电子科技大学材料与能源学院周爱军

sanjiyou

周爱军，男，电子科技大学材料与能源学院 副教授。2004年获浙江大学学士学位，2010年获浙江大学工学博士学位，其中2007.10-2009.09年获国家公派及德意志学术交流中心（DAAD）资助于德国航空航天研究中心（DLR）材料研究所进行博士联合培养。曾获曾宪梓教育基金会全国优秀大学生、浙江大学优秀毕业生等荣誉称号。2010.04加入电子科技大学，2013.07-2014.07为香港中文大学（CUHK）机械与自动化工程系访问学者，2017.09-2018.09为美国得克萨斯州大学奥斯汀分校（UT Austin）机械工程系访问学者（合作导师：John B. Goodenough教授）。研究方向包括锂/钠/钾离子电池，薄膜材料及薄膜锂离子电池，热电材料及器件等。先后承担国家自然科学基金、四川省国际合作项目、中国博士后基金、中央高校业务费项目等多个科研项目。在Adv. Energy Mater.、Small、J. Mater. Chem. A、ACS Appl. Mater. Interfaces、J. Power Sources等国际权威期刊发表SCI论文50余篇，申请发明专利13项，授权专利3项，多次在国内外大型学术会议上做学术报告，长期担任多个SCI学术期刊审稿人。


周爱军   博士
办公电话:
邮  箱: zhouaj@uestc.edu.cn
办公地点:沙河校区三系楼343
个人主页：http://faculty.uestc.edu.cn/zhouaijun/zh_CN/index.htm


科研领域
锂离子电池及新型二次电池材料
1）高压钴酸锂、三元材料锂离子电池极材料的界面特性
2）薄膜型和全固态锂离子电池、金属锂负极
3）钠离子电池和钾离子电池正极材料
4）水系储能电池


热电材料与器件
1）硅化物、碲化物、锑化物及氧化物体系热电材料
2）薄膜热电材料的制备及热电性能表征
3）基于物联网和建筑一体化应用的热电器件和储电系统的开发


学术成果
[1] A. Zhou*, W. Cheng, W. Wang, Q. Zhao, J. Xie*, W. Zhang*, H. Gao, L. Xue, J. Li, Hexacyanoferrate-type Prussian blue analogs: Principles and advances toward high-performance sodium and potassium ion batteries, Advanced Energy Materials, 2020, accepted,
[2] A. Zhou, Z. Xu, H. Gao, L. Xue, J. Li, J.B. Goodenough*, Size-, Water-, and Defect-Regulated Potassium Manganese Hexacyanoferrate with Superior Cycling Stability and Rate Capability for Low-Cost Sodium-Ion Batteries, Small, 2019, 1902420.
[3] X. Yao, Z. Xu, Z. Yao, W. Cheng, H. Gao, Q. Zhao, J. Li, A. Zhou*, Oxalate co-precipitation synthesis of LiNi0.6Co0.2Mn0.2O2 for low-cost and high-energy lithium-ion batteries, Materials Today Communications, 2019, 19, 262-270.
[4] C. Li, J. Xue, A. Huang, J. Ma, F. Qing, A. Zhou, Z. Wang, Y. Wang, J. Li*, Poly(N-vinylcarbazole) as an advanced organic cathode for potassiumion-based dual-ion battery, Electrochimica Acta, 2019, 297, 850-855.
[5] L. Xue, W. Zhou, S. Xin, H. Gao, Y. Li, A. Zhou, J.B. Goodenough*, Room-Temperature Liquid Na-K Anode Membranes, Angewandte Chemie-International Edition, 2018, 57, 14184-14187.
[6] H. Xu, Y. Li, A. Zhou, N. Wu, S. Xin, Z. Li, J.B. Goodenough*, Li3N-Modified Garnet Electrolyte for All-Solid-State Lithium Metal Batteries Operated at 40 degrees C, Nano Letters, 2018, 18, 7414-7418.
[7] A. Zhou*, W. Wang, Q. Liu, Y. Wang, X. Yao, F. Qing, E. Li, T. Yang, L. Zhang, J. Li*, Stable, fast and high-energy-density LiCoO2 cathode at high operation voltage enabled by glassy B2O3 modification, Journal of Power Sources, 2017, 362, 131-139.
[8] A.J. Zhou, Q. Liu, Y. Wang, W.H. Wang, X. Yao, W.T. Hu, L. Zhang, X.Q. Yu*, J.Z. Li*, H. Li, Al2O3 surface coating on LiCoO2 through a facile and scalable wet-chemical method towards high-energy cathode materials withstanding high cutoff voltages, Journal of Materials Chemistry A, 2017, 5, 24361-24370.
[9] A. Zhou, Y. Lu, Q. Wang, J. Xu, W. Wang, X. Dai, J. Li*, Sputtering TiO2 on LiCoO2 composite electrodes as a simple and effective coating to enhance high-voltage cathode performance, Journal of Power Sources, 2017, 346, 24-30.
[10] A. Zhou*, B. Yang, W. Wang, X. Dai, M. Zhao, J. Xue, M. Han, C. Fan, J. Li*, Enhanced reversibility and electrochemical performances of mechanically alloyed Cu3P achieved by Fe addition, RSC Advances, 2016, 6, 26800-26808.
[11] A. Zhou*, J. Xu, X. Dai, B. Yang, Y. Lu, L. Wang, C. Fan, J. Li*, Improved high-voltage and high-temperature electrochemical performances of LiCoO2 cathode by electrode sputter-coating with Li3PO4, Journal of Power Sources, 2016, 322, 10-16.
[12] A. Zhou*, W. Wang, X. Yao, B. Yang, J. Li, Q. Zhao, C. Wang, D. Xu, P. Ziolkowski*, E. Mueller, Impact of the film thickness and substrate on the thermopower measurement of thermoelectric films by the potential-Seebeck microprobe (PSM), Applied Thermal Engineering, 2016, 107, 552-559.
[13] A. Zhou*, W. Wang, B. Yang, J. Li, Q. Zhao, Thermal conductivity study of micrometer-thick thermoelectric films by using three-omega methods, Applied Thermal Engineering, 2016, 98, 683-689.
[14] A. Zhou, X. Dai*, Y. Lu, Q. Wang, M. Fu, J. Li*, Enhanced interfacial kinetics and high-voltage/high-rate performance of LiCoO2 cathode by controlled sputter-coating with a nanoscale Li4Ti5O12 ionic conductor, ACS Applied Materials & Interfaces, 2016, 8, 34123-34131.
[15] J. Xue, C. Fan*, L. Wang, A. Zhou, J. Li*, Silver-mediated calcium terephthalate with enhanced electronic conductivity as an organic anode for efficient Li-ion batteries, Rsc Advances, 2016, 6, 29404-29409.
[16] J. Xue, C. Fan*, Q. Deng, M. Zhao, L. Wang, A. Zhou, J. Li*, Silver Terephthalate (Ag2C8H4O4) Offering in-situ Formed Metal/Organic Nanocomposite as the Highly Efficient Organic Anode in Li-ion and Na-ion Batteries, Electrochimica Acta, 2016, 219, 418-424.
[17] W. Jia, C. Fan*, L. Wang, Q. Wang, M. Zhao, A. Zhou, J. Li*, Extremely Accessible Potassium Nitrate (KNO3) as the Highly Efficient Electrolyte Additive in Lithium Battery, ACS Applied Materials & Interfaces, 2016, 8, 15399-15405.
[18] Q. Deng, J. Xue, W. Zou, L. Wang, A. Zhou, J. Li*, The electrochemical behaviors of Li2C8H4O6 and its corresponding organic acid C8H6O6 as anodes for Li-ion batteries, Journal of Electroanalytical Chemistry, 2016, 761, 74-79.
[19] X. Dai, A. Zhou*, J. Xu, Y. Lu, L. Wang, C. Fan, J. Li*, Extending the high-voltage capacity of LiCoO2 cathode by direct coating of the composite electrode with Li2CO3 via magnetron sputtering, The Journal of Physical Chemistry C, 2016, 120, 422-430.
[20] A. Zhou, Q. Fu, W. Zhang, B. Yang, J. Li, P. Ziolkowski, E. Mueller, D. Xu*, Enhancing the Thermoelectric Properties of the Electroplated Bi2Te3 Films by Tuning the Pulse Off-to-on Ratio, Electrochimica Acta, 2015, 178, 217-224.
[21] J. Xue, L. Wang, A. Zhou, J. Li, D.E.P. Inc, Improved Electrochemical Performance of Li2C8H4O4/Graphene Composites as Anode Materials for Li-ion Batteries, 2015 2nd International Conference on Intelligent Materials and Mechatronics (Imm 2015), 2015, 148-151.
[22] X. Dai, A. Zhou*, J. Xu, B. Yang, L. Wang, J. Li*, Superior Electrochemical Performance of LiCoO2 Electrodes Enabled by Conductive Al2O3-doped ZnO Coating via Magnetron Sputtering, Journal of Power Sources, 2015, 228, 114-122.
[23] H.Q. Zhang, Q.J. Deng, A.J. Zhou, X.Q. Liu, J.Z. Li*, Porous Li2C8H4O4 coated with N-doped carbon by using CVD as an anode material for Li-ion batteries, Journal of Materials Chemistry A, 2014, 2, 5696-5702.
[24] Y. Wang, W. Zou, X.Y. Dai, L.D. Feng, H.Q. Zhang, A.J. Zhou, J.Z. Li*, Solid-state synthesis of graphite carbon-coated Li4Ti5O12 anode for lithium ion batteries, Ionics, 2014, 20, 1377-1383.
[25] Y. Wang, A.J. Zhou, X.Y. Dai, L.D. Feng, J.W. Li, J.Z. Li*, Solid-state synthesis of submicron-sized Li4Ti5O12/Li2TiO3 composites with rich grain boundaries for lithium ion batteries, Journal of Power Sources, 2014, 266, 114-120.
[26] Y. Wang, A. Zhou, X. Dai, L. Feng, X. Xu, J. Du, J. Li*, A Review of Selenization of Metal Precursors for the Deposition of CIGS Thin Film (in Chinese), Rare Metal Materials & Engnineering, 2014, 43, 506-512.
[27] L.P. Wang, H.Q. Zhang, Q.J. Deng, Z.L. Huang, A.J. Zhou, J.Z. Li*, Superior rate performance of Li4Ti5O12/TiO2/C/CNTs composites viamicroemulsion-assisted method as anodes for lithium ion battery, Electrochimica Acta, 2014, 142, 202-207.
[28] Z. W., J.W. Li, Q.J. Deng, J. Xue, X.Y. Dai, A.J. Zhou, J.Z. Li*, Microspherical Na2Ti3O7 prepared by spray-drying method as anode material for sodium-ion battery, Solid State Ionics, 2014, 262,
[29] X.Y. Dai, A.J. Zhou*, L.D. Feng, Y. Wang, J. Xu, J.Z. Li*, Molybdenum thin films with low resistivity and superior adhesion deposited by radio-frequency magnetron sputtering at elevated temperature, Thin Solid Films, 2014, 567, 64-71.
[30] X.Y. Dai, L.P. Wang*, J. Xu, Y. Wang, A.J. Zhou, J.Z. Li*, Improved Electrochemical Performance of LiCoO2 Electrodes with ZnO Coating by Radio-Frequency Magnetron Sputtering, ACS Applied Materials & Interfaces, 2014, 6, 15853-15859.
[31] A.J. Zhou*, L.D. Feng, W. Liu, X.Y. Dai, H.G. Cui, X.B. Zhao, J.Z. Li, Sequential Evaporation and Thermoelectric Transport Properties of Bi-Te Thin Films with Controllable Composition Journal of Electronic Materials, 2013, 42, 2184-2191.
[32] A. Zhou*, L. Feng, W. Liu, X. Dai, H. Cui, X. Zhao, J. Li, Performance evaluation of a silicide-based thermoelectric generator for power generation, Materials Science Forum, 2013, 743-744, 144-152.
[33] H. Zhang, Q. Deng, C. Mou, Z. Huang, Y. Wang, A. Zhou, J. Li*, Surface Structure and High-Rate Performance of Spinel Li4Ti5O12 Coated with N-Doped Carbon as Anode Material for Lithium-Ion Batteries, Journal of Power Sources, 2013, 239, 538-545.
[34] J. Li, A. Zhou, X. Liu, J. Li*, Si Nanowire Anode Prepared by Chemical Etching for High Energy Density Lithium-ion Battery (in Chinese), Journal of Inorganic Materials, 2013, 28, 1207-1212.
[35] W. Zou, X. Cai, J. Li, X. Dai, H. Zhang, A. Zhou, J. Li*, L. Song, T. Iyoda, Selective deposition on block copolymer film by thermal evaporation of silver, Surface & Coatings Technology, 2012, 206, 4634-4638.
[36] A.J. Zhou, D. Mei, X.G. Kong, X.H. Xu, L.D. Feng, X.Y. Dai, T. Gao, J.Z. Li*, One-step synthesis of Cu(In,Ga)Se-2 absorber layers by magnetron sputtering from a single quaternary target, Thin Solid Films, 2012, 520, 6068-6074.
[37] W. Zou, Y. Wang, Z. Wang, A. Zhou, J. Li*, A. Chang, Q. Wang, M. Komura, K. Ito, T. Iyoda, Solvent induced formation of an ordered nanorod array of gold/polymer composite by block copolymer film templating, Nanotechnology, 2011, 22, 335301.
[38] A.-J. Zhou*, H.-G. Cui, J.-Z. Li, X.-B. Zhao, Structure and Morphology of Induction-Melted Higher Manganese Silicide (in Chinese), Acta Physico-Chimica Sinica, 2011, 27, 2915-2919.
[39] A. Zhou, T. Zhu, X. Zhao*, E. Mueller, Grain size effect on the phase transformations of higher manganese silicide thermoelectric materials: An in situ energy dispersive x-ray diffraction study, Journal of Materials Research, 2011, 26, 1900-1906.
[40] W. Huo, J. Li*, G. Chen, Y. Wang, W. Zou, Q. Rao, A. Zhou, A. Chang, Q. Wang, LiCoO2 thin film cathode fabricated by pulsed laser deposition, Rare Metals, 2011, 30, 106-110.
[41] T. Dasgupta, C. Stiewe, R. Hassdorf, A.J. Zhou, L. Boettcher, E. Mueller*, Effect of vacancies on the thermoelectric properties of Mg2Si1-xSbx (0 < ="x" <="0.1)," Physical Review B, 2011, 83,
[42] T.J. Zhu, K. Xiao, C. Yu, J.J. Shen, S.H. Yang, A.J. Zhou, X.B. Zhao*, J. He, Effects of yttrium doping on the thermoelectric properties of Hf(0.6)Zr(0.4)NiSn(0.98)Sb(0.02) half-Heusler alloys, Journal of Applied Physics, 2010, 108,
[43] A.J. Zhou, T.J. Zhu, X.B. Zhao*, S.H. Yang, T. Dasgupta, C. Stiewe, R. Hassdorf, E. Mueller, Improved Thermoelectric Performance of Higher Manganese Silicides with Ge Additions, Journal of Electronic Materials, 2010, 39, 2002-2007.
[44] A.J. Zhou, X.B. Zhao*, T.J. Zhu, S.H. Yang, T. Dasgupta, C. Stiewe, R. Hassdorf, E. Mueller, Microstructure and thermoelectric properties of SiGe-added higher manganese silicides, Materials Chemistry and Physics, 2010, 124, 1001-1005.
[45] A.J. Zhou, X.B. Zhao*, T.J. Zhu, T. Dasgupta, C. Stiewe, R. Hassdorf, E. Mueller, Mechanochemical decomposition of higher manganese suicides in the ball milling process, Intermetallics, 2010, 18, 2051-2056.
[46] A.J. Zhou, X.B. Zhao, T.J. Zhu, Y.Q. Cao, C. Stiewe, R. Hassdorf, E. Mueller, Composites of Higher Manganese Silicides and Nanostructured Secondary Phases and Their Thermoelectric Properties, Journal of Electronic Materials, 2009, 38, 1072-1077.
[47] A.J. Zhou, T.J. Zhu, X.B. Zhao*, H.Y. Chen, E. Mueller, Fabrication and thermoelectric properties of perovskite-type oxide La1-xSrxCoO3 (x=0, 0.1), Journal of Alloys and Compounds, 2008, 449, 105-108.
[48] A.J. Zhou, T.J. Zhu, X.B. Zhao*, Thermoelectric properties of perovskite oxides La(1-x)Sr(x)CoO(3) prepared by polymerlized complex method, Journal of Materials Science, 2008, 43, 1520-1524.
[49] A.J. Zhou, T.J. Zhu, H.L. Ni, Q. Zhang, X.B. Zhao*, Preparation and transport properties of CeSi2/HMS thermoelectric composites, Journal of Alloys and Compounds, 2008, 455, 255-258.
[50] Q. Zhang, T.J. Zhu, A.J. Zhou, H. Yin, X.B. Zhao*, Preparation and thermoelectric properties of Mg(2)Si(1-x)Sn(x), Physica Scripta, 2007, T129, 123-126.
[51] J.Z. Hu, X.B. Zhao*, T.J. Zhu, A.J. Zhou, Synthesis and transport properties of Bi2Te3 nanocomposites, Physica Scripta, 2007, T129, 120-122.
[52] A.J. Zhou, T.J. Zhu, X.B. Zhao*, Thermoelectric properties of perovskite-type oxide La1-xSrxCoO3 (x=0, 0.1) prepared by solid state reactions, Materials Science and Engineering B-Solid State Materials for Advanced Technology, 2006, 128, 174-178.

sanjiyou

材料与能源学院周爱军副教授受邀在能源材料领域国际顶级期刊《先进能源材料》（Advanced Energy Materials, IF=24.884）在线发表题为“Hexacyanoferrate‐Type Prussian Blue Analogs: Principles and Advances Toward High‐Performance Sodium and Potassium Ion Batteries”（六铁氰化物型普鲁士蓝类材料在高性能钠离子及钾离子电池中的应用原理和进展）的综述论文。周爱军副教授为论文第一作者兼通讯作者。浙江大学材料科学与工程学院谢健副教授、华中科技大学材料科学与工程学院张五星副教授为论文的共同通讯作者，材料与能源学院李晶泽教授、赵强副教授、硕士研究生程威杰、王伟以及美国得州大学奥斯汀分校高洪才博士和薛雷刚博士为共同作者，材料与能源学院为第一通讯单位。
近年来，钠离子电池（NIBs）和钾离子电池（KIBs）因原料丰富、成本低廉且具有较为可观的能量/功率密度而成为了电储能领域的研究热点。在众多电极材料体系中，普鲁士蓝类材料（PBAs）拥有刚性和开放的框架结构和较大尺寸的间隙通道（> 3.5 Å），并具有原料易得、结构组成多样、合成温度低、易规模化等综合优势。其中，基于Fe(CN)6的六铁氰化物（HCFs）在钠/钾离子电池中表现出较高的氧化还原电位（2.5–3.8 V）和比容量（70–170 mAh g-1），是普鲁士蓝类材料中研究最多的正极材料。但是，该材料的结构对称性和晶胞体积对碱金属/过渡金属种类、合成条件和碱金属离子脱嵌量等因素比较敏感，并且该框架结构中存在固有的Fe(CN)64-配位空位和亚稳态结晶水，其电极的循环稳定性和倍率性能必须进行优化以满足规模化电储能应用的要求。

该论文首先从“立方-单斜-菱方”的多相结构转变和过渡金属的多自旋态的角度，深入分析了六铁氰化物型普鲁士蓝类材料的结构特点和氧化还原机理，阐明了不同碱金属和过渡金属的六铁氰化物之间的差异性，然后从材料的结晶性调控、结晶水的物理和化学脱出、高比表面复杂形貌的构建、导电复合和表面修饰、过渡金属和碱金属元素取代等五个方面系统梳理和讨论了该材料体系的优化改性原理和近十年来取得的主要研究进展。最后，文章总结了六铁氰化物在空位缺陷、结晶水、结构变化和离子动力学方面的现存问题并对未来的研究进行了展望。
周爱军副教授所在的“先进能源材料与系统”实验室（李晶泽教授团队）长期开展新型电池材料的研究，包括锂/钠/钾离子二次电池电极材料，全固态薄膜锂离子电池、金属锂负极、聚合物电池等方向。团队自2007年成立以来获得国家及地方、国防及企业的多项资金支持，共发表SCI论文100余篇，培养博士和硕士研究生30余人，拥有多项授权专利。