上海交通大学化学化工学院高分子系郑思珣

sanpang

郑思珣,上海交通大学教授、博士生导师。1997年获中国科技大学高分子化学与物理专业博士学位。1992年7月起任中国科技大学高分子科学与工程系助教、讲师(1995年)、副教授(1998年)。分别于1996年和1998年两次赴香港科技大学化学工程系做访问学者。1999年1月, 获德意志研究联合会资助，赴德国高分子研究所(Deutsches Kunststoff-Institut, Darmstadt, Germany)及达姆施塔特工业大学(TechnischeUniversitaet Darmstadt, Germany)物理系从事博士后研究。1999年9月转至美国加州大学欧文分校(University of California, Irvine, USA)化学系，为NationalScience Foundation (NSF)博士后研究员。2001年9月加入上海交通大学任高分子科学与工程系教授。先后承担或参加国家自然科学基金、中科院院长基金以及国家部委科研基金的研究工作; 2002年获“教育部优秀青年教师资助计划”基金支持，2004年获上海市“曙光学者”称号，2009年获上海市“育才”奖。已在Advanced Materials, Chemistry of Materials, Macromolecules, Journalof Physical Chemistry, Polymer, Journal of Polymer Science等国际学术期刊发表SCI收录的论文180余篇，论文被国际同行引用(SCI他引) 超过3500次。

联系方式：

上海市闵行区东川路800号

上海交通大学化学化工学院

邮编：200240

Email: szhengAT sjtu DOT cn

Tel: 021-54743278

Fax: 021-54741297

主要研究方向：

1、热固性聚合物的结构与性能：反应诱致微相分离、自组装行为以及材料断裂力学;
2、含笼型硅氧烷(Polyhedral Oligomeric Silsesquioxanes, POSS)的聚合物的结构与性能;
3、有机-无机复合聚合物水凝胶的微结构与凝胶行为;
4、具有拓扑结构高分子的合成及其微结构研究;
5、高分子固体核磁共振波谱研究(H-1、H-2、Si-29、C-13 CP/MAS NMR等)：a)多组分高分子体系的 相结构及其大分子动力学研究；b)有机/无机纳米复合材料中的组分间相互作用研究。

近年来发表的部分论文

1. Kun Wei, Lei Wang, Lei Li, SixunZheng*, Synthesis and Characterization of Bead-like Poly(N-isopropylacrylamide)with Double Decker Silsesquioxanes in the Main Chains, Polymer Chemistry, 2015,6, 256-269

2. Houluo Cong, Jingang Li, Lei Li, SixunZheng*, Dielectric Constant Enhancement of Epoxy Thermosets via Formation ofPolyelectrolyte Nanophases, Journal of Physical Chemistry B, 2014, 118,14703                                      

3. Jingang Li, Houluo Cong, Lei Li,Sixun Zheng*, Thermoresponse Improvement of Poly(N-isopropylacrylamide)Hydrogels via Formation of Poly(sodium p-styrene sulfonate) Nanophases, ACSApplied Materials & Interfaces, 2014, 16, 13677

4. Yulin Yi, Lei Li, Sixun Zheng*,Poly(epsilon-caprolactone)-block-poly(N-vinylpyrrolidone) Diblock CopolymersGrafted from Macrocyclic Oligomeric Silsesquioxane, Polymer, 2014, 55, 3925

5. Houluo Cong, Lei Li, Sixun Zheng*,Formation of Nanostructures in Thermosets Containing Block Copolymers: FromSelf-assembly to Reaction-induced Microphase Separation Mechanism, Polymer,2014, 55, 1190

6.Chongyin Zhang, Lei Li, Houluo Cong,Sixun Zheng*, Poly(methyl methacrylate)-block-poly(N-vinyl pyrrolidone) DiblockCopolymer: a Facile Synthesis via Sequential Radical Polymerization Mediated byIsopropylxanthic Disulfide and Its Nanostructuring Polybenzoxazine Thermosets,Journal of Polymer Science, Part A: Polymer Chemistry, 2014, 52, 952

7.Kun Wei, Lei Li, Sixun Zheng*,Organic-Inorganic Random Copolymers from Methacrylate-terminated Poly(ethyleneoxide) with 3-Methacryloxypropyl heptaphenyl Polyhedral OligomericSilsesquioxane: Synthesis via RAFT Polymerization and Self-assembly Behavior,Soft Matter, 2014, 10, 383

8. Kun Wei, Lei Wang, Sixun Zheng*,Organic-inorganic copolymers with double-decker silsesquioxane in the mainchains by polymerization via click chemistry, Journal of Polymer Science, PartA: Polymer Chemistry, 2013, 51, 4221  

9.Lei Wang, Chongyin Zhang, Houluo Cong,Lei  Li, Sixun Zheng*, Xiuhong Li, Jie Wang, Formation of nanophases inepoxy thermosets containing amphiphilic block copolymers with linear andstar-like topologies, Journal of Physical Chemistry B, 2013, 117(27),8256  

10. Chongyin Zhang, Lei Li, Sixun Zheng*,"Formation and Confined Crystallization of Polyethylene Nanophases inEpoxy Thermosets", Macromolecules, 2013, 46, 2740.  

11. Lei Wang, Jingang Li, Lei Li, SixunZheng*, Organic-inorganic Hybrid Diblock Copolymer Composed ofPoly(ε-caprolactone) and Poly(MA POSS): Synthesis and Its Nanocomposites withEpoxy Resin, Journal of Polymer Science, Part A: Polymer Chemistry, 2013, 51,2079  

12. Kun Wei, Lei Wang, Sixun Zheng*,Organic-Inorganic Polyurethanes with 3,13-DihydroxypropyloctaphenylDouble-Decker Silsesquioxane Chain Extender, Polymer Chemistry, 2013, 4,1501

13. Houluo Cong, Lei Li, Sixun Zheng*,Poly(N-isopropylacrylamide)-block-poly(vinyl pyrrolidone) Block CopolymerNetworks:  Synthesis and Rapid Thermoresponse of Hydrogels, Polymer, 2013,54, 1370.

14. Rentong Yu, Sixun Zheng*, Xiuhong Li,Jie Wang,  Reaction-induced Microphase Separation in Epoxy Thermosets ContainingBlock Copolymers Composed of Polystyrene and Poly(e-caprolactone): Influence ofCopolymer Architectures on Formation of Nanophases, Macromolecules, 2012, 45, 9155.

15. Liliang Zhu, Chongyin Zhang, JinHan, Sixun Zheng*, Formation of Nanophases in Epoxy Thermosets ContainingOrganic-Inorganic Macrocyclic Molecular Brush withPoly(ε-caprolactone)-block-polystyrene Side Chains, Soft Matter, 2012, 8, 7062.

16. Qinqin Zheng, Sixun Zheng*, FromPoly(N-isopropylacrylamide)-block-poly(ethylene oxide)-block-poly(N-isopropylacrylamide) Triblock Copolymer toPoly(N-isopropylacrylamide)-block-poly(ethylene oxide) Hydrogels: Synthesis andRapid Deswelling and Reswelling Behavior of Hydrogels, Journal of PolymerScience, Part A: Polymer Chemistry, 2012, 50, 1717

17. Lei Wang, Chongyin Zhang, SixunZheng*, Organic-inorganic Poly(hydroxyether of bisphenol A) with Double-deckerSilsesquioxane in the Main Chains, Journal of Materials Chemistry, 2011, 21,19344.

18. Fangping Yi, Rentong Yu, Sixun Zheng*,Self-organized Thermosets from Epoxy and Poly(2,2,2-trifluoroethylacrylate)-block-poly(glycidyl methacrylate) Diblock Copolymer: Demixing ofReactive Blocks and Thermomechanical Properties, Polymer, 2011, 52, 5669.

19. Rentong Yu, Sixun Zheng*,Morphological Transition from Spherical to Lamellar Nanophases in EpoxyThermosets Containing Poly(ethyleneoxide)-block-poly(ε-caprolactone)-block-polystyrene Triblock Copolymer byHardeners, Macromolecules, 2011, 44,8546.

20. Ke Zeng, Lei Wang, Sixun Zheng*, Nanostructuresand Surface Hydrophobicity of Epoxy Thermosets ContainingHepta(3,3,3-trifluropropyl) Polyhedral Oligomeric Silsesquioxane-cappedPoly(hydroxyether of bisphenol A) Telechelics, Journal of Colloid and InterfaceScience, 2011, 363, 250.

21.Junzhang Song, Rentong Yu, Lei Wang,Sixun Zheng*, Poly(N-vinylpyrrolidone)-grafted Poly(N-isopropylacrylamide)Copolymers: Synthesis, Characterization and Rapid Deswelling and ReswellingBehavior of Hydrogels, Polymer, 2011, 52, 2340

22. Lei Wang, Ke Zeng, Sixun Zheng*,Hepta(3,3,3-trifluoropropyl) Polyhedral Oligomeric Silsesquioxane-cappedPoly(N-isopropylacrylamide) Telechelics: Synthesis and Behavior of PhysicalHydrogels, ACS Applied Materials & Interfaces, 2011, 3, 898

23.Wenchun Fan, Lei Wang, Sixun Zheng*,Double Reaction-induced Microphase Separation in Epoxy Resin ContainingPolystyrene-block- poly(ε-caprolactone)-block-poly(n-butyl acrylate) ABCTriblock Copolymer, Macromolecules, 2010, 43, 10600

24.Di Hu, Sixun Zheng*, Reaction-inducedMicrophase Separation in Polybenzoxazine Thermosets Containing Poly(N-vinylpyrrolidone)-block- polystyrene Diblock Copolymer, Polymer, 2010,51, 6346

25.Di Hu, Chongyin Zhang, Rentong Yu, LeiWang, Sixun Zheng*, Self-Organized Thermosets Involving Epoxy andPoly(ε-caprolactone)-block-poly(ethylene-co-ethylethylene)-block-poly(ε-caprolactone) Amphiphilic Triblock Copolymer,Polymer, 2010, 51, 6047

26.Di Hu, Zhiguang Xu, Ke Zeng, SixunZheng*, From Self-organized Novolac Resins to Ordered Nanoporous Carbons,Macromolecules, 2010, 43, 2960

27.Lei Wang, Sixun Zheng*, Morphology andThermomechanical Properties of Main-chain Polybenzoxazine-block-PolydimethylsiloxaneMultiblock Copolymers, Polymer, 2010, 51, 1124

28.Jin Han, Sixun Zheng*, Organic-inorganicHybrid Brushes Consisting of Macrocyclic Oligomeric Silsesquioxane andPoly(ε-caprolactone): Synthesis, Characterization and SupramolecularInclusion Complexation with alfa-Cyclodextrin, Journal of Polymer Science PartA: Polymer Chemistry, 2009, 47, 6894

29.Ke Zeng, Lei Wang, Sixun Zheng*, RapidDeswelling and Reswelling Response of Poly(N-isopropylacrylamide) Hydrogels viaFormation of Interpenetrating Polymer Networks with Polyhedral OligomericSilsesquioxane-capped Poly(ethylene oxide) Amphiphilic Telechelics, Journal ofPhysical Chemistry B, 2009, 113, 11831

30.Xingtian Yang, Fangping Yi, Zhirong Xin,Sixun Zheng*,  Morphology and Mechanical Properties of NanostructuredBlends of Epoxy Resin with Poly(epsilon-caprolactone)-block-Poly(butadiene-co-acrylonitrile)-block-Poly(epsilon-caprolactone) Triblock Copolymer, Polymer, 2009, 50, 4089

31.Fangping Yi, Sixun Zheng*, Tianxi Liu,Nanostructures and Surface Hydrophobicity of Self-assembled Thermosets involvingEpoxy Resin and Poly(2,2,2-trifluoroethyl acrylate)-block-poly(ethylene oxide)Amphiphilic Diblock Copolymer, Journal of Physical Chemistry B, 2009, 113, 1857

32.Ke Zeng, Lei Wang, Sixun Zheng*, XuefengQian, Self-assembly Behavior of Hepta(3,3,3-trifluropropyl) PolyhedralOligomeric Silsesquioxane-capped Poly(epsilon-caprolactone) in Epoxy Resin :Nanostructures and Surface Properties, Polymer, 2009, 50, 685

33.Fangping Yi, Sixun Zheng*, Effect ofHydrophobic Polystyrene Microphases on Temperature-responsive Behavior ofPoly(N-isopropylacrylamide) Hydrogels, Polymer, 2009, 50, 670

34.Wenchun Fan, Lei Wang, Sixun Zheng*,Nanostructures in Thermosetting Blends of Epoxy Resin withPolydimethylsiloxane-block-Poly(epsilon-caprolactone) -block-Polystyrene ABCTriblock Copolymer, Macromolecules, 2009, 42, 327

35.Wei Gong, Ke Zeng, Lei Wang, SixunZheng*, Poly(hydroxyether of bisphenol A)-block-PolydimethylsiloxaneAlternating Block Copolymer and Its Nanostructured Blends with Epoxy Resin,Polymer, 2008, 49, 3318

36.Wenchun Fan, Sixun Zheng*,Reaction-induced Microphase Separation in Thermosetting Blends of Epoxy Resinwith Poly(methyl methacrylate)-block- Polystyrene Block Copolymers: Effect ofTopologies of Block Copolymers on Morphological Structures, Polymer, 2008,49,3157

37.Jin Han, Sixun Zheng*, Highly PorousPolysilsesquioxane Networks via Hydrosilylative Polymerization of MacrocyclicOligomeric Silsesquioxanes, Macromolecules, 2008, 41, 4561

38.Fanliang Meng, Zhiguang Xu, SixunZheng*, Microphase Separation in Thermosetting Blends of Epoxy Resin andPoly(epsilon-caprolactone)- block-Polystyrene Diblock Copolymers,Macromolecules, 2008, 41, 1411

huachuan

热固性树脂中嵌段共聚物的原位合成、纳米结构的调控以及材料的结构与性能研究
批准号        51973113       
项目负责人        郑思珣       
依托单位        上海交通大学
资助金额        61.00万元       
项目类别        面上项目       
研究期限        2020 年 01 月 01 日 至2023 年 12 月 31 日