陕西师范大学化学化工学院有机化学石先莹

zhongyuzhong

石先莹
职  称：教授（博士生导师）
毕业学校：陕西师范大学
电  话：029-81530726
电子邮箱：shixy@snnu.edu.cn
研究方向：绿色催化合成
个人简介
        2008年12月份获得工学博士学位，2011年10月至2013年8月，在加拿大麦吉尔大学做访问教授。主要从事高效串联反应、H2O2 选择性氧化等绿色催化合成方面的研究工作，在环境友好反应介质绿色过程替代等方面具有较好的研究积累。目前主持国家自然科学基金面上项目2项、参与国家自然科学基金重点项目一项，主持完成国家自然科学基金、陕西省自然科学基金、西安市工业应用技术研究项目等5 项。在J. Am. Chem. Soc.、Angew Chem. Int. Ed.、Org. Lett.、Adv. Synth. Catal.、Chem.Eur. J.、J. Org. Chem.等本领域主流学术期刊发表研究论文50 余篇，申请中国发明专利10件，其中授权4 件，获陕西省高等学校科学技术奖一等奖（2016 年，第二完成人）和陕西省科学技术奖二等奖（2016 年，第二完成人）。参编《有机化学学习指导与习题详解》和《中级有机化学》，编著《过渡金属催化的碳氢键官能团化反应》。研究兴趣：(1) 过氧化氢为氧源的绿色催化氧化反应；(2)过渡金属催化碳氢键活化的高效串联反应。
代表性成果
1. Peng-Min Wang, Fan Pu, Ke-Yan Liu, Chao-Jun Li, Zhong-Wen Liu, Xian-Ying Shi*, Juan Fan, Ming-Yu Yang, Jun-Fa Wei, Catalyst-free three-component tandem CDC cyclization: convenient access to isoindolinones from aromatic acid, amides, and DMSO by a pummerer-type rearrangement, Chem. Eur. J., 2016, 22, 6262–6267.
2. Xian-Ying Shi*, Wen-Jing Han, Chao-Jun Li*, Transition-metal-catalyzed direct addition of aryl C–H bonds to unsaturated electrophiles, Chem. Rec., 2016, 16, 1178–1190.
3. Juan Fan, Fan Pu, Man Sun, Zhong-Wen Liu, Xiao-Yan Han, Jun-Fa Wei, Xian-Ying Shi*, Immobilized bis-layered ionic liquids/peroxotungstates as an efficient catalyst for selective oxidation of alcohols in neat water, New J. Chem., 2016, 40, 10498–10503.
4. Xian-Ying Shi*, Ke-Yan Liu, Juan Fan, Xue-Fen Dong, Jun-Fa Wei, Chao-Jun Li*, A convenient synthesis  of N-aryl benzamides by rhodium-catalyzed ortho-amidation and decarboxylation of benzoic acids, Chem. Eur. J., 2015, 21, 1900–1903.
5. Xian-Ying Shi*, Man Sun, Juan Fan, Peng-Min Wang, Wen-Juan Ma, Jun-Fa Wei*, Deep oxidative desulfurization of benzothiophene and dibenzothiophene with a peroxophosphotungstate–ionic liquid brush assembly, Appl. Organometal. Chem., 2015, 29, 633–637.
6. Xue-Fen Dong, Juan Fan, Xian-Ying Shi*, Ke-Yan Liu, Peng-Min Wang, Jun-Fa Wei*, Ruthenium (II)-catalyzed N-substituted phthalimide synthesis via C?H activation/[3+2] annulations, J. Organometal. Chem., 2015, 779, 55–61.
7. Xian-Ying Shi*, Xue-Fen Dong, Juan Fan, Ke-Yan Liu, Jun-Fa Wei, Chao-Jun Li*, Ru(II)-catalyzed ortho-amidation and decarboxylation of aromatic acids: a versatile route to meta-substituted N-aryl benzamides, Sci. China. Chem., 2015, 58, 1286–1291.
8. Xian-Ying Shi, Andrea Renzetti, Soumen Kundu, Chao-Jun Li*, A rhodium-catalyzed cascade cyclization: direct synthesis of N-substituted phthalimides from isocyanates and benzoic acids, Adv. Synth. Catal., 2014, 356, 723–728.
9. Xian-Ying Shi, Chao-Jun Li*, Synthesis of indene frameworks via rhodium-catalyzed cascade cyclization of aromatic ketone and unsaturated carbonyl compounds, Org. Lett., 2013, 15, 1476–1479.
10. Xian-Ying Shi, Chao-Jun Li*, A novel Rhodium-catalyzed cascade cyclization: direct synthesis of 3-substituted phthalides from aldehydes and aromatic acids, Adv. Synth. Catal., 2012, 354, 2933–2938. (Highlighted by Synfacts 2013, 9(5), 0082).