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张袁斌,理学博士,浙江大学助理研究员,2018年6月毕业于浙大化学系。 博士期间从事基于硼烷化学的有机方法学研究(B-H键活化)及其在材料化学、药物化学等领域的应用;博后期间从事阴离子杂化多孔材料及其在气体分离领域的应用,发表论文十余篇,一作/共同一作7篇,申请专利2项,主持博士后面上基金和青年基金各一项。
张袁斌
博士 | 博士后 助理研究员
学科 化学工程与技术
单位 化学工程与生物工程学院
邮箱 ybzhang@zju.edu.cn
研究方向
· 金属有机化学
· 有机方法学
· 惰性键活化
· 多孔材料设计
· 化工分离
2009.9-2013.6 南京理工大学化工学院 本科 制药工程专业(工学学士)和英语专业(文学学士)
2013.9-2018.6. 浙大化学系 直博 理学博士 导师:Simon Duttwyler (https://person.zju.edu.cn/duttwyler#0)
2017.9-2018.3 加州大学洛杉矶分校 联合培养 导师:Alex Spokoyny(https://www.organomimetic.com)
2018.7- 浙大化学工程与生物工程学院 博士后 导师: 邢华斌 (https://person.zju.edu.cn/xinghb)
代表性论文:
1. Y. Zhang, J. Liu, S. Duttwyler, Synthesis and Structural Characterization of Ammonio/Hydroxo Undecachloro‐closo‐Dodecaborates [B12Cl11NH3]–/[B12Cl11OH]2– and Their Derivatives. Eur. J. Inorg. Chem. 2015, 5158–5162.
2. Y. Zhang, Y. Sun, F. Lin, S. Duttwyler, Rhodium(III)‐Catalyzed Alkenylation–Annulation of closo‐Dodecaborate Anions through Double B−H Activation at Room Temperature. Angew. Chem. Int. Ed. 2016, 55, 15609-15614.
3. Y. Zhang, T. Wang, L. Wang, Y. Sun, F. Lin, J. Liu, S. Duttwyler. RhIII‐Catalyzed Functionalization of closo‐Dodecaborates by Selective B-H Activation: Bypassing Competitive C-H Activation. Chem.– Eur J. 2018, 24 (59), 15812-15817. (Frontispiece, hot paper)
4. Y. Zhang, Y. Sun, T. Wang, J. Liu, B. Spingler, S. Duttwyler. Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B12H11NH3]−, Molecules, 2018, 23 (12), 3137
5. F. Lin, Y. Shen, Y. Zhang, Y. Sun, J. Liu, S. Duttwyler, Fusing carborane carboxylic acids with alkynes: 3D analogues of isocoumarins via regioselective B− H activation. Chem. Eur. J. 2018, 24, 551-555. (cover feature, hot paper)
6. Y. Sun, J. Zhang, Y. Zhang, J. Liu, S. van der Veen, S. Duttwyler The closo‐Dodecaborate Dianion Fused with Oxazoles Provides 3D Diboraheterocycles with Selective Antimicrobial Activity Chem. Eur. J. 2018, 24 (41), 10364-10371. (cover feature, hot paper)
博士后期间课题:利用硼烷阴离子作为独特配体构建多孔材料,应用于低碳烃的选择性分离。
代表性论文:
1. Y. Zhang, L. Yang, L. Wang, X. Cui, H. Xing. Pillar iodination in functional boron cage hybrid supramolecular frameworks for high performance separation of light hydrocarbons, J. Mater Chem. A. 2019, 7, 27560-27566.
2. Y. Zhang, L. Yang, L. Wang, S. Duttwyler, H. Xing. A Microporous Metal‐Organic Framework Supramolecularly Assembled from a CuII Dodecaborate Cluster Complex for Selective Gas Separation, Angew. Chem. Int. Ed. 2019, 58, 8145-8150.
3. Y. Huang, Y. Zhang (equal contribution), H. Xing. Separation of light hydrocarbons with ionic liquids: A review. Chinese J. Chem. Eng., 2019, 27, 1374-1382.
4. L. Yang, X. Cui, Y. Zhang, Q. Yang, H. Xing A highly sensitive flexible metal–organic framework sets a new benchmark for separating propyne from propylene. J. Mater. Chem. A, 2018, 6, 24452-24458.
5. L. Yang, X. Cui, Y. Zhang, Q. Wang, Z. Zhang, X. Suo, H. Xing. Anion Pillared Metal–Organic Framework Embedded with Molecular Rotors for Size-Selective Capture of CO2 from CH4 and N2. ACS. Sustain. Chem. Eng. 2019, 7 (3), 3138-3144.
6. J. Cui, Z. Zhang, B. Tan, Y. Zhang, P. Wang, X. Cui, H.Xing, Efficient Separation of n‐Butene and iso‐Butene by Flexible Ultramicroporous Metal‐Organic Frameworks with Pocket‐like Cavities. Chem.-Asian J. doi.org/10.1002/asia.201900735.
7. L .Wang, Y. Zhang, R. Du, H. Yuan, Y. Wang, J. Yao, H. Li. Selective One‐Step Aerobic Oxidation of Cyclohexane to ϵ‐Caprolactone Mediated by N‐Hydroxyphthalimide (NHPI). ChemCatChem, 2019, 11 (9), 2260-2264. (cover feature)
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