天津工业大学环境与化学工程学院颜范勇

pingju

个人简介：
颜范勇，男，工学博士、副教授、硕士生导师，中国化学会会员，主要从事荧光探针和药物合成方向的本科/研究生教学及科研工作。近五年来在 Carbon, Sensors and Actuators B等国内外学术刊物上发表论文 60 余篇，其中被 SCI、EI 收录 30 篇，申请国家发明专利 6项，主持在研天津市科委 2 项。
电 话：022-83955766
E-mail：yanfanyong@tjpu.edu.cn
工作及教育经历:
2004/03–2007/01，天津大学，药物科学与技术学院，博士
2001/09–2004/03，天津大学，化工学院化学工程专业，硕士
1994/09–1998/07，大连理工大学，化工学院化学工程系，学士
研究方向：
2007/01–至今，天津工业大学，环境与化学工程学院制药工程系，副教授
1998/07–2001/09，沈阳化工研究院，染料所/农药所，助理工程师
获奖与社会兼职：
2010 年桑麻奖——香港桑麻基金会
主持及参加的科研项目：
1. 2013年，The 13th Pacific Polymer Conference，中国台湾
2. 2014年，The 4th International Conference on Molecular Sensors and Molecular Logic Gates，
中国上海
3. 2014年，陕西省重点科技创新团队第四届学术论坛，中国西安
代表性学术论文：
1. Yan, F.Y*., Kong, D.P., Fu, Y. Ye., Q.H., Wang, Y.Y., and Chen, L. Construction of carbon nanodots/tungsten trioxide and their visible-light sensitive photocatalytic activity. Journal of Colloid and Interface Science 2016, 466, 268–274
2. Yan, F.Y*., Shi, D. C., Zheng, T.C., Yun, K.Y., Zhou, X.G., and Chen, L*., Carbon dots as nanosensor for sensitive and selective detection of Hg2+ and l-cysteine by means of fluorescence ―Off–On‖ switching. Sensors and Actuators B-Chemical 2016, 224, 926–935
3. Yan, F.Y*., Kong, D.P., Luo, Y.M., Ye, Q.H., He, J.J., Guo, X.F., and Chen, L. Carbon dots serve as an effective probe for the quantitative determination and for intracellular imaging of mercury(II). Microchimica Acta 2016, DOI, 10.1007/s00604-016-1788-5
4. Shi, D.C., Yan, F.Y*., Zhou, X.G., Zheng, T.C., Shi, Y. Y., Fu, W. G., and Chen, L. Preconcentration and fluorometric detection of mercury ions using magnetic core-shell chitosan microspheres modifiedwith a rhodamine spirolactam. Microchimica Acta 2016, 183(1), 319-327.
5. Gao Y.Z., He Y., Zhao Y.P., Chen L*., Yan, F.Y*. Fabrication of thermosensitive hydrogel-supported Ni nanoparticles with tunable catalytic activity for 4-nitropheno. J Mater Sci. 2016, 51, 3200–3210
6. Yan, F.Y*., Zheng, T.C., Shi, D.C., Zou, Y., Wang, Y., Fu, M.M., Chen, L., and Fu, W.G. Rhodamine-aminopyridine based fluorescent sensors for Fe3+in water, Synthesis, quantum chemical interpretation and living cell application. Sensors and Actuators B-Chemical 2015,
215, 598–606
7. Yan, F.Y., Zheng, T.C., Guo, S.S., Shi, D.C., Han, Z.Y., Zhou, S.Y.S., and Chen, L. New fluorescence probe for Fe(3+) with bis-rhodamine and its application as a molecular logic gate. Spectrochimica Acta Part A, Molecular and Biomolecular Spectroscopy 2015, 151,881-887
8. Zou, Y., Yan, F.Y.,*Zheng, T.C., Shi, D.C., Sun, F.Z., Yang, N., and Chen, L. Highly luminescent organosilane-functionalized carbon dots as a nanosensor for sensitive and selective detection of quercetin in aqueous solution. Talanta 2015, 135, 145-148
9. Shi, D. C., Yan, F.Y*., Zheng, T.C., Wang, Y. Y., Zhou, X.G., and Chen, L. P-doped carbonm dots act as nanosensor for trace 2,4,6-trinitrophenol detection and fluorescent reagent for bacterial labeling. RSC Advances 2015, 5, 98492-98499
10. Shi, D. C., Yan, F.Y*., Wang, M., Zou, Y., Zheng, T.C., Zhou, X.G., and Chen, L. Rhodamine derivative functionalized chitosan as efficient sensor and adsorbent for mercury(II) detection and removal. Materials Research Bulletin 2015, 70, 958-964
11. Ye, Q.H., Yan, F.Y*., Kong, D.P., Wang, J., Zhou, X.G*., and Chen, L. Synthesis of fluorescent polymers and their applications. Current Organic Chemistry 2015, 20(3),  266-288
12. Kong, D.P., Yan, F.Y.,* Shi, D.C., Ye, Q.H., Han, Z. Y., Chen, L., and Wang, L. Carbon dots, synthetic methods and applications as fluorescent probes for the detection of metal ions,inorganic anions and organic molecules. Journal of the Iranian Chemical Society 2015,
12(10), 1841-1857
13. 付杨，颜范勇*，郑坦承，母雪玲，孙凤展，陈莉*。反应型罗丹明类荧光探针。化学进展 2015, 27 (9), 1213-1229
14. Shi, D.C., Zhou, X.G., Zheng, T.C., Zou, Y., Guo, S.S., Lv, J., and Yan, F.Y*. Recognition and Fluorescent Sensing of Zinc Ions using Organic Fluorophores-based Sensor Molecules. Journal of the Iranian Chemical Society 2015, 12(2), 293-308
15. Zou, Y., Yan, F.Y∗., Dai, L.F., Luo, Y. M., Fu, Y. Yang, N., Wen, J.Y., and Chen, L. High Photoluminescent Carbon Nanodots and Quercetin-Al3+ Construct A Ratiometric Fluorescent Sensing System. Carbon 2014, 77, 1148–1156
16. Yan, F.Y∗., Zou, Y., Wang, M., Mu, X.L., Yang, N., and Chen, L. Highly photoluminescent carbon dots-based fluorescent chemosensors for sensitive and selective detection of mercury ions and application of imaging in living cells. Sensors and Actuators B-Chemical 2014,
192, 488–495
17. Wang, M., Yan, F.Y∗., Zou, Y., Chen, L., Yang, N., and Zhou, X.G. Recognition of Cu2+ and Hg2+ in physiological conditions by a new rhodamine based dual channel fluorescent probe.Sensors and Actuators B-Chemical 2014, 192, 512–521
18. Zheng, T.C., Yan, F.Y*., Shi, D.C., Zou, Y., Zhang, S.L., and Chen, L. Fluorescent Probes for Detection of Lead Ion. Recent Innovations in Chemical Engineering 2014, 7, 10-16,
19. 颜范勇∗,邹宇,王猛,代林枫,周旭光,陈莉。荧光碳点的制备及应用。化学进展 2014，26（1），61-74
20. Wang, M., Yan, F.Y*., Zou, Y., Yang, N., Chen, L*., and Chen, L.G. A rhodamine derivative as selective fluorescent and colorimetric chemosensor for mercury(II) in buffer solution, test strips and living cells. Spectrochimica Acta Part A, Molecular and Biomolecular
Spectroscopy 2014, 123, 216-223
21. 高友志，王猛，颜范勇*，陈莉*。水凝胶/金属纳米粒子复合物的制备及其在催化反应中 的应用。化学进展 2014，26（4），626-637
22. Yan, F.Y*., Wang, M., Cao, D.L., Yang, N., Fu, Y. Chen, L*., and Chen, L. G. New
fluorescent and colorimetric chemosensors based on the rhodamine detection of Hg2+ and Al 3+ and application of imaging in living cells. Dyes and Pigments 2013, 98(1), 42-50
23. Yan, F.Y., Wang, M., Cao, D.L., Guo, S.S., and Chen, L*. Preparation of thermosensitive, calix[4]arene incorporated P(NIPAM-co-HBCalix) hydrogel as a reusable adsorbent of nickel(II) ions. Journal of Polymer Science, Part A, Polymer Chemistry 2013,51(11),2401-2408
24. Yan, F.Y., Wang, M., Cao, D.L., Yang, N., Ma, B. and Chen, L*. Recognition preference of  rhodamine derivative bearing phthalimido gly for Hg2+ by UV-Vis and flourescence spectroscopy. Journal of Spectroscopy 2013, 1(1),1-7
25. Yan, F.Y., Cao, D.L., Yang, N., Wang, M., Dai, L.F., Li, C.Y. and Chen, L*. A rhodamine based fluorescent probe for Hg2+ and its application to cellular imaging. Spectrochimica Acta Part A, Molecular and Biomolecular Spectroscopy 2013, 106, 19-24
26. Yan, F.Y*., Li, C.Y., Liang, X.L., Guo, S.S., and Chen, L. Baeyer-Villiger reaction in different catalysis. Recent Patents on Chemical Engineering 2013, 6(1), 43-56
27. Wang, M., Yan, F.Y*., Cao, D.L., and Song, X.Y. A novel thermoresponsive P(NIPAAm-coCalix) hydrogel, synthesis, characterization and its sorption ability for metal ions. Advanced Materials Research 2013, 641-642(1), 325-328
28. Cao, D.L., Yan, F.Y*., Wang, M., Wen, J. Y., Li, X.F., Fu, Y. and Chen, L. Synthesis of rhodamine cinnamide and its use as a new fluorescence probe in fluorosepctrophotometric determination of mercury. Physical and Chemical Testing-Chemical 2013, 49(2), 138-142
29. Yan, F.Y., Cao, D.L., Yang, N., Yu, Q.H., Wang, M., and Chen, L*. A selective turn-on fluorescent chemosensor based on rhodamine for Hg2+ and its application in live cell imaging. Sensors and Actuators B-Chemical 2012, 162, 313-320
30. Yan, F.Y*., Cao, D.L., Wang, M., Yang, N., Yu, Q.H., Dai, L.F., and Chen, L. A new rhodamine-based "off-on" fluorescent chemosensor for Hg (II) ion and its application in imaging Hg (II) in living cells. Journal of Fluorescence 2012, 22(5), 1249-1256
31. Yan, F.Y*., Wang, M., Wen, J.Y., Fu, Y. and Chen, L. Solubility of fudosteine in some pure and mixed solvents from(278.15 to 308.15) K. Journal of Applied Solution Chemistry and Modeling 2012, 1, 65-73
32. 代林枫，颜范勇*，李楚盈，罗云梅，陈莉，非诺贝特印迹聚合物的制备与性能研究， 化学研究与应用 2012, 10-15
33. Yan, F.Y*., Chen, L. Solubility of (+)-(S)-2-(6-Methoxynaphthalen-2-yl) Propanoic Acid in Acetone, Methanol, Ethanol, Propan-2-ol, and Ethyl Ethanoate at Temperatures between (278 and 320) K, Journal of Chemical and Engineering Data, 2009, 54(3): 1117-1119
34. Liu,Qing-Hao, Yan Xi-Long, Guo Jin-Chun, Wang Dong-Hua, Li Lei, Yan FanYong, Chen LiGong, Spectrofluorimetric determination of trace nitrite with a novel fluorescent probe, Spectrochimica acta part A: molecular and biomolecular spectroscopy, 2009, 73(5):
789-793
35. He Xiaoling, Yu Shen, Dong YouYu, Yan Fanyong, Chen Li, Preparation and properties of a novel thermo-responsive poly(N-isopropylacrylamide) hydrogel containing glycyrrhetinic acid, Journal of Materials Science, 2009, 44(15): 4078-4086
36. Liu Qinghao, Liu Jia, Guo Jinchun, Yan Xilong, Wang Donghua, Chen Lei, Yan Fanyong, Chen Ligong. Preparation of polystyrene fluorescent microspheres based on some fluorescent labels. Journal of Materials Chemistry. 2009, 19(14): 2018-2025

jia33

碳点（CDs）作为一种新型的光致发光纳米材料，具有优异的光学特性、良好的生物相容性、低毒性、低成本和易于功能化等性能，在荧光传感、环境监测、药物传递、生物成像和光电器件等领域显示出巨大的潜力。多色CDs对于制造多色LED与WLED具有较高应用价值，有望替代传统的半导体基量子点和有机染料。但遗憾的是，绝大多数CDs都显示蓝绿色荧光，而高效长波（黄色和红色光区）发射的CDs并未得到广泛的研究，而且目前报道的长波长发射CDs的量子产率通常低于20%，很大程度上阻碍了CDs在发光器件领域的应用研究。前驱体和溶剂的选择对于能否得到多色发射的CDs有着至关重要的作用。迄今为止，少有研究报道使用相同的前体并仅通过改变反应溶剂成功合成可调荧光发射CDs的方法，并且尚未研究多色CDs对常见有机染料选择性的特殊影响。

        天津工业大学颜范勇课题组以柠檬酸和尼罗蓝A作为前体，通过改变反应溶剂体系从而控制带隙，成功获得了三色荧光发射CDs（B-、Y-和RCDs）。所选的前体和不同的溶剂是形成三种发射CDs的关键，详细的表征和密度泛函理论（DFT）计算进一步表明，CDs发出的荧光颜色差异与sp2共轭结构域的大小有关。此外，BCDs和YCDs均对苏丹红I具有较高的选择性和灵敏度。通过将CDs与基质混合得到了多色发射荧光粉、荧光膜、单色LED和WLED。该研究为调控CDs长波长发射提供了一种新视角。



        文章信息：Zhonghui Sun, Fanyong Yan*, Jing Xu, Hao Zhang & Li Chen. Solvent-controlled synthesis strategy of multicolor emission carbon dots and its applications in sensing and light-emitting devices. Nano Research https://doi.org/10.1007/s12274-021-3495-8.