科研成果与代表作 SELECTED PUBLICATIONS
The Essential Role of Bond Energetics in C-H Activation/Functionalization, X.-S. Xue, P. Ji, B. Zhou, J.-P. Cheng, Chem. Rev. 2017, DOI: 10.1021/acs.chemrev.6b00664.
Asymmetric Conjugate Addition of Benzofuran-2-ones to Alkyl 2-Phthalimidoacrylates: Modeling Structure-Stereoselectivity Relationships with Steric and Electronic Parameters, C. Yang, E.-G. Zhang, X. Li, J.-P. Cheng, Angew. Chem. Int. Ed. 2016, 55, 6506-6510.
Phosphoric Acid Catalyzed Asymmetric 1,6-Conjugate Addition of Thioacetic Acid to para-Quinone Methides, N. Dong, Z.-P. Zhang, X.-S. Xue, X. Li, J.-P. Cheng, Angew. Chem. Int. Ed. 2016, 55, 1460-1464.
Weakly Polar Aprotic Ionic Liquids Acting as Strong Dissociating Solvent: A Typical “Ionic Liquid Effect” Revealed by Accurate Measurement of Absolute pKa of Ylide Precursor Salts. Mao, C.; Wang, Z.-D.; Wang, Z.; Ji, P.; Cheng, J.-P. J. Am. Chem. Soc. 2016, 138, 5523-5526.
Mechanism and Selectivity of Bioinspired Cinchona Alkaloid Derivatives Catalyzed Asymmetric Olefin Isomerization: A Computational Study, X.-S. Xue, X. Li, A. Yu, C. Yang, C. Song, J. P. Cheng, J. Am. Chem. Soc. 2013, 135, 7462-7473.
Asymmetric Supramolecular Primary Amine Catalysis in Aqueous Buffer: Connections of Selective Recognition and Asymmetric Catalysis,?S. S. Hu, J. Y. Li, J. F. Xiang, J. Pan, S. Z. Luo, J. –P. Cheng, J. Am. Chem. Soc. 2010, 20, 7216–7228.
Hydride, Hydrogen Atom, Proton, and Electron Transfer Driving Forces of Various Five-Membered Heterocyclic Organic Hydrides and Their Reaction Intermediates in Acetonitrile, X. Q. Zhu, M. T. Zhang, A. Yu, C. H. Wang, J. –P. Cheng,?J. Am. Chem. Soc., 2008, 130, 2501–2516.
A simple primary-tertiary Diamine-Bronsted acid catalyst for asymmetric direct aldol reactions of linear aliphatic ketones,?S. Z. Luo, H. Xu, J. Y. Li, L. Zhang, J. –P. Cheng, , J. Am. Chem. Soc. 2007, 129, 3074-3075.
A facile experimental method to determine the hydride affinity of polarized olefins in acetonitrile,?X. Q. Zhu, M. Zhang, Q. Y. Liu, X. X. Wang, J. Y. Zhang, J. –P. Cheng, Angew. Chem. Int. Ed. 2006, 45, 3954-3957.
Functionalized chiral ionic liquids as highly efficient asymmetric organocatalysts for michael addition to nitroolefins,?S. Z. Luo, X. L. Mi, L. Zhang, S. Liu, H. Xu, J. –P. Cheng, Angew. Chem. Int. Ed. 2006, 45, 3093-3097.
Determination of N-NO bond dissociation energies of N-methyl-N-nitrosobenzenesulfonamides in acetonitrile and application in the mechanism analyses on NO transfer,?X. Q. Zhu, W. F. Hao, H. Tang, C. H. Wang, J. –P. Cheng, J. Am. Chem. Soc. 2005, 127, 2696-2708.
First estimation of C4-H bond dissociation energies of NADH and its radical cation in aqueous solution,?X. Q. Zhu, Y. Yang, M. Zhang, J. –P. Cheng, J. Am. Chem. Soc. 2003, 125, 15298-15299.
Dissociation energies and charge distribution of CO-NO bond for nitrosyl-alpha, beta, gamma, deta-tetraphenylporphinatocobalt (II) and nitrosyl-alpha, beta, gamma, deta-tetraphenylporphinatocobalt (III) in benzonitrile solution,?X. Q. Zhu, Q. Li, W. F. Hao, J. -P. Cheng, J. Am. Chem. Soc. 2002, 124, 9887-9893.
NO affinities of S-nitrosothiols: A direct experimental and computational investigation of RS-NO bond dissociation energies,?J. Lu, K. Wang, J. M. Wittbrodt, Z. Wen, H. B. Schlegel, P. G. Wang, J. –P. Cheng, J. Am. Chem. Soc. 2001, 123, 2903-2904.
Homolytic cleavage energies of R-H bonds centered on carbon atoms of high electronegativity: the first general observations of O-type variation on C-H BDEs and its implication for the governing factors leading to the distinct O/S Patterns of radical subst,?J. –P. Cheng, B. Liu, Y. Zhao, Z. Wen, Y. Sun, J. Am. Chem. Soc. 2000, 122, 9987-9992.
