中国科学院兰州化学物理研究所资源化学领域毕迎普

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姓名：毕迎普　 性别：男　 学历：博士研究生
职称：研究员　 博士生导师 学科类别：物理化学
个人网页：http://www.licp.cas.cn/bypz
电话：0931-4968651 传真：0931-8277088  电子邮件：yingpubi@licp.cas.cn
通讯地址：甘肃省兰州市天水中路18号  邮编：730000
　　简历：
　　中国科学院兰州化学物理研究所研究员，博士生导师，能源与环境纳米催化材料组课题组长，中国光催化专业委员会青年工作部副主任。
　　2008年毕业于中国科学院兰州化学物理研究所并获理学博士学位。  
　　2009-2011年在日本国立物质材料研究所国际纳米材料研究中心博士后。  
　　2011年入选中科院“百人计划”引进国外杰出人才到中科院兰州化学物理研究所工作，任创新研究员，2012年获得择优支持。  
　　    研究工作主要集中于半导体光催化及光电催化纳米材料的结构设计构建及其性能研究，揭示半导体材料的结构与光催化和光电催化性能之间的构效，从而构建具有高活性的半导体光催化及光电催化纳米材料。 在J. Am. Chem. Soc, Adv. Mater , Nano Energy, Chem Mater, Chem Commun, Chem Eur J等权威杂志发表80余篇论文，相关工作被引用5000余次，其中8篇引用超过100次，最高单篇引用1700余次，H因子为27。
　　    2014年获得中国化学会催化委员会 “中国催化新秀奖”，2016年获中国可再生能源学会光化学委员会“优秀青年奖”， 2016年获国家自然科学基金“优秀青年基金”支持，2017年获中科院“百人计划”终期考核优秀。  
　　本课题组招聘有相关研究兴趣的硕博士研究生和博士后，欢迎有具有物理化学及材料化学背景的学生咨询。  
　　研究方向：
　　1. 半导体纳米材料可控构建；
　　2. 半导体光电催化性能研究；
　　3. 光催化制氢及CO2还原；
　　4. 光生电荷分离迁移研究；
　　5. 能源与环境纳米催化材料。
　　承担项目
　　1.中科院“百人计划”A类-引进国外杰出人才项目：能源与环境纳米催化材料研究。2012.1-2016.12  
　　2.中科院兰州化物所特聘人才计划项目，一维半导体光电催化材料，2017.1-2019.12   
　　3.中科院兰州化物所OSSO重点实验室自主课题，异质光催化材料合成, 2012.1-2018.12
　　4.国家自然科学基金优秀青年基金项目：光催化, 26122310，2017.1-2019.12
　　5.国家自然科学基金面上项目：高效光生载流子分离及电子传输异质光催化材料设计合成，21273255，2013.1-2016.12
　　6.国家自然科学基金面上项目：半导体纳米阵列晶面间载流子迁移与光催化性能研究，21573264， 2016.1-2019.12   
　　代表论著：
　　2017　
　　[1] Lei Wang, Yang Yang, Yajun Zhang, Qiang Rui, Beibei Zhang, Zhiqiang Shen, Yingpu Bi*, One dimensional Hematite Photoanodes with Spatially Separated Pt and FeOOH Nanolayers for Efficient Solar Water Splitting, J. Mater. Chem. A, 2017, DOI: 10.1039/C7TA05318E。
　　[2] Ying Ma, Zhonghao Wang a, Yulong Jia, Lina Wang, Min Yang, Yanxing Qi*, Yingpu Bi*, Bi2MoO6 nanosheet array modified with ultrathin graphitic carbon nitride for high photoelectrochemical performance, Carbon, 2017, 114, 591.
　　[3] Qizhao Wang*. Jijuan He, Yanbiao Shi, Shuling Zhang, Tengjiao Niu, Houde She, Yingpu Bi*, Ziqiang Lei, Synthesis of MFe2O4 (M = Ni, Co)/BiVO4 film for photolectrochemical hydrogen production activity, App. Catal. B, 2017, 214, 158.
　　[4] Lei Wang, Nhat Truong Nguyen, Yajun Zhang, Yingpu Bi*， Patrik Schmuki*, Ehanced Solar Water Splitting by Swift Charge Separation in Au/FeOOH Sandwiched Single Crystalline Fe2O3 Nanoflake Photoelectrodes, ChemSusChem, 2017, 10, 2720.  
　　[5] Lei Wang, Hongyan Hu, Nhat Truong Nguyen, Yajun Zhang, Patrik Schmuki*, Yingpu Bi*, Plasmon-Induced Hole-Depletion Layer on Hematite Nanoflake Photoanodes for Highly Efficient Solar Water Splitting, Nano Energy, 2017, 35, 171.  
　　[6] Wei Wang, Yajun Zhang, Lei Wang, Yingpu Bi*, Facile synthesis of Fe3+/Fe2+ self-doped nanoporous FeVO4 photoanodes for efficient solar water splitting, J. Mater. Chem. A, 2017, 5, 2478.  
　　[7]  Chenchen Feng, Zhonghao Wang, Ying Ma, Yajun Zhang, Lei Wang, Yingpu Bi*, Ultrathin graphitic C3N4 nanosheets as highly efficient metal-free cocatalyst for water oxidation, App. Catal. B, 2017, 205, 19.  
　　[8] Zhengbo Jiao*, Mingdong Shang, Jiamei Liu, Gongxuan Lu, Xuesen Wang, Yingpu Bi*, The charge transfer mechanism of Bi modified TiO 2 nanotube arrays: TiO2 serving as a “charge-transfer-bridge”, Nano Energy, 2017, 31,96.  
　　2016　
　　[1] Ying Ma, Yulong Jia, Lina Wang, Min Yang, Yingpu Bi*, Yanxing Qi*, Facile synthesis of three-dimensional flower-like MoO2–graphene nanostructures with enhanced electrochemical performance, J. Mater. Chem. A, 2016, 4, 10414.
　　[2]  Zhengbo Jiao*, Jingjing Zheng, Chenchen Feng, Zeli Wang, Xuesen Wang, Gongxuan Lu, Yingpu Bi*, Fe/W Co-Doped BiVO4 Photoanodes with a Metal–Organic Framework Cocatalyst for Improved Photoelectrochemical Stability and Activity, ChemSusChem, 2016, 9, 2824.
　　[3] Yunxiang Li, Shuxin Ouyang*, Hua Xu, Xin Wang, Yingpu Bi, Yuanfang Zhang, and Jinhua Ye*, Constructing Solid–Gas-Interfacial Fenton Reaction over Alkalinized-C3N4 Photocatalyst To Achieve Apparent Quantum Yield of 49% at 420 nm,  J. Am. Chem. Soc., 2016, 138, 13289.  
　　[4] Mingdong Shang, Hongyan Hu, Gongxuan Lu, and Yingpu Bi*, Synergistic effects of SrTiO3 nanocubes and Ti3+ dual-doping for highly improving photoelectrochemical performance of TiO2 nanotube arrays under visible light, J. Mater. Chem. A, 2016, 4, 5849.
　　[5] Ying Ma, Yulong Jia, Lina Wang, Min Yang, Yingpu Bi*, Yanxing Qi*, Efficient Charge Separation between Bi and Bi2MoO6 for Photoelectrochemical Properties, Chem. Eur. J, 2016, 22, 5844.
　　[6] Xiaogang Liu, Guojun Dong, Shaopeng Li, Gongxuan Lu, Yingpu Bi*, Direct Observation of Charge Separation on Anatase TiO2 Crystals with Selectively Etched {001} Facets, J. Am. Chem. Soc. 2016, 138, 2917.   
　　[7] Shaopeng Li, Hongyan Hu, Yingpu Bi*, Ultra-thin TiO2 nanosheets decorated with Pd quantum dots for high-efficiency hydrogen production from aldehyde solution, J. Mater. Chem. A, 2016, 4, 796.  
　　2015
　　[1] Chenchen Feng, Zhengbo Jiao, Shaopeng Li, Yan Zhang, and Yingpu Bi*, Facile Fabrication of BiVO4 Nanofilms with Controlled Pore Size and their Photoelectrochemical Performances, Nanoscale, 2015, 7, 20374.
　　[2] Bingjun Jin, Zhengbo Jiao, Yingpu Bi*, Efficient Charge Separation between Bi2MoO6 Nanosheets and ZnO Nanowires for Enhanced Photoelectrochemical Properties, J. Mater. Chem. A, 2015, 3, 19702.  
　　[5] David James Martin, Guigao Liu, Savio J. A. Moniz, Yingpu Bi, Andrew M. Beale, Jinhua Ye*, Junwang Tang*, Efficient visible driven photocatalyst, silver phosphate: performance, understanding and perspective, Chem. Soc. Rev, 2015, DOI:10.1039/c5cs00380f.   
　　[6] Dongdong Qin, Yingpu Bi, Xinjian Feng, Wei Wang, Greg D. Barber, Ting Wang, Yumin Song, Xiaoquan Lu, Thomas E. Mallouk*, Hydrothermal Growth and Photoelectrochemistry of Highly Oriented, Crystalline Anatase TiO2 Nanorods on Transparent Conducting Electrodes, Chem Mater, 2015, 27, 4180.
　　[7] Ying Ma, Yulong Jia, Zhengbo Jiao, Min Yang, Yanxing Qi*, and Yingpu Bi*,  Hierarchical Bi2MoO6 Nanosheet-Built Frameworks with Excellent Photocatalytic Properties, Chem Commun, 2015, 51, 6655.   
　　[8] Teng Wang, Bingjun Jin, Zhengbo Jiao, Gongxuan Lu, and Yingpu Bi*, Electric-Field-Directed Growth and Photoelectrochemical Properties of Cross-linked Au/ZnO Hierarchical Architecture, Chem Commun, 2015, 51, 2103.   
　　2014
　　[1] Zhengbo Jiao, Yan Zhang, Shuxin Ouyang, Hongchao Yu, Gongxuan Lu, Jinhua Ye, Yingpu Bi*, BiAg Alloy Nanospheres: A New Photocatalyst for H2 Evolution from Water Splitting, ACS Appl. Mater. Inter, 2014, 6, 19488.
　　[2] Teng Wang, Bingjun Jin, Zhengbo Jiao, Gongxuan Lu, Jinhua Ye, Yingpu Bi*,  Photo-directed growth of Au nanowires on ZnO arrays for enhancing photoelectrochemical performances, J. Mater. Chem. A, 2014, 2,15553.   
　　[3] Hongyan Hu, Zhengbo Jiao, Jinhua Ye, Gongxuan Lu, Yingpu Bi*, Highly Efficient Hydrogen Production from Alkaline Aldehyde Solutions Facilitated by Palladium Nanotubes, Nano Energy, 2014, 8, 103.   
　　[4] Zhengbo Jiao, Yan Zhang, Tao Chen, Gongxuan Lu, Jinhua Ye, and Yingpu Bi*, TiO2 Nanotube Arrays Modified with Cr-doped SrTiO3 Nanocubes for Highly Efficient Hydrogen Evolution under Visible Light, Chem Eur J, 2014, 20, 2654.   
　　[5] Hongchao Yu, Qingsong Dong, Zhengbo Jiao, Teng Wang, Jiantai Ma, Gongxuan Lu,* and Yingpu Bi*, Ion exchange synthesis of PAN/Ag3PO4 core-shell nanofibers with enhanced photocatalytic properties, J. Mater. Chem. A, 2014, 2, 1668.   
      2013　  
　　[1] Zhengbo Jiao, Tao Chen, Jinyan Xiong, Teng Wang, Gongxuan Lu, Jinhua Ye & Yingpu Bi*, Visible-light-driven photoelectrochemical and photocatalytic performances of Cr-doped SrTiO3/TiO2 heterostructured nanotube arrays, Sci. Rep., 2013, 3, 2720.   
　　[2] Hongyan Hu, Zhengbo Jiao, Teng Wang, Jinhua Ye, Gongxuan Lu* and Yingpu Bi*, Enhanced Photocatalytic Activity of Ag/Ag3PO4 Coaxial Hetero-Nanowires, J. Mater. Chem A., 2013, 1, 10612.   
　　[3] Teng Wang, Zhenbo Jiao, Tao Chen, Yawen Li, Wei Ren, Shengling Lin,* Gongxuan Lu,* Jinhua Ye, and Yingpu Bi*, Vertically aligned ZnO nanowire arrays tip-grafted with silver nanoparticles for photoelectrochemical applications, Nanoscale, 2013,5, 7552.   
　　[4] Jinyan Xiong, Zhengbo Jiao, Gongxuan Lu, Jinhua Ye and Yingpu Bi*,Facile and Rapid Oxidation Fabrication of BiOCl Hierarchical Nanostructure with Enhanced Photocatalytic Properties, Chem Eur J, 2013, 19, 9472.   
　　[5] Hongyan Hu, Zhengbo Jiao, Hongchao Yu, Gongxuan Lu, Jinhua Ye and Yingpu Bi*, Facile synthesis of tetrahedral Ag3PO4 submicro-crystals with enhanced photocatalytic properties, J. Mater. Chem A., 2013, 1, 2387.  
　　[6] Zhengbo Jiao, Yan Zhang, Hongchao Yu, Gongxuan Lu, Jinhua Ye and Yingpu Bi*, Concave trisoctahedral Ag3PO4 microcrystals with high-index facets and enhanced photocatalytic properties, Chem Commun, 2013, 49, 636.  
　　2012
　　[1] Shuxin Ouyang, Hua Tong, Naoto Umezawa, Junyu Cao, Peng Li, Yingpu Bi, Yuanjian Zhang, and Jinhua Ye, Surface-Alkalinization-Induced Enhancement of Photocatalytic H2 Evolution over SrTiO3-Based Photocatalysts, J. Am. Chem. Soc., 2012, 134, 1974.   
　　[2] Yingpu Bi*, Hongyan Hu, Shuxin Ouyang, Zhengbo Jiao, Gongxuan Lu*, Jinhua Ye*, Selective Growth of Metallic Ag Nanocrystals on Ag3PO4 Submicro-Cubes for Photocatalytic Applications, Chem. Eur. J. 2012, 18, 14272.  
　　[3] Yingpu Bi*, Hongyan Hu, Shuxin Ouyang, Zhengbo Jiao, Gongxuan Lu* and Jinhua Ye*, Selective growth of Ag3PO4 submicro-cubes on Ag nanowires to fabricate necklace-like heterostructures for photocatalytic applications, J. Mater. Chem., 2012, 22, 14847.   
　　[4] Yingpu Bi*, Hongyan Hu, Shuxin Ouyang, Gongxuan Lu,* Junyu Cao and Jinhua Ye*, Photocatalytic and photoelectric properties of cubic Ag3PO4 sub-microcrystals with sharp corners and edges, Chem Commun, 2012, 48, 3748.   
　　[5] Hua Tong, Shuxin Ouyang, Yingpu Bi, Naoto Umezawa, Mitsutake Oshikiri, Jinhua Ye*. Nano-photocatalytic Materials: Possibilities and Challenges. Adv Mater. 2012, 24, 229.   
　　2008-2011   
　　[1] Yingpu Bi, Shuxin Ouyang, Naoto Umezawa, Junyu Cao, and Jinhua Ye*, Facet Effect of Single-Crystalline Ag3PO4 Sub-microcrystals on Photocatalytic Properties. J. Am. Chem. Soc. 2011, 133, 6490.  　  
　　[2] Yingpu Bi, Jinhua Ye*, Direct Conversion of Commercial Silver Foils into High Aspect Ratio AgBr Nanowires with Enhanced Photocatalytic Properties. Chem Eur J, 2010, 16, 10327.  　  
　　[3] Yingpu Bi, Jinhua Ye*, Cold-welding fabrication of highly ordered gold nanochannel monolayers in aqueous medium. Chem Commun, 2010, 46, 6912. (Highlighted as a Hot Paper)  　  
　　[4] Yingpu Bi, Jinhua Ye*. Heteroepitaxial growth of platinum nanocrystals on AgCl nanotubes via galvanic replacement reaction. Chem Commun, 2010, 46, 1532.  　  
　　[5] Yingpu Bi, Hongyan Hu, Gongxuan Lu*, Highly ordered rectangular silver nanowire monolayers: water-assisted synthesis and galvanic replacement reaction with HAuCl4. Chem Commun, 2010, 46, 598.  　  
　　[6] Yingpu Bi, Jinhua Ye*. In situ oxidation synthesis of Ag/AgCl core-shell nanowires and their photocatalytic properties. Chem Commun, 2009, 6551.   　  
　　[7] Yingpu Bi, Gongxuan Lu*. Control growth of uniform platinum nanotubes and their catalytic properties for methanol electrooxidation. Electrochem Commun, 2009,11, 45.   　　  
　　[8] Yingpu Bi, Gongxuan Lu*. Iodide ions control galvanic replacement growth of uniform rhodium nanotubes at room temperature. Chem Commun, 2008, 6402.  
　　[9] Yingpu Bi, Gongxuan Lu*. Facile synthesis of platinum nanofiber/nanotube junction structures at room temperature. Chem Mater. 2008, 20, 1224.

daretian

兰州化物所毕迎普Nano Energy : 原子间电子转移与TiO2光催化活性之间的关系

太阳能驱动的光催化分解水，即利用丰富的太阳能来生产清洁和可再生的氢能，是有望解决能源危机的策略之一。在各种半导体中，二氧化钛(TiO2)被视为光催化研究中的基准半导体，其通常存在四种晶相，即锐钛矿、金红石、板钛矿和TiO2(B)。尽管具有适当能带结构和捕集深度的上述TiO2多晶在热力学上均可进行水还原和氧化反应，但是单独的TiO2不具备催化全分解水活性。氢气仅在金属助催化剂或牺牲试剂的存在下产生。为了深入探究该问题，研究人员付出了巨大的努力来寻找这一现象背后的内在原因。 目前研究人员已经通过各种技术对水分子与单晶TiO2的相互作用等表面反应进行了广泛的研究，包括程序升温脱附(TPD)、振动光谱(VS)、表面X射线衍射(SXRD)以及超高真空(UHV)扫描隧道显微镜(STM)等。尽管对基态下的光催化机理已经得到了深入的了解，但是在激发态下TiO2不能分解水的内在原因至今仍不清楚。

近日，中科院兰州化物所毕迎普研究员(通讯作者)等通过同步辐射X射线光电子能谱(SI-XPS)直接观察到单晶TiO2(001)表面上分解水过程中的原子间电子激发和转移，并在Nano Energy上发表了题为“Relationship between interatomic electron transfer and photocatalytic activity of TiO2”的研究论文。定量结果清楚地表明，TiO2表面最初吸收的水分子促进了Ti和O原子之间的电子转移。然而，当水分子分别在Ti和O位点上解离成OH和H基团时，电子激发和转移能力逐渐降低并最终终止，这可能是由于Ti原子上OH基团的反向电子吸引。令人惊讶的是，当Pt助催化剂沉积在TiO2上时，Ti和O原子之间的电子激发得到显著增强，并且在整个分解水过程中没有明显的降低。此外，还检测了光催化界面处Pt-O和Ti-O化学键的变化。此外，基于上述机理研究，作者研究了在含有CH3OH的KOH溶液中Pt/R-TiO2(001)体系的光催化制氢性能，其析氢速率得到显著提高(20.78 μmol·h-1)，比传统Pt/R-TiO2(001)体系在CH3OH中(8.35 μmol·h-1)高2.5倍。该工作的发现为开发基于TiO2的光催化剂的其他高效光催化制氢系统铺平了道路。

fengtou

2018国家自然科学基金重点项目-光催化剂原子间光生电荷迁移及化学价键变化研究
批准号        21832005        学科分类        ( B020106 )
负责人        毕迎普        职称                单位名称        中国科学院兰州化学物理研究所
资助金额        315万元        项目类别        重点项目        起止年月        2019年01月01日 至 2023年12月31日