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周少东
百人计划研究员 博士生导师
电话 0571-87951615
邮箱 szhou@zju.edu.cn
址 浙江大学玉泉校区教10-3203
研究方向
· 精细有机合成
· 气相化学
· C1 化学
2004-2008，浙江大学，学士
2008-2013，浙江大学，工学博士
2013-2017，柏林工业大学，博士后
2017-至今， 浙江大学，研究员，入选“青年##计划”
主要研究领域涉及气相化学与凝聚相化学。气相化学研究以一碳化学和金属有机化学为主：一碳化学研究包括甲烷活化转化、一氧化碳氧化、二氧化碳还原等；金属有机化学研究包括金属配合物气相异构化及与小分子反应等。凝聚相化学研究以精细化学品高效生产及转化为主，包括含氮及含硫有机物的合成转化、金属配合物催化等。
selected Publications:
Shaodong Zhou,* Xiaoyan Sun, Lei Yue, Cheng Guo, Maria Schlangen, and Helmut Schwarz*
Selective Nitrogen-Atom Transfer Driven by a Highly Efficient Intersystem Crossing in the [CeON]+/CH4 System
Angewandte Chemie International Edition 2018, 57, 15902-15906.
Sreekanta Debnath, Harald Knorke, Wieland Schöllkopf, Shaodong Zhou,* Knut R. Asmis,* and Helmut Schwarz*
Experimental Identification of the Active Site in the Heteronuclear [AlVOx]+•/CO/N2O (x = 3, 4) Redox Couples by Gas-Phase IR Spectroscopy
Angewandte Chemie International Edition 2018, 57, 7448-7452. VIP Paper
Xiaoyan Sun, Shaodong Zhou,* Lei Yue, Maria Schlangen, and Helmut Schwarz*
On the Origin of the Distinctly Different Reactivity Behavior of Ruthenium in [MO]+/CH₄ Systems (M = Fe, Ru, Os)
Angewandte Chemie International Edition 2018, 57, 5934-5937.
Shaodong Zhou, Lei Yue, Maria Schlangen, and Helmut Schwarz*
Electronic Origin of the Competitive Mechanisms in the Thermal Activation of Methane by the Heteronuclear Cluster Oxide [Al2ZnO4]•+.
Angewandte Chemie International Edition 2017, 56, 14297-14300.
Shaodong Zhou, Jilai Li, Marjan Firouzbakht, Maria Schlangen, and Helmut Schwarz*
Sequential Gas-Phase Activation of Carbon Dioxide and Methane by [Re(CO)2]+: The Sequence of Events Matters!
Journal of the American Chemical Society 2017, 139, 6169-6176.
Shaodong Zhou, Jilai Li, Maria Schlangen, and Helmut Schwarz*
On the Origin of Reactivity Enhancement/Suppression upon Sequential Ligation: [Re(CO)x]+/CH4 (x = 0 - 3) Couples.
Angewandte Chemie International Edition 2017, 56, 2951-2954.
Shaodong Zhou, Jilai Li, Maria Schlangen, and Helmut Schwarz*
On the Origin of the Remarkably Variable Reactivities of [AlCeOx]+ (x = 2 ‒ 4) Towards Methane as a Function of Oxygen Content.
Angewandte Chemie International Edition 2017, 56, 413-416.
Shaodong Zhou, Jilai Li, Maria Schlangen, and Helmut Schwarz*
Bond Activation by Metal-Carbene Complexes in the Gas phase.
Accounts of Chemical Research 2016, 49, 494-502.
Shaodong Zhou, Jilai Li, Maria Schlangen, and Helmut Schwarz*
On the Origin of the Efficient, Thermal Chemisorption of Methane to the Heteronuclear Metal-Oxide Cluster [Al₂TaO₅]+.
Angewandte Chemie International Edition 2016, 55, 14867-14871.
Shaodong Zhou, Jilai Li, Maria Schlangen, and Helmut Schwarz*
Thermal Dehydrogenation of Methane by [ReN]+.
Angewandte Chemie International Edition 2016, 55, 14863-14866.
Shaodong Zhou, Jilai Li, Maria Schlangen, and Helmut Schwarz*
Efficient Room-Temperature Activation of Methane by TaN+ under C-N Coupling.
Angewandte Chemie International Edition 2016, 55, 11678-11681.
Shaodong Zhou, Jilai Li, Maria Schlangen, and Helmut Schwarz*
Spin-selective, Thermal Activation of Methane by Closed-shell [TaO3]+.
Angewandte Chemie International Edition 2016, 55, 7257-7260.
Shaodong Zhou, Jilai Li, Maria Schlangen, and Helmut Schwarz*
The Unique Gas-phase Chemistry of the [AuO]+/CH4 Couple: Selective Oxygen-atom Transfer to Rather than Hydrogen-atom Abstraction from Methane.
Angewandte Chemie International Edition 2016, 55, 10877-10880.
Shaodong Zhou, Jilai Li, Maria Schlangen, and Helmut Schwarz*
Thermal Activation of Methane by [HfO]●+ and [XHfO]+ (X = F, Cl, Br, I) and The Origin of A Remarkable Ligand Effect.
Angewandte Chemie International Edition 2016, 55, 7685-7688.
Shaodong Zhou, Jilai Li, Xiao-Nan Wu, Maria Schlangen, and Helmut Schwarz*
Efficient Room-temperature, Au+-Mediated Coupling of a Carbene Ligand with Methane to Generate C2Hx (x = 4, 6).
Angewandte Chemie International Edition 2016, 55, 441-444.
专利
间接氢转移还原芳香烃的方法. CN102408291A. 2013-11-20
1,4,5,6-四氢哒嗪的制备方法. CN102060781A. 2011.05.18
手性胺的制备方法. CN102786420A. 2014-3-5
苯磺酰胺衍生物的制备方法. CN103012221A. 2014-4-16
由苯磺酰胺衍生物氨解制备有机胺的方法. CN103012154A. 2014-10-8
甲酰胺衍生物的制备方法. CN103012184A. 2014-7-2
磺酸的还原方法. CN102584651A. 2013-12-18
负载型salen锰配合物催化剂及其制备方法和应用. CN102580777A. 2013-11-20
卞胺的制备方法. CN102276377A. 2011.12.14
芳香腈的还原方法. CN102267915A. 2013-11-20
二苯乙烯或其衍生物的制备方法. CN102010278A. 2013-4-10
硫酚的制备方法. CN101709045A. 2013-12-18
一种N-环己烯基环己亚胺的制备方法. CN101318911A. 2008.12.10
3-甲氧基-N-甲基二苯胺的制备方法. CN101343238A. 2009.01.14
间乙氧基二苯胺的制备方法. CN101402578A. 2009.04.08
3,3’-(1,2-二氧乙基)双二苯胺的制备方法. CN101402579A. 2009.04.08
间溴乙氧基二苯胺的制备方法. CN101402581A. 2009.04.08
1,1,3,3-四甲基硫脲的制备方法. CN102558003A. 2013-11-20
一种基于反应-分离耦合生产叔丁胺的方法. CN101497572A. 2009.08.05
硫酚的制备方法. CN102531978A. 2012.07.04
N,N-二异丙基乙胺的制备方法. CN101759571A. 2010.06.30
4-甲硫基苯甲醛的制备方法. CN102731352A. 2012.10.17
负载型手性酮催化剂的制备方法及其应用. CN102580773A. 2012.07.18
2-氨基二苯硫醚的制备方法. CN102796031A. 2012.11.28
生产1,3-二氧六环的方法及所用装置和催化剂. CN102794184A. 2014-7-2
基于反应-分离耦合生产1,3-二氧六环的方法. CN102267974A. 2011.12.07
3-己炔-2，5-二醇的合成方法. CN102285867A. 2011.12.21
制备1,3-二氧戊环的方法及所用催化剂和装置. CN102794185A. 2012.11.28
基于反应-分离耦合生产1,3-二氧戊环的方法. CN102267972A. 2013-3-13
3-羟基-1,3-二氧六环的管道化合成方法. CN103588753A. 2014.02.19
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发表于 2018-12-13 23:05:42
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