Dicarboxylic Acid Promoted Immortal Copolymerization for Controllable Synthesis of Low-Molecular Weight Oligo(Carbonate-Ether) Diols with Tunable Carbonate Unit Content. Journal of Polymer Science Part a-Polymer Chemistry, 2012, 50(24):5177-5184.  
　37. Gao Fengxiang, Zhou Qinghai, Dong Yanlei, Qin Yusheng, Wang Xianhong*, Zhao Xiaojiang, Wang Fosong. Ether Linkage in Poly(1,2-Propylene Carbonate), a Key Structure Factor to Tune Its Performances. Journal of Polymer Research, 2012, 19(5).  
　38. Dong Yanlei, Wang Xianhong*, Zhao Xiaojiang, Wang Fosong. Facile Synthesis of Poly(Ether Carbonate)S Via Copolymerization of CO2 and Propylene Oxide under Combinatorial Catalyst of Rare Earth Ternary Complex and Double Metal Cyanide Complex. Journal of Polymer Science Part a-Polymer Chemistry, 2012, 50(2):362-370.  
　39. Zhang Hongming, Zhao Qiang, Zhou Shuiping, Liu Nianjiang, Wang Xianhong*, Li Ji, Wang Fosong. Aqueous Dispersed Conducting Polyaniline Nanofibers: Promising High Specific Capacity Electrode Materials for Supercapacitor. Journal of Power Sources, 2011, 196(23):10484-10489.  
　40. Zhang Hongming, Lu Jinlong, Wang Xianhong*, Li Ji, Wang Fosong. From Amorphous to Crystalline: Practical Way to Improve Electrical Conductivity of Water-Borne Conducting Polyaniline. Polymer, 2011, 52(14):3059-3064.  
　41. Zhang Hongming, Li Yingping, Wang Xianhong*, Li Ji, Wang Fosong. A Facile Route to Hollow Microspherical Polyaniline. Polymer, 2011, 52(19):4246-4252.  
　42. Su Riting, Qin Yusheng, Qiao Lijun, Li Ji, Zhao Xiaojiang, Wang Pixin, Wang Xianhong*, Wang Fosong. Synthesis of Poly(2-Furyloxirane) with High Molecular Weight and Improved Regioregularity Using Macrocyclic Ether as a Cocatalyst to Potassium Tert-Butoxide. Journal of Polymer Science Part a-Polymer Chemistry, 2011, 49(6):1434-1442.  
　43. Qin Yu-sheng, Chen Li-jie, Wang Xian-hong, Zhao Xiao-jiang, Wang Fo-song. Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide under Cobalt Porphyrin Catalyst. Chinese Journal of Polymer Science, 2011, 29(5):602-608.  
　44. Qin Yusheng, Wang Xianhong*, Zhao Xiaojiang, Wang Fosong. Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Aluminum Porphyrin. Acta Polymerica Sinica, 2011, (7):784-790.  
　45. Qin Yusheng, Wang Xianhong*, Wang Fosong. Recent Advances in Carbon Dioxide Based Copolymer. Progress in Chemistry, 2011, 23(4):613-622.  
　46. Qin Yusheng, Chen Lijie, Wang Xianhong*, Zhao Xiaojiang, Wang Fosong. Enhanced Mechanical Performance of Poly(Propylene Carbonate) Via Hydrogen Bonding Interaction with O-Lauroyl Chitosan. Carbohydrate Polymers, 2011, 84(1):329-334.  
　47. Lu Hongwei, Qin Yusheng, Wang Xianhong*, Yang Xiangguang, Zhang Suobo, Wang Fosong. Copolymerization of Carbon Dioxide and Propylene Oxide under Inorganic Oxide Supported Rare Earth Ternary Catalyst. Journal of Polymer Science Part a-Polymer Chemistry, 2011, 49(17):3797-3804.  
　48. Li Zhifeng, Qin Yusheng, Zhao Xiaojiang, Wang Fosong, Zhang Suobo, Wang Xianhong*. Synthesis and Stabilization of High-Molecular-Weight Poly(Propylene Carbonate) from Zn-Co-Based Double Metal Cyanide Catalyst. European Polymer Journal, 2011, 47(11):2152-2157.  
　49. Li Yingping, Zhang Hongming, Wang Xianhong*, Li Ji, Wang Fosong. Role of Dissolved Oxygen Diffusion in Coating Defect Protection by Emeraldine Base. Synthetic Metals, 2011, 161(21-22):2312-2317.  
　50. Li Yingping, Zhang Hongming, Wang Xianhong*, Li Ji, Wang Fosong. Growth Kinetics of Oxide Films at the Polyaniline/Mild Steel Interface. Corrosion Science, 2011, 53(12):4044-4049.  
　51. Li Guofa, Qin Yusheng, Wang Xianhong*, Zhao Xiaojiang, Wang Fosong. Study on the Influence of Metal Residue on Thermal Degradation of Poly(Cyclohexene Carbonate). Journal of Polymer Research, 2011, 18(5):1177-1183.  
　52. Hu Yuxi, Qiao Lijun, Qin Yusheng, Wang Xianhong*, Zhao Xiaojiang, Wang Fosong. Diels-Alder Reaction of Furfuryl Glycidyl Ether/Carbon Dioxide Copolymer. Acta Polymerica Sinica, 2011, (11):1336-1340.  
　53. Gu Lin, Wang Xianhong*, Chen Xuesi, Zhao Xiaojiang, Wang Fosong. Thermal and Ph Responsive High Molecular Weight Poly(Urethane-Amine) with High Urethane Content. Journal of Polymer Science Part a-Polymer Chemistry, 2011, 49(24):5162-5168.  
　54. Gao Fengxiang, Zhou Qinghai, Qin Yusheng, Wang Xianhong*, Zhao Xiaojiang, Wang Fosong. Chain Extension of Maleic Anhydride End-Capped Poly(1,2-Cyclohexylene Carbonate) by Bisoxazolines. Acta Polymerica Sinica, 2011, (7):772-777.  
　55. Chen Lijie, Qin Yusheng, Zhou Qinghai, Wang Xianhong*, Zhao Xiaojiang, Wang Fosone. Toughening and Strengthening of Poly(Propylene Carbonate) by 1,6-Bis(Hydroxyisopropyl Urethane) Hexane. Acta Polymerica Sinica, 2011, (11):1349-1354.  
　56. Chen Lijie, Qin Yusheng, Wang Xianhong*, Zhao Xiaojiang, Wang Fosong. Plasticizing While Toughening and Reinforcing Poly(Propylene Carbonate) Using Low Molecular Weight Urethane: Role of Hydrogen-Bonding Interaction. Polymer, 2011, 52(21):4873-4880.  
　57. Chen Lijie, Qin Yusheng, Wang Xianhong*, Li Yuesheng, Zhao Xiaojiang, Wang Fosong. Toughening of Poly(Propylene Carbonate) by Hyperbranched Poly(Ester-Amide) Via Hydrogen Bonding Interaction. Polymer International, 2011, 60(12):1697-1704.  
　58. 《二氧化碳的固定和利用》，化工出版社，2010年 　　　　  　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　
研究组人员概况
       目前领导一个由30位固定职工（3个研究员，9个副研究员，11位助理研究员）和10余位研究生组成的研发团队，领导项目组发明了稀土三元催化剂，2004年建成千吨级二氧化碳基塑料中试线，在世界上率先突破二氧化碳基塑料的工业化瓶颈，实现了二氧化碳基塑料工业化从无到有的突破，2012年在浙江台州建成万吨级生产线，二氧化碳基树脂和薄膜以PCO2Ⓡ商标在美国3个州销售。发明了稀土掺杂的双金属催化剂，合成出窄分布、低分子量的二氧化碳基多元醇，所制备的二氧化碳基水性胶粘剂成功用于包括聚丙烯等低表面能基材的粘结，打破了跨国公司在汽车内饰胶粘剂领域的长期垄断。