中国科学院大连化学物理研究所Goldbach

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姓名：Goldbach       
性别：男
类别：研究员       
学科：化学物理
职称：研究员       
学历：博士研究生
电话：0411-84379285       
Email：goldbach@dicp.ac.cn
地址：大连市中山路457号       
邮编：116023


化学工程或物理化学 （膜科学和制氢）研究领域：氢能作为一种清洁、高效、可持续的新能源，被视为21世纪最具发展潜力的能源，其需求量正逐渐增大。金属钯膜分离技术具有100%的透氢选择性、装置密集型、节能、高效率等优点成为燃料电池和其它氢能技术以及膜催化等相关领域中氢气生产、纯化和利用的研究热点。针对这些应用，GOLDBACH的主要研究方向涉及高性能、高稳定性的金属氢分离膜的研制、表征和应用。具体来说，包括以下几个方面：
1. 高效的Pd合金膜的研制
    包括双组份、三组分如PdCu、PdAu、PdAg、PdNi等合金膜的制备及其结构特点、分离性能的研究。
2. Pd以及Pd合金膜的化学、热稳定性以及失活机理的研究
    尽管Pd及其合金膜本身具有较好的化学稳定性和热稳定性，但是在具体应用条件包括温度、气氛、压力等下，其稳定性尚需深入系统的研究。
3. 膜反应器中制氢的研究
    膜反应器可将分离和反应耦合到一个物理单元，同时由于在线分离产物而促进反应的进行，主要涉及水蒸气重整、水煤气变换（包括抗硫催化剂的研制）的研究。
4. 膜反应器中选择氧化的研究
    尤其低温选择氧化，如H2O2的合成，以及利用原位生成的H2O2选择性氧化碳氢化合物。
发表论文:[1] Sour water-gas shift reaction over Pt/CeO2 catalysts, B. Liu, A. Goldbach*,
     H.Y. Xu*, Catal. Today (2011), doi:10.1016/jcattod.2011.03.050.
[2] Nanoscale heterogeneity in alkyl-methylimidazolium bromide ionic liquids
     B. Aoun, A. Goldbach, M. Gonzalez, S. Kohara, D. Price, and M.-L.
     Saboungi,* J. Chem. Phys. 134 (2011) 104509.
[3] High-flux H2 separation membranes from (Pd/Au)n nanolayers, L. Shi,
      A. Goldbach,* and H. Xu, Int. J. Hydrogen Energy 36 (2011) 2281.
[4] Structure of a prototypic ionic liquid: Ethyl-methylimidazolium bromide, B.
     Aoun, A. Goldbach, S. Kohara, J.-F. Wax, M. Gonzales and M.-L. Saboungi,*
    J. Phys. Chem. B 114 (2010) 11623.
[5] H2O2 synthesis over PdAu membranes, L. Shi, A. Goldbach,* G. Zeng and
      H. Xu, Catal. Today 156 (2010) 118.
[6] Preparation and performance of thin-layered PdAu/ceramic composite
     membranes. Shi, A. Goldbach,* G. Zeng and H. Xu,* Int. J. Hydrogen
     Energy  35 (2010) 4201.
[7] Impact of the fcc/bcc phase transition on the homogeneity and behavior of
      PdCu membranes, A. Goldbach,* L. Yuan, H. Xu,* Separ. Purif. Technol. 73
      (2010) 65.
[8] Direct H2O2 synthesis over Pd membranes at elevated temperatures,
      L. Shi, A. Goldbach,* G. Zeng, H. Xu, J. Membr. Sci. 348 (2010) 160.
[9] Hydrogen membrane reactors for CO2 capture, D. Jansen,* J. W. Dijkstra,
      R. W. van den Brink, T. A. Peters, M. Stange, R. Bredesen, A. Goldbach, H.
      Xu, A. Gottschalk, A. Doukelis, Energy Procedia 1 (2009) 253-260.
[10] Development of hydrogen membrane reactors for CO2 capture, J. W.
        Dijkstra, D. Jansen, R. W. van den Brink, T. A. Peters, M. Stange, R.
        Bredesen, A. Goldbach, H. Xu, A. Gottschalk, S. Tlatlik, A. Doukelis, in:   
        Carbon Dioxide Capture for Storage in Deep Geological Formations,
        Volume 3, edited by L.I. Eide, CPL Press (2009).
[11] Water gas shift reaction in a Pd membrane reactor over Pt/Ce0.6Zr0.4O2
      catalyst, Y. Bi, H. Xu,* W. Li, A. Goldbach,* Int. J. Hydrogen Energy 34
      (2009) 2965.
[12] Defect sealing in Pd membranes via point-plating, G. Zeng, A. Goldbach,*
       H. Xu, J. Membr. Sci. 328 (2009) 6.
[13] Impact of support mass flow resistance on low-temperature H2,
       Permeation characteristics of a Pd95Ag5/Al2O3 composite membrane
       G. Zeng, A. Goldbach,* H. Xu, J. Membr. Sci. 326 (2009) 681.
[14] Nanocomposite materials: Semiconductors in zeolites, A. Goldbach, M.-L.
        Saboungi, in: Nanomaterials: Inorganic and Bioinorganic Perspectives;
        edited by C. M. Lukehart, R. A. Scott. Chichester, UK: John Wiley & Sons,
         Ltd., 2008, pp 649-658.
[15] Permeation hysteresis in PdCu membranes, L. Yuan, A. Goldbach,*
        H. Xu, J. Phys. Chem. B 112 (2008) 12692.
[16] CO2 decomposition over Pd membrane surfaces, H. Li, A. Goldbach,*
        W. Li, H. Xu, J. Phys. Chem. B 112 (2008) 12182.
[17] On CH4 decomposition during separation from H2 mixtures with thin Pd
        membranes, H. Li, A. Goldbach,* W. Li, H. Xu, J. Membr. Sci. 324(2008)
        95.
[18] Real-time monitoring of metal deposition and segregation phenomena
       during preparation of PdCu membranes, L. Yuan, A. Goldbach,* H. Xu, J.
       Membr. Sci. 322 (2008) 39.
[19] Segregation and H2 transport rate control in body-centered cubic PdCu
        membranes, L. Yuan, A. Goldbach, H. Xu, J. Phys. Chem. B 111 (2007)
       10952.
[20] PdC formation in ultra-thin Pd membranes during separation of H2/CO
        mixtures, H. Li, A. Goldbach, W. Li, H. Xu, J. Membr. Sci. 299 (2007) 130.
[21] Selenium/Zeolite Y Nanocomposites, A. Goldbach* and M.-L. Saboungi,
        Acc. Chem. Res. 38 (2005) 705.
[22] Low-Temperature H2 and N2 transport through thin Pd0.66Cu0.34Hx
        layers, X. Pan,* M. Kilgus, and A. Goldbach,* Catal. Today 104 (2005) 225.
[23] An Air-Stable Selenium/Zeolite Nanocomposite, A. Goldbach, L. Iton, M.
       Grimsditch, and M.-L. Saboungi, Chem. Mater. 16 (2004) 5107.
[24] Optical spectroscopy on Se clusters and chains confined in zeolites,
        A. Goldbach and M.-L. Saboungi, Eur. J. Phys. E 12 (2003) 185
[25] 77Se and 87Rb Solid State NMR study of the Structure of Rb2[Pd(Se4)2]？
        Se8, A. Goldbach, F. Fayon, T. Vosegaard, M.Wachhold, M. Kanatzidis, D.
         Massiot, and M.-L. Saboungi, Inorg. Chem. 42 (2003) 6996.
[26] An Approach to Band Gap Alignment in Confined Semiconductors,
        A. Goldbach, M.-L. Saboungi, L. Iton, D. L. Price, J. Chem. Phys. 115
       (2001) 11254.
[27] Oxidation of Aqueous Polyselenide Solutions - A Mechanistic Pulse  
        Radiolysis Study, A. Goldbach, M.-L. Saboungi, J. A. Johnson, A. R. Cook,
        D. Meisel, J. Phys. Chem. A 104 (2000) 4011.
[28] Short and intermediate-range atomic structure of glassy and liquid
        As2Se3 - An anomalous x-ray scattering study, S. Hosokawa,
       A. Goldbach,  M. Boll, F. Hensel, Physica Status Solidi (b), 215 (1999)
       785 .
[29] Stabilization of Selenium in Zeolites - An Anomalous X-Ray Scattering
        Study , A. Goldbach, M.-L. Saboungi, L. Iton, D. L. Price, Chem. Comm.
        1999 997.
[30] On the Constituents of Aqueous Polyselenide Electrolytes: A Combined
       Theoretical and Raman Spectroscopic Study, A. Goldbach, J. Johnson, D.
       Meisel, L. A. Curtiss, M.-L. Saboungi, J. Am. Chem. Soc. 121 (1999) 4461
[31] The Clusters Cd22+ and Cd42+ in Zeolite A, A. Goldbach, P. D. Barker, P.
        A. Anderson, P. P. Edwards, Chem. Phys. Lett. 292 (1998) 137.
[32] Vibrational Frequencies of Small Selenium Molecules, S. Kohara,
       A. Goldbach, N. Koura, M.-L. Saboungi, L. A. Curtiss, Chem. Phys. Lett.   
      287   (1998) 282.
[33] Optical Spectroscopy on Se8 Clusters and Se Chains Embedded in
        Zeolite Matrices, A. Goldbach, M.-L. Saboungi, Ber. Bunsenges. Phys.
        Chem. 101 (1997) 1660.
[34] On the Formation of Isolated Se8 Rings in Zeolites, A. Goldbach, L. Iton,
       M.-L. Saboungi, Chem. Phys. Lett. 281 (1997) 69.
[35] Semiconductors in  the disordered state: From bulk to nanoscale, P.      
        Armand, A. Goldbach, C. Cramer, R. Csencsits, L. E. Iton, D. L. Price,
        M.-L. Saboungi, J. Non-Cryst. Solids, 205-207 (1996) 797.
[36] Photoinduced Formation of Selenium Molecules in Zeolites: A Resonant
        Raman Spectroscopy Study, A. Goldbach, L. Iton, M. Grimsditch, M.-L.
        Saboungi, J. Phys. Chem. B 101 (1997) 330
[37] The Formation of Se2-: A New Resonance Raman Feature in the
        Photochemistry of Zeolite-Encapsulated Selenium, A. Goldbach, L. Iton,
        M. Grimsditch, M.-L. Saboungi, J. Am. Chem. Soc. 118 (1996) 2004.
[38] Formation of potassium oxide clusters by seeded supersonic expansion,,
        A. Goldbach, F. Hensel, K. Rademann, Int. J. Mass. Spec. Ion Processes   
        148 (1995) L5 .
[39] Size-dependent Trends in the Scattering of Small Potassium Clusters by
         Water Molecules, A. Goldbach, F. Hensel, K. Rademann, Z. Naturforsch.   
        49a (1994) 1067.
[40] Streuung von Kaliumclustern in Molekularstrahlen, A. Goldbach, PhD
        thesis, Marburg (1993).
[41] Kinetics of the Reactions of CH2 (X 3B1) with HCl and HBr
        A. Goldbach, F. Temps, H. Gg. Wagner, Ber. Bunsenges. Phys. Chem.
        94(1990) 1367.