复旦大学化学系有机化学张俊良

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报告题目: SadPhos Never Make You Sad
报告人: 张俊良 教授，博导
复旦大学化学系
上海市淞沪路 2005 号江湾化学楼 A7001 室
电话：021-31249180
E-mail: junliangzhang@fudan.edu.cn
报告时间：2019 年 05 月 18 日(星期六) 15:00~16:30
报告地点：同济大学 化学馆 241 室


研究方向：
主要研究有机合成方法学研究，包括烯炔与小环化学，不对称催化，近年来设计和发展了一系列手性膦催化剂和配体。教育部创新团队学术带头人，上海市东方学者(跟踪)，2014 年国家杰出青年基金，上海市浦江计划，曙光计划，上海市优秀学科带头人。先后主持自然基金委面上项目 4 项，973 项目参与 2 项，子课题负责人 1 项，发表文章 180 余篇，撰写英文章节 6 章，作为《Comprehensive Organic Synthesis II》第 4 卷主编之一。
报告摘要：
Since 2014, we have developed a new class of chiral sulfonamidephosphines (SadPhos), which are easily made from inexpensive commercially available tert-butanesulfinamide.in 2-5 steps in garm-sacle. Sadphos have shown good performance in various asymmetric metal-catalyzed reactions including gold-catalyzed cyclization and cycloaddition reactions, copper-catalyzed cycloaddition, and palladium-catalyzed cross-coupling reaction and domino reactions. Besides as the chiral ligands, Sadphos can be as organocatalysts and applied in R-C reaction and allylation and cycloaddition. Sadphos never make us sad so far and we believe Sadphos will never make you sad in future!