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卢志云
职称与职务 教 授
专 业 有机化学
电 话 028-85410059
E-Mail luzhiyun@scu.edu.cn
简 历
卢志云,女,博士,教授,博士生导师。出生于1974年9月,于1991年9月进入四川大学化学系精细化工专业读本科,于1995年7月获得理学学士学位,2000年6月获得理学博士学位。毕业后在四川大学化学学院从事教学研究工作。其间于2001年3月赴新加坡工作一年(Research Fellow)。目前为中国化工学会精细化工专业委员会委员及《精细化工》杂志编委。
主要研究方向
具有光、电特性的有机功能材料的设计开发,包括有机电致发光显示及照明用功能分子、有机太阳电池能源材料、具有光电响应信号输出的新型化学传感器分子等。
主要工作业绩
主持了国家自然科学基金六项、科技部863项目子课题一项、教育部归国留学人员科研启动基金项目一项以及与企业横向协作项目多项,参加了国家自然科学基金委重大项目一项,重点项目一项。现已在《Advanced Functional Materials》、《Small》、《Chemical Communications》、《Journal of Materials Chemistry》、《ACS Appl. Mater. Interfaces》、《ACS Sensors》、《Dalton Transactions》等SCI收录的本研究领域重要期刊杂志上发表论文八十余篇,另有19项国家发明专利获准授权。
近年来本课题组承担的研究项目
1. 以 ‘RISC为主, TTA为辅’ 的新机制高效利用三线态激子的深蓝光OLED材料的设计、合成及性能研究”,国家自然科学基金面上项目,2017.01-2020.12
2. 基于C–H键直接高效高选择性转化构筑有机光电功能分子的化学基础”,国家自然科学基金委重点项目(主研人员),2015.01-2019.12
3. 多功能有机共轭分子体系的研究”,国家自然科学基金委重大研究项目(主研人员), 2011.01-2016.12
4. 基于扭曲的分子内电荷转移机理的新型聚集诱导发光分子的设计、合成及性能研究”,国家自然科学基金面上项目,2014.1-2017.12
5. 用于选择发射极太阳电池的纳米硅浆料B”,科技部863项目,2012.1-2014.12
6. 多重氢键自组装铱配合物电致磷光材料的设计合成及性能研究”,国家自然科学基金面上项目,2011.1-2013.12
7. 光伏TCO靶材无铟粘接技术研究 ”,与企业横向协作项目,2011.2-2012.6
8. 共建研发平台”,与企业横向协作项目,2009.4-2012.4
9. 新型电致磷光铱配合物的设计合成及性能研究”,国家自然科学基金面上项目,2009.1-2011.12
10. 高密度封装BGA/CSP用助焊体系的研发及产业化”,粤港招标重点突破项目,2009.1-2012.6
11. 低银SAC-X免清洗无铅焊锡膏的研发及产业化”,广东省产学研项目,2009.6-2012.6
12. 有机自由基电池”项目可行性论证,与企业横向协作项目,2008.10-2009.1
13. 共建电子材料平台”,与企业横向协作项目,2007.4-2009.4
14. 氢键自组装超分子聚合物电致发光材料的设计合成及性能研究”,国家自然科学基金面上项目,2007.1-2009.12
代表性成果 (获奖成果、专著、论文、专利)
近年来发表的代表性论文:
1. Yanju Luo, Yi Wang, Shiqi Chen, Ning Wang, Yige Qi, Xiaogen Zhang, Minghui Yang*, Yan Huang, Ming Li, Junsheng Yu*, Daibing Luo, Zhiyun Lu,* Facile Access to Twisted Intramolecular Charge-Transfer Fluorogens Bearing Highly Pretwisted Donor-Acceptor Systems Together with Readily Fine-Tuned Charge-Transfer Characters, Small, 13, 1604113, 2017.
2. Li Xiong, Jun Ma, Yan Huang, Zihe Wang, Zhiyun Lu,* Highly Sensitive Squaraine-Based Water-Soluble Far-Red/Near-Infrared Chromofluorogenic Thiophenol Probe, ACS Sensors, 2, 599-605, 2017.
3. Li Xiong, Lin Yang, Shuai Luo, Yan Huang, Zhiyun Lu,* Highly Sensitive Iridium(III) Complex-Based Phosphorescent Probe for Thiopheol Detection, Dalton Transactions, 2017, DOI: 10.1039/C7DT02263H.
4. Yan Jiao, Ming Li, Ning Wang, Tao Lu, Liang Zhou,* Yan Huang, Zhiyun Lu,* Daibing Luo, Xuemei Pu.* A facile color-tuning strategy for constructing a library of Ir(III) complexes with fine-tuned phosphorescence from bluish green to red using a synergetic substituent effect of –OCH3 and –CN at only the C-ring of C^N ligand, J. Mater. Chem. C, 4, 4269-4277, 2016.
5. Daobin Yang, Yan Jiao, Yan Huang,* Taojun Zhuang, Lin Yang, Zhiyun Lu,* Xuemei Pu, Hisahiro Sasabe,* Junji Kido.* Two different donor subunits substituted unsymmetrical squaraines for solution-processed small molecule organic solar cells, Organic Electronics, 32, 179-1865, 2016.
6. Lin Yang, Daobin Yang, Yao Chen, Qian Luo, Mangang Zhang, Yan Huang,* Zhiyun Lu,* Hisahiro Sasabe,* Junji Kido, Unsymmetrical squaraines with new linkage manner for high-performance solution-processed small-molecule organic photovoltaic cells, RSC Adv.,6, 1877-1884, 2016.
7. Xujun Zheng, Qiming Peng, Jie Lin, Yi Wang, Jie Zhou, Yan Jiao, Yuefeng Bai, Yan Huang, Feng Li,* Xingyuan Liu,* Xuemei Pu and Zhiyun Lu,* Simultaneous harvesting of triplet excitons in OLEDs by both guest and host materials with an intramolecular charge-transfer feature via triplet-triplet annihilation, J. Mater. Chem. C, 3, 6970-6978, 2015 (Cover story).
8. Ming Li, Baozhan Zheng, Daibing Luo, Huiqin Sun, Ning Wang, Yan Huang,* Jun Dai, Dan Xiao,* Shi-Jian Su and Zhiyun Lu,* Small molecular neutral microcrystalline iridium(III) complexes as promising molecular oxygen sensors, Chem. Commun., 51, 1926-1929, 2015.
9. Shuai Luo, Jie Lin, Jie Zhou, Yi Wang, Xingyuan Liu,* Yan Huang, Zhiyun Lu* and Changwei Hu*, Novel 1,8-naphthalimide derivatives for standard-red organic light-emitting device applications, J. Mater. Chem. C, 3, 5259-5267, 2015.
10. Xu Wang, Jie Zhou, Juan Zhao, Zhiyun Lu,* Junsheng Yu,* High performance fluorescent and phosphorescent organic light-emitting diodes based on a charge-transfer-featured host material, Organic Electronics, 21, 78-85, 2015.
11. Yao Chen, Youqin Zhu, Daobin Yang, Qian Luo, Lin Yang, Yan Huang,* Suling Zhao,* Zhiyun Lu.* Novel AsymmetricalSquaraines for High-Performance Small-Molecule Organic Solar Cells with High Short Circuit Current of over 12 mA cm-2. Chem. Commun., 51, 6133-6136, 2015.
12. Daobin. Yang, Yan Jiao, Lin Yang, Yao Chen, Satoshi Mizoi, Yan Huang,* Xuemei Pu, Zhiyun Lu, Hisahiro Sasabe,* Junji Kido.* Cyano-substitution on the end-capping group: facile access toward asymmetrical squaraine showing strong dipole-dipole interactions as a high performance small molecular organic solar cells material. J. Mater. Chem. A, 3, 17704–17712, 2015.
13. Daobin. Yang, Lin Yang, Yan Huang,* Yan Jiao, Tsukasa Igarashi, Yao Chen, Zhiyun Lu,* Hisahiro Sasabe,* Junji Kido.* Asymmetrical Squaraines Bearing Fluorine-Substituted Indoline Moieties for High-Performance Solution-Processed Small-Molecule Organic Solar Cells, ACS Appl. Mater. Interfaces, 7, 13675-13684, 2015.
14. Jie Zhou, Ping Chen, Xu Wang, Yan Wang, Yi Wang, Feng Li,* Minghui Yang, Yan Huang, Junsheng Yu,* Zhiyun Lu,* Charge-Transfer-Featured Materials—Promising Hosts for Fabrication of Efficient OLED through Triplet Harvesting via Triplet Fusion, Chem. Commun., 50, 7586-7589, 2014 (Cover story).
15. Xujun Zheng, Wencheng Zhu, Dong Liu, Hua Ai,* Yan Huang,* Zhiyun Lu,* Highly Selective Colorimetric/Fluorometric Dual-Channel Fluoride Ion Probe, and Its Capability of Differentiating Cancer Cells, ACS Appl. Mater. Interfaces, 6, 7996-8000, 2014.
16. Daobin Yang, Qianqian Yang, Lin Yang, Qian Luo, Yao Chen, Youqin Zhu, Yan Huang,* Zhiyun Lu* and Suling Zhao,* A low bandgap asymmetrical squaraine for high-performance solution-processed small molecule organic solar cells. Chem. Commun., 50, 9436-9348, 2014.
17. Lin Yang, Qianqian Yang, Daobin Yang, Qian Luo, Youqin Zhu, Yan Huang,* Suling Zhao,* Zhiyun Lu,* Marked Indolyl vs Indolinyl-Substituent Effects on Solid-State Structure, Carrier Mobility and Photovoltaic Efficiency of Asymmetrical Squaraine Dyes, J. Mater. Chem. A, 2, 18313–18321, 2014.
18. Fang Yu, Yan Wang, Wencheng Zhu, Yan Huang, Minghui Yang,* Hua Ai*and Zhiyun Lu,* A novel fluorescent pH probe with valuable pKa based on a twisted intramolecular charge transfer mechanism, and its applications in cell imaging, RSC Adv., 4, 36849-36853, 2014.
19. Hanyu Wang, Jie Zhou, Xu Wang, Zhiyun Lu,* and Junsheng Yu*, High performance organic integrated device with ultraviolet photodetective and electroluminescent properties consisting of a charge-transfer-featured naphthalimide derivative, Appl. Phys. Lett., 105, 063303, 2014.
20. Jian Hu, Qian Luo, Zhanyuan Zhang, Yan Huang,* Daobin Yang, Xuemei Pu and Zhiyun Lu,* Self-assembled nanopillar arrays by simple spin coating from blending systems comprising PC61BM and conjugated polymers with special structure. RSC Adv., 4, 24316-24320, 2014.
21. Yi Wang, Jie Zhou, Xu Wang, Xujun Zheng, Zhiyun Lu,* Wei Zhang, Yunqing Chen, Yan Huang,* Xuemei Pu, Junsheng Yu*. An Efficient Guest/Host Fluorescent Energy Transfer Pair Based on the Naphthalimide Skeleton, and its Application in Heavily-Doped Red Organic Light-Emitting Diodes, Dyes and Pigments, 100, 87-96, 2014.
22. Dongbing Zhao, Gaocan Li, Di Wu, Xurong Qin, Patrik Neuhaus, Yangyang Cheng, Shuaijun Yang, Zhiyun Lu, Xuemei Pu, Chao Long, Jingsong You,* Developments and Applications of Coupling Reactions in Dye Discovery: Regiospecific N-Heteroarylation of Amidines to Full-Color-Tunable Boron Difluoride Dyes with Mechanochromic Luminescence, Angew. Chem. Int. Ed., 52, 13676-13680, 2013.
23. Daobin Yang, Qianqian Yang, Lin Yang, Qian Luo, Yan Huang,* Zhiyun Lu,* Suling Zhao,* Novel High Performance Asymmetrical Squaraines for Small Molecule Organic Solar Cells with a High Open Circuit Voltage of 1.12 V, Chem. Commun., 49, 10465-10467, 2013.
24. Jun Dai, Kaifeng Zhou, Ming Li, Huiqin Sun, Yunqing Chen, Shijian Su,* Xuemei Pu, Yan Huang,* Zhiyun Lu,* Iridium(III) Complexes with Enhanced Film Amorphism as Guests for Efficient Orange Solution-Processed Single-Layer PhOLEDs with Low Efficiency Roll-Off, Dalton Trans., 42, 10559-10571, 2013.
25. Zhanyuan Zhang, Qing Peng, Daobin Yang, Yunqing Chen, Yan Huang,* Xuemei Pu, Zhiyun Lu,* Yu Liu,* Novel Conjugated Polymers with Planar Backbone Bearing Acenaphtho[1,2-b]quinoxaline Acceptor Subunit for Polymer Solar Cells, Synth. Met., 175, 21-29, 2013.
26. Qi Wang, Junsheng Yu,* Juan Zhao, Jun Wang, Ming Li, Zhiyun Lu,* High-Efficiency and Heavily Doped Organic Light-Emitting Devices Based on Quench-Resistant Red Iridium Complex, J. Lumin.,134, 870-873, 2013.
27. Qi Wang, Junsheng Yu,* Juan Zhao, Ming Li, Zhiyun Lu,* Enhancement of charge carrier recombination efficiency by utilizing a hole-blocking interlayer in white OLEDs, J. Phys. D: Appl. Phys., 46, 155102, 2013
28. Erfu Huo, Daobin Yang, Zhanyuan Zhang, Zhiyun Lu,* Huiqin Sun, Xing Xin, Yan Huang,* Yu Liu, Qing Jiang, Synthesis and Characterization of 4-Dodecyloxyphenyl and ( 4’-Dodecyloxy-4-biphenyl) methylene-Substituted Bispyrrolylvinylthiophene-Based Polysquaraines Having Good Solubility and Very Low Bandgap for Light Absorption, J. Appl. Poly. Sci.,128, 1632-1639, 2013.
29. Hui Zeng, Fang Yu, Jun Dai, Huiqin Sun, Zhiyun Lu,* Ming Li, Qing Jiang, Yan Huang,* A Highly Selective Sulfur-Free Iridium(III)-Complex-Based Phosphorescent Chemidosimeter for Detection of Mercury(II) Ions, Dalton Trans.,41, 4878-4883, 2012.
30. Daobin Yang, Zhiqiang Guan, Lin Yang, Yan Huang, * Qingjian Wei, Zhiyun Lu,* Junsheng Yu,* Novel High-Performance Photovoltaic D-A Conjugated Polymers Bearing 1,2- Squaraine Moieties as Electron-Deficient Units, Sol. Energ. Mater. Sol. Cells, 105, 220-228, 2012.
31. Ming Li, Qi Wang, Jun Dai, Zhiyun Lu,* Yan Huang, Junsheng Yu,* Shuai Luo, Shijian Su,* Highly Efficient Orange and Red Organic Light-Emitting Diodes with Iridium(III) Complexes Bearing Benzothiazole Cyclometallate Ligands as Emitters, Thin Solid Films, 526, 231-236, 2012.
32. Jingjing Liu, Yanhu Li, Yi Wang, Huiqin Sun, Zhiyun Lu,* Hongbin Wu, Junbiao Peng,* Yan Huang,* Synthesis and Luminescent Properties of Blue Sextuple-Hydrogen-Bond Self-Assembly Molecular Duplexes Bearing 4-Phenoxy-1,8-Naphthalimide Moieties , Opt. Mater.,34, 1535-1542 , 2012.
33. Yong Zou, Zhiqiang Guan, Zhanyuan Zhang, Yan Huang,* Nana Wang, Zhiyun Lu,* Qing Jiang, Junsheng Yu,* Yu Liu, Xuemei Pu, Synthesis and Photovoltaic Properties of Conjugated Copolymers Bearing Planar Acenaphtho[1,2-b] quinoxaline Moiety with Deep HOMO Level, J. Mater. Sci.,47 (14), 5535-5545, 2012.
34. Ming Li, Hui Zeng, Yanyan Meng, Huiqin Sun, Zhiyun Lu,* Yan Huang, Xuemei Pu,* Fine Tuning of Emission Color of Iridium(III) Complexes from Yellow to Red via Substituent Effect on 2-Phenylbenzothiazole Ligands: Synthesis, Photophysical, Electrochemical and DFT Study, Dalton Trans., 40, 7153-7164, 2011.
35. Yi Wang, Xiaogen Zhang, Bing Han, Junbiao Peng, Shiyou Hou, Yan Huang,* Huiqin Sun, Minggui Xie, Zhiyun Lu,* The Synthesis and Photoluminescence Characteristics of Novel Blue Light-Emitting Naphthalimide Derivatives, Dyes and Pigments, 86, 190-196, 2010.
36. Jingjing Liu, Yi Wang, Guangdong Lei, Junbiao Peng, Yan Huang,* Yong Cao, Minggui Xie, Xuemei Pu, Zhiyun Lu,* A Sextuple Hydrogen Bonding Molecular Duplex Bearing 1,8-Naphthalimide Moieties and Polymer Light-Emitting Diode Based on It, J. Mater. Chem.,19, 7753-7758, 2009.
37. Xiaoqiang Wei, Junbiao Peng, Jianbo Cheng, Minggui Xie, Zhiyun Lu,*Chun Li, Yong Cao, High Performance Polymer Electrophosphorescent Devices with tert-Butyl group Modified Iridium Complexes as Emitters, Adv. Func. Mater., 17, 3319-3325, 2007.
获得授权发明专利:
1) 黄艳,杨琳,陈静,杨道宾,卢志云,一系列不对称方酸菁小分子及其制备方法和应用, ZL 201310114027.9
2) 卢志云,郑徐军,王毅,黄艳,红光有机电致发光材料及器件,中国,ZL201310396364.1
3) 黄艳,罗骞,陈群,卢志云,含多重氢键的助焊体系及施用该体系的印刷线路板,中国ZL201310554618.8
4) 黄艳,王宁,陈瑶,卢志云,陈群,含多重氢键超分子自组装体系的银浆料及其应用,中国,ZL201310554671.8
5) 卢志云,刘景景,曾晖,黄艳,谢明贵,六重氢键自组装蓝色萘酰亚胺类荧光材料,中国,ZL201110175951.9
6) 卢志云,李明,代军,黄艳,谢明贵,红光有机电致磷光铱配合物,中国,ZL201110041449.9
7) 黄艳,杨道宾,霍二福,卢志云,蒋青,聚方酸类共轭聚合物及其制备方法和应用,中国,ZL201110175951.9
8) 黄艳,杨道宾,张占元,陈群,卢志云,邓小成,郑伟民 ,一种高润湿性的无铅无卤焊膏,中国, ZL201110041094.3
9) 黄艳,李英,卢志云,邓小成,郑伟民,电子工业用无铅无卤锡膏,中国,ZL201010028054.0
10) 黄艳,陈群,卢志云,邓小成,郑伟民,电子工业用无卤助焊剂,中国,ZL201010028055.5
11) 卢志云,王毅,陈静,黄艳,谢明贵,蓝光萘酰亚胺类荧光化合物,中国,ZL200910167687.7
12) 雷光东,卢志云,邱德敏,黄艳,氢键自组装超分子蓝色荧光聚合物及其合成方法, 中国,ZL200910167872.6
13) 黄艳,陈群,郭丹,卢志云,谢明贵,金属表面处理剂及施用该处理剂形成保护膜的印刷线路板,中国,ZL200910058833.2
14) 黄荣,魏孝强,卢志云,谢明贵,铱配合物类有机电致磷光材料,中国,ZL 200710048563.8
15) 雷光东,卢志云,谢明贵,4.6-二羟基-1.3-苯二甲酸及1.3-二羟基-1.4-苯二甲酸的一步合成方法,中国,ZL200410040760.1
16) 雷光东,卢志云,谢明贵,一种六氢键自组装超分子黄绿色发光材料及其合成方法,中国,ZL 200410081544.1
17) 谢明贵,魏孝强,卢志云,黄艳,蒋青,杯芳烃有机电致发光材料,中国,ZL03117828.6
18) 谢明贵,魏孝强,卢志云,黄艳,蒋青,有机电致发光材料,中国,ZL 02113399.9
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