北京理工大学化学与化工学院赵伟

xiuxing

赵伟，北京理工大学化学与化工学院特别研究员。2016年博士毕业于中国科学院大学化学研究所，随后在美国印第安纳大学化学系Amar Flood课题组从事博士后研究。2020年7月加入北京理工大学化学与化工学院，主持国家自然科学基金青年项目、北京市自然科学基金面上项目和北京理工大学青年教师学术启动计划，研究兴趣侧重于新型阴离子配体的设计、合成、客体识别与分离等。

姓 名 赵 伟
职 称 特别研究员（博士生导师）
学术兼职 无
电子邮件 zhaochem@bit.edu.cn
系/研究所 无机化学研究所
网站 https://www.x-mol.com/groups/wu_biao
https://orcid.org/0000-0001-8941-3044
教育背景
2011.09-2016.07 中国科学院大学化学研究所，有机化学专业，理学博士
2007.09-2011.07 东北林业大学，化学专业，化学学士
工作履历
2020.07 至今 北京理工大学化学与化工学院，特别研究员，博士生导师
2016.11-2020.01 美国印第安纳大学博士后，合作导师 Prof. Amar Flood
研究方向
1 新型阴离子配体的设计与合成
2 超分子体系的精确构筑，包括高级自组装与超分子聚合物的制备
3 新型多功能超分子自适应材料的设计与制备
荣誉奖励
1 Student Travel Award, RE3 Workshop, 美国路易维尔 (2017)
2Outstanding Poster Award, The 5th Notre Dame-Purdue Symposium on SoftMatter & Polymers, 美国圣母大学 (2018)
3Best Oral Presentation Award, 6th Annual Symposium on Materials Research,美国印第安纳大学 (2019)
承担项目
1国家自然科学基金青年科学基金项目，磷酸根离子选择性配位脲基分子笼的设计与合成 (22101024)，2022.1–2024.12，30 万，主持
2北京市自然科学基金面上项目，新型多脲大环分子的设计合成及硫酸根离子配位研究（2222025），2022.1–2024.12，20 万，主持
3 北京理工大学青年教师学术启动计划，2020.7–2023.12，60 万，主持
4美国自然科学基金 SBIR 附属项目，Birght and Lightfast Fluorescent Pigments for Paints, Polymers, and Inks，6.8 万美元，主持，已结题
研究兴趣
主要研究方向为阴离子配位化学及应用，以阴离子化学为核心，探索“分子设计”、“组装结构”和“材料性质”三者相互关系，以期通过分子层面的微观调控实现对合成或组装材料宏观性质的预测与精确控制。在国内外学术刊物上发表学术论文 30 余篇，包括 Chem. Soc. Rev., Science, Chem, J. Am. Chem. Soc.,Angew. Chem. Int. Ed., Chem. Sci., CCS Chem.等。


发表论文
28 Chen, S.-Q.; Zhao, W.*; Wu, B. Separation of Sulfate Anion from Aqueous
Solution Governed by Recognition Chemistry: A Minireview. Front. Chem.
2022, online
27 Li, H.‡
; Kou, L.‡
; Liang, L.; Li, B.; Zhao, W.*; Yang, X.-J.; Wu, B.* AnionCoordination-Driven Single-Double Helix Switching and Chiroptical
Molecular Switch based on Oligoureas. Chem. Sci. 2022, 13, online
26 Yan, L.‡
; Saha, A.‡
; Zhao, W.‡
; Neal, J. F.; Chen, Y.; Flood, A. H.*; Allen, H.
C.* Recognition competes with hydration in anion-triggered monolayer
formation of cyanostar supra-amphiphiles at aqueous interfaces. Chem. Sci.,
2022, 13, 4283-4294.
3
25 Wang, Y.; Li, B.; Zhu, J.; Zhang, W.; Zheng, B.; Zhao, W., Tang, J.; Yang, X.-
J.; Wu, B.* Light-Triggered High-Affinity Binging of Tetramethylammonium
over Potassium Ion by [18]crown ether in a Tetrahedral Anion Cage. Angew.
Chem. Int. Ed., 2022, 61, e202201789.
24 Zhao, X.; Wang, H.; Li, B.; Zhang, W; Li,
X.; Zhao, W.; Janiak, C.; Heard, A. W.;
Yang, X.-J.; Wu, B.* A Hydrogen-Bonded
Ravel Assembled by Anion Coordination.
Angew. Chem. Int. Ed., 2022, 61,
e202115042.
23 Zhang, W.; Feng, Y.; Li, B.; Yang, D.; Hou, L.; Zhao, W.; Yang, X.-J.; Wu,
B.* Acid-Tolerant Sulfate Tetrahedral Cages from Anion-CoordinationDriven Assembly. Chem. Eur. J. 2022, 28, e202103671.
4
22 Zhao, G.; Chen, S.-Q.; Zhao, W.*; Li, B.;
Zhang, W.; Zheng, B., Yang, X.-J.; Wu, B.*
Modular Synthesis of Tetraurea and
Octaurea Macrocycles Encoded with
Specific Monomer Sequences. CCS Chem.
2021, 3, 2692–2701.
21 Zhu, D.; Jiang, S.; Zhao, W.; Yan, X.; Xie, W.; Xiong, Y.; Wang, S.; Cai, W.;
Gao, Y.; Ren A. A novel ratiometric fluorescent probe for sensitive and
selective detection of Cu2+ based on Boranil derivatives. Inorganica Chimica
Acta 2021, 524, 120438.
20 Fadler, R. E.; Al Ouahabi, A.; Qiao, B.; Carta, V.; König, N. F.; Gao, X.; Zhao,
W.; Zhang, Y.; Lutz, J.-F.; Flood, A. H., Chain Entropy Beats Hydrogen
Bonds to Unfold and Thread Dialcohol Phosphates inside Cyanostar
Macrocycles to form [3]Pseudorotaxanes. J. Org. Chem. 2021, 86, 4532–
4546.
19 Zhao, W.; Flood, A. H.; White, N. G. Recognition and applications of anion–
anion dimers based on anti-electrostatic hydrogen bonds (AEHBs). Chem.
Soc. Rev. 2020, 49, 7893–7906.
18 Neal, J. F.; Saha, A.; Zerkle, M.; Zhao, W.; Rogers, M.;
Flood, A. H.; Allen, H. C., Molecular recognition and
hydration energy mismatch combine to inform ion
binding selectivity at aqueous interfaces, J. Phys.
Chem. A 2020, 124, 10171–10180.
5
17 Benson, C. R.; Kacenauskaite, L.; VanDenburgh, K. L.; Zhao,
W.; Qiao, B.; Sadhukhan, T.; Pink, M. Chen, J.; Borgi, S.;
Chen, C. H.; Davis, B. J.; Simon, Y. C.; Raghavachari, K.;
Laursen, B. W.; Flood, A. H. Plug-and-play Optical Materials
from Fluorescent Dyes and Macrocycles. Chem 2020, 6,
1978–1997. (cover)
16 Grooms, A. J.; Neal, J. F.; Ng, K. C.; Zhao, W.; Flood, A. H.;
Allen, H. C. Thermodynamic Signatures of the Origin of AntiHofmeister Selectivity for Phosphate at Aqueous Interfaces. J.
Phys. Chem. A 2020, 124, 5621–5630. (cover)
15 Zhao, W.; Tropp, J.; Qiao, B.; Pink, M.; Azoulay, J. D.; Flood, A. H. Tunable
Adhesion from Stoichiometry-controlled and Sequence-defined
Supramolecular Polymers Emerges Hierarchically from Cyanostar-stabilized
Anion-anion Linkages. J. Am. Chem. Soc. 2020, 142, 2579-2591. Highlighted
in JACS spotlights: Supramolecular polymers stick it with stoichiometry, J.
Am. Chem. Soc. 2020, 142, 3275.
14 Liu, Y.; Zhao, W.; Chen, C. H.; Flood, A. H. Chloride Capture
using a C–H Hydrogen-bonding Cage. Science, 2019, 365,
159–161.
13 Zhao, W.; Qiao, B.; Tropp, J.; Pink, M.; Azoulay, J. D.; Flood,
A. H. Linear Supramolecular Polymers Driven by AnionAnion Dimerization of Difunctional Phosphonate Monomers
inside Cyanostar Macrocycles. J. Am. Chem. Soc. 2019, 141,
4980–4989. (cover)
12 Neal, J. F.; Zhao, W.; Grooms, A. J.; Smeltzer, M. A.; Shook, B. M.; Flood,
A. H.; Allen, H. C. Interfacial Supramolecular Structures of Amphiphilic
Receptors Drive Phosphate Recognition. J. Am. Chem. Soc. 2019, 141, 7876–
7886.
11 Liu Y.; Parks, F. C.; Zhao, W.; Flood, A. H. Sequence-controlled StimuliResponsive Single-Double Helix Conversion between 1:1 and 2:2 ChlorideFoldamer Complexes. J. Am. Chem. Soc, 2018, 140, 15477–15486.
10 Qiao, B.; Leverick, G.; Zhao, W.; Johnson, J.; Flood, A. H.;
Shao-Horn, Y. Supramolecular Regulation of Anions
Enhances Conductivity and Transference Number of Lithium
in Liquid Electrolytes. J. Am. Chem. Soc, 2018, 140, 10932–
10936. (cover)
6
9 Neal, K.; Zhao, W.; Grooms, A.; Flood, A. H.; Allen, H. C.
Arginine-phosphate Recognition Enhanced in Phospholipid
Monolayers at Aqueous Interfaces. J. Phys. Chem. C 2018,
122, 26362–26371. (cover)
8 Zhao, W.†
; Qiao, B.†
; Chen, C. H.; Flood, A. H. HighFidelity Multistate Switching with Anion-Anion and AcidAnion Dimers of Organophosphates in Cyanostar
Complexes. Angew. Chem. Int. Ed. 2017, 56, 13083–13087.
7 Yang, L.; Zhao, W.; Che, Y.; Wang, Y.; Jiang, H. Influence of Terminal
Substituents on the Halide Anion Binding of Foldamer-based Receptors.
Chin. Chem. Lett. 2017, 28, 1659–1662.
6 Zhao, W.; Huang, F.; Wang, Y.; Li, Q.; Shang, J.; Che, Y.; Jiang, H. Aryltriazole Foldamers with Ethynyl Spacers as Effective Receptors for Halides
and Oxyanions. Tetrahedron Lett. 2016, 57, 1691–1694.
5 Huang, F.; Zhao, W.; Che, Y.; Jiang, H. Review and Prospect of Molecular
Machines: Introduction to Nobel Prize in Chemistry 2016. Chin. J. Chem.
Edu. 2016, 37(22), 1–5.
4 Wang, Y.; Zhao, W.; Bie, F.; Wu, L.; Li, X.; Jiang, H. Ruthenium(II)
Complexes of Aryl-triazole Foldamers as Receptors for Anions. Chem. Eur.
J. 2016, 22, 5233–5242.
3 Shang, J.†
; Zhao, W.†
; Li, X.; Wang, Y.; Jiang, H. Aryl-triazole Foldamers
Incorporating Pyridinium Motif for Halide Anions Binding in Aqueous
Media. Chem. Commun. 2016, 52, 4505–4508.
2 Zhao, W.; Wang, Y.; Shang, J.; Che, Y.; Jiang, H. Acid/Base-Mediated Uptake
and Release of Halide Anions with a Preorganized Aryl-triazole Foldamer.
Chem. Eur. J. 2015, 21, 7731–7735.
1 Shang, J.; Si, W.; Zhao, W.; Che, Y.; Hou, J.; Jiang, H. Preorganized Aryltriazole Foldamers as Effective Transmembrane Transporters for Chloride
Anion. Org. Lett. 2014, 16, 4008−4011.