山西大学化学化工学院杨恒权

kyuan · 发表于 2017-11-29 09:00:41

杨恒权，男，1976年出生于湖北省郧西县，教授，博士生导师，现任山西大学化学化工学院副院长。主要从事绿色催化研究。曾入选教育部新世纪优秀人才、青年三晋学者、山西省高等学校中青年拔尖人才、山西省高等学校优秀青年学术带头人、山西省学术技术带头人、山西省131领军人才、山西大学英才计划。担任Chinese Journal of Catalysis 编委。曾获辽宁省自然科学一等奖。
教育经历：
1995.9—1999.6，三峡大学，化学专业，获得理学学士学位
1999.9—2001.7，武汉大学，有机化学硕士研究生
2001.8—2004.6，武汉大学，物理化学专业，获得理学博士学位
工作经历:
2004.8—2007.8, 中科院大连化学物理研究所催化基础国家重点实验室，博士后，副研究员
2008.6—2008.9，中科院大连化学物理研究所催化基础国家重点实验室，访问教授
2007.9—至今，山西大学化学化工学院，教授
讲授课程：本科生《催化原理》
科研方向：绿色催化
主持科研项目：
1.国家自然科学基金重点项目（合作部分），2018-2022；
2.国家自然科学基金，2016－2019；
3.国家基金委-山西煤基低碳联合基金，2016－2018；
4.国家自然科学基金，2012－2015；
5.国家自然科学基金，2010－2012；
6.教育部新世纪优秀人才项目，2013－2015；
7.青年三晋学者，2016-2020；
8.山西省CO2重大专项子课题，2017-2019；
9.教育部博士点基金（博导类），2014-2016;
10.教育部博士点基金（新教师类），2009－2011；
11.山西省高等学校中青年拔尖人才项目，2012-2015；
12.山西省高等学校优秀青年教师学术带头人项目，2011－2013;
13.山西大学英才计划项目，2012；
14.中科院煤转化国家重点实验室基金，2015－2016；
15.中科院催化基础国家重点实验室基金，2008－2010；
16.中科院煤转化国家重点实验室基金，2010－2011；
17.山西省自然科学基金，2009－2011；
18.山西省人才引进与研发专项，2009－2011；
19.亚宝药业课题，2010－2012；
20.中利思创课题，2008－2009；
21.江苏省精细石油化工重点实验室基金，2009－2011；
22.太原市科技项目，依托山西世纪同兴科技有限公司，2012。

代表性论文：
1、Ming Zhang, Rammile Ettelaie, Tao Yan, Suojiang Zhang, Fangqin Cheng, Bernard P. Binks, and Hengquan Yang*, Ionic Liquid Droplet Micro-Reactor for Catalysis Reactions not at Equilibrium, J. Am. Chem. Soc., 2017, DOI: 10.1021/jacs.7b07731.
2、Tianyu Yang, Lijuan Wei, Lingyan Jing, Jifen Liang, Xiaoming Zhang, Min Tang, Michael J. Monteiro, Ying (Ian) Chen, Yong Wang, Sai Gu, Dongyuan Zhao, Hengquan Yang*, Jian Liu* and G. Q. Max Lu, Dumbbell-shaped amphiphilic Janus structured solid catalysts for efficient biphase-interface catalysis, Angew. Chem. Int. Ed., 2017,56, 8459-8463.
3、Xiaoming Zhang, Lingyan Jing, Lijuan Wei, Fengwei Zhang, and Hengquan Yang*, Semipermeable Organic-Inorganic Hybrid Microreactors for Highly Efficient and Size-Selective Asymmetric Catalysis, ACS Catal., 2017, 7, 6711-6718. (back cover)
4、Jifen Liang, Xiaoming Zhang, Lingyan Jing, Hengquan Yang*, N-doped ordered mesoporous carbon as a multifunctional support of ultrafine Pt nanoparticles for hydrogenation of nitroarenes, Chin. J. Catal., 2017, 38, 1252-1260.
5、Xia Rong, Hengquan Yang*, and Ning Zhao, Rationally Turning the Interface Activity of Mesoporous Silicas for Preparing Pickering Foam and "Dry Water", Langmuir, 2017, 33, 9025-9033.
6、Wei Xue, Hengquan Yang*, and Zhiping Du, Synthesis of pH-Responsive Inorganic Janus Nanoparticles and Experimental Investigation of the Stability of Their Pickering Emulsions, Langmuir, 2017, 33, 10283-10290.
7、Xiaoming Zhang, Lingyan Jing, Fangfang Chang, Shuai Chen, Hengquan Yang* and Qihua Yang, Positional immobilization of Pd nanoparticles and enzymes in hierarchical yolk-shell@shell nanoreactors for tandem catalysis, Chem. Commun., 2017, 53, 7780-7783.
8、Huan Chen, Houbing Zou, Yajuan Hao, Hengquan Yang*, Flow Pickering Emulsion Interfaces Enhance Catalysis Efficiency and Selectivity for Cyclization of Citronella, ChemSusChem, 2017, 10, 1989-1995.
9、Yajuan Hao, Xuan Jiao, Houbing Zou, Hengquan Yang*,Jian Liu*, Growing a hydrophilic nanoporous shell on a hydrophobic catalyst interface for aqueous reactions with high reaction efficiency and in situ catalyst recycling, J. Mater. Chem. A, 2017, 5, 16162-16170. (cover)
10、Fengwei Zhang*, Chao Zhao, Shuai Chen, Huan Li, Hengquan Yang*, Xian-Ming Zhang*,, In situ mosaic strategy generated Co-based N-doped mesoporous carbon for highly selective hydrogenation of nitroaromatics, J. Catal., 2017, 348, 212-222.
11、Xiaomin Ren, He Li, Jian Chen, Lijuan Wei, Arindam Modak, Hengquan Yang*, Qihua Yang*, N-doped porous carbons with exceptionally high CO2 selectivity for CO2 capture, Carbon, 2017, 114, 473-481.
12、Fen Xue, Yabin Zhang, Fengwei Zhang, Xiaomin Ren, Hengquan Yang*, Tuning the Interfacial Activity of Mesoporous Silicas for Biphasic Interface Catalysis Reactions, ACS Appl. Mater. Interfaces, 2017, 9, 8403-8412.
13、Ming Zhang, Lijuan Wei, Huan Chen, Zhiping Du, Bernard P. Binks, Hengquan Yang*, Compartmentalized Droplets for Continuous Flow Liquid Liquid Interface Catalysis, J. Am. Chem. Soc., 2016, 138, 10173-10183.
14、Lijuan Wei, Ming Zhang, Xiaoming Zhang, Hongchuan Xin, Hengquan Yang*, Pickering Emulsion as an Efficient Platform for Enzymatic Reactions without Stirring, ACS Sustainable Chem. Eng., 2016, 4, 6838-6843.
15、Jianping Huang, Fangqin Cheng, Bernard P. Binks, Hengquan Yang*, pH-Responsive Gas-Water-Solid Interface for Multiphase Catalysis, J. Am. Chem. Soc., 2015, 137, 15015-15025.
16、Hengquan Yang*, Luman Fu, Lijuan Wei, Jifen Liang, Bernard P. Binks, Compartmentalization of Incompatible Reagents within Pickering Emulsion Droplets for One-Pot Cascade Reactions, J. Am. Chem. Soc., 2015, 137, 1362-1371.
17、Wenjuan Zhang, Luman Fu, Hengquan Yang*, Micrometer-Scale Mixing with Pickering Emulsions: Biphasic Reactions without Stirring, ChemSusChem, 2014, 7, 391-396. (inside cover)
18、Hengquan Yang*, Ting Zhou, Wenjuan Zhang, A Strategy for Separating and Recycling Solid Catalysts Based on the pH-Triggered Pickering-Emulsion Inversion, Angew. Chem. Int. Ed., 2013, 52, 7455-7459.（VIP）
19、Hengquan Yang*, Lei Zhang, Lin Zhong, Qihua Yang, Can Li, Enhanced cooperative activation effect in the hydrolytic kinetic resolution of Epoxides on Co(salen) catalysts confined in nanocages, Angew. Chem. Int. Ed., 2007, 46, 6861-6865.
20、Jianping Huang, Hengquan Yang*, A pH-switched Pickering emulsion catalytic system: high reaction efficiency and facile catalyst recycling, Chem. Commun., 2015, 51, 7333-7336.
21、Qibiao Li, Ting Zhou, Hengquan Yang*, Encapsulation of Hoveyda-Grubbs(2nd) Catalyst within Yolk-Shell Structured Silica for Olefin Metathesis, ACS Catal., 2015, 5, 2225-2231.
22、Fengwei Zhang, Hengquan Yang*, Multifunctional mesoporous silica-supported palladium nanoparticles for selective phenol hydrogenation in the aqueous phase, Catal. Sci. Technol., 2015, 5, 572-577.
23、Luman Fu, Shuru Li, Zhongyuan Han, Huifang Liu, Hengquan Yang*, Tuning the wettability of mesoporous silica for enhancing the catalysis efficiency of aqueous reactions, Chem. Commun., 2014, 50, 10045-10048.
24、Huifang Liu, Zhiming Zhang, Hengquan Yang*, Fangqin Cheng, Zhiping Du, Recycling Nanoparticle Catalysts without Separation Based on a Pickering Emulsion/Organic Biphasic System, ChemSusChem, 2014, 7, 1888-1900.
25、Yuhong Yu, Luman Fu, Fengwei Zhang, Ting Zhou, Hengquan Yang*, Pickering-Emulsion Inversion Strategy for Separating and Recycling Nanoparticle Catalysts, ChemPhysChem, 2014, 15, 841-848.
26、Hengquan Yang*, Zhancheng Ma, Ting Zhou, Wenjuan Zhang, Jianbin Chao, Yong Qin, Encapsulation of an Olefin Metathesis Catalyst in the Nanocages of SBA-1: Facile Preparation, High Encapsulation Efficiency, and High Activity, ChemCatChem, 2013, 5, 2278-2287.
27、Shuru Li, Xuan Jiao, Hengquan Yang*, Hydrophobic Core/Hydrophilic Shell Structured Mesoporous Silica Nanospheres: Enhanced Adsorption of Organic Compounds from Water, Langmuir, 2013, 29, 1228-1237.
28、Haixia Wang, Hengquan Yang*, Huanrong Liu, Yuhong Yu, Hongchuan Xin, A Mesoporous Silica Nanocomposite Shuttle: pH-Triggered Phase Transfer between Oil and Water, Langmuir, 2013, 29, 6687-6696.(Cover)
29、Yajuan Hao, Yanzhu Chong, Shuru Li, Hengquan Yang*, Controlled Synthesis of Au Nanoparticles in the Nanocages of SBA-16: Improved Activity and Enhanced Recyclability for the Oxidative Esterification of Alcohols. J. Phys. Chem. C, 2012, 116, 6512-6519.
30、Hengquan Yang*, Yanzhu Chong, Xuekuan Li, Hui Ge, Weibin Fan, Jianguo Wang, Encapsulation of a catalytically active core with a nanoporous shell: a new strategy for designing size-selective catalysts, J. Mater. Chem., 2012, 22, 9069-9076.
31、Hengquan Yang*, Xuan Jiao, Shuru Li, Hydrophobic core-hydrophilic shell-structured catalysts: a general strategy for improving the reaction rate in water, Chem. Commun., 2012, 48, 11217-11219.
32、Hengquan Yang*, Guang Li, Zhancheng Ma, Magnetic core-shell-structured nanoporous organosilica microspheres for the Suzuki-Miyaura coupling of aryl chlorides: improved catalytic activity and facile catalyst recovery, J. Mater. Chem., 2012, 22, 6639-6648.
33、Jian Liu, Hengquan Yang, Freddy Kleitz, Zhigang Chen, Tianyu Yang, Ekaterina Strounina, Gaoqing Lu(Max)*, Shizhang Qiao*, Yolk-Shell Hybrid Materials with a Periodic Mesoporous Organosilica Shell: Ideal Nanoreactors for Selective Alcohol Oxidation. Adv. Funct. Mater., 2012, 22, 591-599.
34、Hengquan Yang*, Yunwei Wang, Yong Qin, Yanzhu Chong, Qiaozhen Yang, Guang Li, et al., One-pot preparation of magnetic N-heterocyclic carbene-functionalized silica nanoparticles for the Suzuki-Miyaura coupling of aryl chlorides: improved activity and facile catalyst recovery, Green Chemistry, 2011, 13, 1352-1361.
35、Guang Li, Hengquan Yang*, Wei Li, Guoliang Zhang, Rationally designed palladium complexes on a bulky N-heterocyclic carbene-functionalized organosilica: an efficient solid catalyst for the Suzuki-Miyaura coupling of challenging aryl chlorides, Green Chemistry, 2011, 13, 2939-2947.
36、Hengquan Yang*, Zhancheng Ma, Yuekui Wang, Yunwei Wang, Li Fang, Hoveyda-Grubbs catalyst confined in the nanocages of SBA-1: enhanced recyclability for olefin metathesis, Chem. Commun., 2010, 46, 8659-8661.
37、Hengquan Yang*, Guang Li, Zhancheng Ma, Jianbin Chao, Zhiqiang Guo, Three-dimensional cubic mesoporous materials with a built-in N-heterocyclic carbene for Suzuki-Miyaura coupling of aryl chlorides and C(sp(3))-chlorides, J. Catal., 2010, 276, 123-133.
38、Hengquan Yang*, Xiaojing Han, Guang Li, Zhancheng Ma, Yajuan Hao, Mesoporous Ethane-Silicas Functionalized with a Bulky N-Heterocyclic Carbene for Suzuki-Miyaura Coupling of Aryl Chlorides and Benzyl Chlorides, J. Phys. Chem. C, 2010, 114, 22221-22229.
39、Hengquan Yang*, Xiaojing Han, Zhancheng Ma, Runqin Wang, Jing Liu, Xiangfei Ji, Palladium-guanidine complex immobilized on SBA-16: a highly active and recyclable catalyst for Suzuki coupling and alcohol oxidation, Green Chemistry, 2010, 12, 441-451.
授权专利：一种醇(醛)氧化制备有机羧酸酯的催化剂，ZL 2010 1 0224396.X
联系方式：太原市坞城路92号山西大学化学化工学院；邮编：030006
邮箱：hqyang@sxu.edu.cn

xiangshanxing · 发表于 2019-1-5 16:58:43

化学化工学院杨恒权教授指导博士生魏丽娟、刘大伟在绿色催化材料研究中取得新进展，成功制备了具有复杂内部结构的微米球催化材料，分别发表于国际重要期刊Nature子刊NPG Asia Mater.（2018，DOI：10.1038/s41427-018-0083-9）和Angew. Chem. Int. Ed. (2018, 57, 10899-10904)，并被Nature杂志作为亮点报道（https://www.nature.com/articles/d41586-018-05740-7）,同时国际著名期刊邀请撰写新概念。

基于Pickering 乳液限域空间制备具有不同内部结构微球示意图

氧化硅、碳材料广泛应用于化学工业，然而获得其微毫米尺寸微球目前依赖于成型技术，尚无直接的合成方法，特别是具有复杂内部结构的氧化硅、碳材料微球在合成上极具有挑战性。杨恒权课题组在前期乳液限域催化研究的基础上，提出了乳滴限域合成策略，即以固体颗粒稳定的Pickering乳滴界面为模板生长微米球的外壳，利用表面活性剂分子在乳滴限域空间内自组装诱导溶胶-凝胶过程，构建复杂的内部结构。该策略成功得到中空、多腔室、多核、核-壳、实心等新奇结构微米球，实现了外壳层和内部结构的独立调控。通过对材料中间状态的捕捉等实验研究，揭示了乳滴的空间限域效应在微球内部结构演变及有序介孔结构形成中所起的关键作用。这些新奇结构的微球具有高的渗透性和机械强度，可直接填充在固定床反应器中，用于连续流动过程，在二氧化碳吸附、催化加氢反应等领域展现了优异的性能，优于同类材料，显示了为良好的应用前景。

该项研究得到国家基金重点项目（21733009）、国家基金（21573136）、低碳联合基金（U1510105）、青年三晋学者及山西省研究生创新项目的经费支持。

fengxixi · 发表于 2019-4-26 09:22:31

CO2捕集材料的有效设计是一项持续的挑战。山西大学杨恒权课题组报道了一个概念设计，通过利用固液混合超级粒子（SLHSP）来克服与液体和固体CO2捕获材料相关的当前限制。

为了合并液体和固体材料各自的优点，研究者详细介绍了SLHSP吸附剂概念的设计，该吸附剂由疏水多孔壳和四乙烯五胺（TEPA）-介孔SiO2复合芯制成，其中液体和固体在微观层面上为分层组织。具体制备原理涉及疏水SiO2纳米粒子在液态大理石表面上的组装，以及亲水SiO2纳米粒子和TEPA在液态大理石内部的共组装。胺和SiO2之间强烈的界面吸附力和强相互作用被认为是高稳健性的关键因素。

这种结构的独特特征是多方面的：1）高粘度的TEPA被划分为微小的液滴，实现了高的表面积与体积比；2）由于液体内部存在“孔隙”，TEPA的范围可及性进一步增强；3）通过固液相互作用显著增强力学强度；4）由于存在疏水壳，胺损失和设备腐蚀被显著抑制。

该方法能够可靠地控制SLHSP的内部结构、尺寸和力学强度。获得的SLHSP在工业上表现出优异的CO2吸附能力、高吸附速率、长期稳定性和突出的低胺损失能力。出色的性能归功于独特的结构，其在微尺度上分层组织液体和固体。该工作在实验和理论上研究了支持SLHSP形成的基本原理以及对其吸附行为的见解。

Xia Rong, Rammile Ettelaie, Sergey V.Lishchuk, Huaigang Cheng, Ning Zhao, Fukui Xiao, Fangqin Cheng, Hengquan Yang.Liquid marble-derived solid-liquid hybrid superparticles for CO2capture. Nature Communications, 2019.

DOI: 10.1038/s41467-019-09805-7

https://www.nature.com/articles/s41467-019-09805-7

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