复旦大学吴仁兵

canlan

吴仁兵，复旦大学材料科学系青年研究员，博士生导师，中组部青年##，Journal of Alloys and Compounds副主编（Editor）。2004年6月本科毕业于合肥工业大学化学工程与工艺专业，2009年6月博士毕业于浙江大学材料科学与工程专业。2011年至2015年在新加坡南洋理工大学机械与宇航学院从事博士后研究。研究方向集中于配位聚合物剪裁设计及其衍生的功能材料微观结构调控及能源环境应用。近几年来，在上述领域取得了一系列成果，在主流学术期刊发表70篇学术论文，发表的论文被引2000余次。其中以第一作者/通讯作者在Prog. Mater. Sci.，Adv. Mater.，ACS Nano，Adv. Funct. Mater.，Adv. Energy Mater.等期刊发表论文近50篇。第一/通讯作者发表的论文中有6篇属于ESI高被引论文。

吴仁兵

吴仁兵，青年研究员，博士生导师
复旦大学材料科学系材料二楼
上海市邯郸路220号，200433
E-mail：rbwu@fudan.edu.cn

教育与科研背景：
2000年~2004年，合肥工业大学 化学工程与工艺专业，本科
2004年~2009年，浙江大学 材料科学与工程专业，博士
2007年~2008年，美国犹他大学 材料科学与工程专业，国家公派联合培养
2011年12月~2015年11月，新加坡南洋理工大学 机械与宇航学院 博士后/研究员
2015年12月~至今，复旦大学 材料科学学系，青年研究员

主要研究方向：
1）碳化硅材料
2）电催化剂设计及锂/钠离子电池储能器件
3）电磁隐身材料

主持科研项目：
复旦大学引进人才启动经费
国家自然科学基金青年基金、面上基金
凝固技术国家重点实验室开放基金
耐火材料与冶金国家重点实验室开放基金

科研成果：
以第一/通讯作者在Prog. Mater. Sci.，Adv. Mater.，ACS Nano，Adv. Funct. Mater.等学术期刊发表论文39篇，第一作者发表的论文中有5篇属于ESI高被引论文。

备注：
欢迎材料、化学、物理等相关专业背景的学生报考本课题组硕士或博士研究生；欢迎相关研究领域的博士加盟本课题组进行博士后合作研究。

近年代表性论文
(1) H. B. Xu, B. Fei, G. H. Cai, Y. Ha, J. Liu, H. X. Jia, J. C. Zhang, M. Liu, and R. B. Wu*, “Boronization-Induced Ultrathin 2D Nanosheets with Abundant Crystalline-Amorphous Phase Boundary Supported on Nickel Foam Toward Efficient Water Splitting”, Advanced Energy Materials, 2019, (accepted).
(2) H. L. Lv, Z. H. Yang, H. B. Xu, and R. B. Wu*, “An Electrical Switch-Driven Flexible Electromagnetic Absorber”, Advanced Functional Materials, 2019, DOI: 10.1002/adfm.201907251.
(3) H. B. Xu, H. X. Jia, B. Fei, Y. Ha, H. Z. Li, Y. H. Guo, M. Liu and R. B. Wu*, “Charge Transfer Engineering via Multiple Heteroatoms Doping in Dual Carbon-Coupled Cobalt Phosphides for Highly Efficient Overall Water Splitting”, Applied Catalysis B: Environmental, 2019, DOI: 10.1016/j.apcatb.2019.118404.
(4) Z. L. Chen, H. L. Qing, K. Zhou*, D. L. Sun, and R. B. Wu*, “Metal-Organic Framework-Derived Nanocomposites for Electrocatalytic Hydrogen Evolution Reaction”, Progress in Materials Science, 2019, DOI: 10.1016/j.pmatsci.2019.100618.
(5) H. Y. Yang, Z. L. Chen, P. F. Guo, B. Fei, and R. B. Wu*, “B-Doping-Induced Amorphization of LDH for Large-Current-Density Hydrogen Evolution Reaction”, Applied Catalysis B: Environmental, 2020, 261, 118240.
(6) Y. Liu, Z. L. Chen, H. X. Jia, H. B. Xu, M. Liu, and R. B. Wu*, “Iron-Doping-Induced Phase Transformation in Dual Carbon Confined Cobalt Diselenide Enabling Superior Lithium Storage”, ACS Nano, 2019, 13, 6113–6124.
(7) H. Y. Yang, Z. L. Chen, W. J. Hao, H. B. Xu, Y. H. Guo, and R. B. Wu*, “Catalyzing Over Water Splitting at an Ultralow Cell Voltage of 1.42 V via Coupled Co-Doped NiO Nanosheets with Carbon”, Applied Catalysis B: Environmental, 2019, 252, 214–221.
(8) Y. Ha, L. X. Shi, Z. L. Chen, and R. B. Wu*, “Phase-transited Lysozyme-Driven Formation of Self-Supported Co3O4/C Nanomeshes for Overall Water Splitting”, Advanced Science, 2019, 6, 1900272.
(9) Z. L. Chen, Y. Ha, H. X. Jia, X. X. Yan, M. Liu, R. B. Wu*, “Oriented Transformation of Co-LDH into 2D/3D ZIF-67 to Achieve Co-N-C Hybrids for Efficient Overall Water Splitting”, Advanced Energy Materials, 2019, 9, 1803918.
(10) Z. L. Chen, H. B. Xu, Y. Ha, X. Y. Li, M. Liu, and R. B. Wu*, “Two-Dimensional Dual Carbon-coupled Defective Nickel Quantum Dots Towards Highly Efficient Overall Water Splitting”, Applied Catalysis B: Environmental, 2019, 250, 213–223.
(11) W. J. Hao, R. B. Wu*, H. Y. Yang, and Y. H. Guo*, “Photothermal Coupling Electrolysis on Ni-W-B Toward Practical Overall Water Splitting”, Journal of Materials Chemistry A, 2019, 7, 12440–12445.
(12) H. B. Xu, Y. Liu, Q. Y. Bai, and R. B. Wu*, “Discarded Cigarette Filters-Derived Hierarchically Porous Carbon@Graphene Composites for Lithium-Sulfur Batteries”, Journal of Materials Chemistry A, 2019, 7, 3558–3562.
(13) H. Wang, H. B. Xu, K. Jia, and R. B. Wu*, “ZIF-8-Templated Hollow Cube-Like Si/SiO2@C Nanocomposites for Superior Lithium Storage Performance”, ACS Applied Energy Materials, 2019, 2, 531–538.
(14) B. S. Li, R. R. Wang, Z. L. Chen, D. L. Sun, F. Fang* andR. B. Wu*, “Embedding Heterostructured MnS/Co1-xS Nanoparticles in Porous Carbon/Graphene for Superior Lithium Storage”, Journal of Materials Chemistry A, 2019, 7, 1260–1266.
(15) R. R. Wang, B. S. Li*, L. F. Lai andR. B. Wu*, “3D Urchin-Like Architectures Assembled by MnS Nanorods Encapsulated in N-Doped Carbon Tubes for Superior Lithium Storage”, Chemical Engineering Journal, 2019, 355, 752–759.
(16) Z. L. Chen, R. B. Wu*, Y. Liu, Y. Ha, Y. H. Guo, D. L. Sun*, M. Liu, and F. Fang*, “Ultrafine Co Nanoparticles Encapsulated in Carbon-Nanotubes-Grafted Graphene Sheets as Advanced Electrocatalysts for the Hydrogen Evolution Reaction”, Advanced Materials, 2018, 30, 1802011.
(17) W. J. Hao#, R. B. Wu#, R. Q. Zhang, Y. Ha, Z. L. Chen, L. C. Wang, Y. J. Yang, X. H. Ma, F. Fang and Y. H. Guo*, “Electroless Plating of Highly Efficient Bifunctional Boride-Based Electrodes Towards Practical Overall Water Splitting”, Advanced Energy Materials, 2018, 8, 1801372.
(18) Z. L. Chen, R. B. Wu*, M. Liu, Y. Liu, S. Y. Xu, Y. Ha, Y. H. Guo, X. B. Yu, D. L. Sun, and F. Fang*, “Tunable Electronic Coupling of Cobalt Sulfide/Carbon Composites for Optimizing Oxygen Evolution Reaction Activity”,Journal of Materials Chemistry A, 2018, 6, 10304–10312.
(19) Z. L. Chen, M. Liu, and R. B. Wu*, “Strongly Coupling of Co9S8/Zn-Co-S Heterostructures Rooted in Carbon Nanocages Towards Efficient Oxygen Evolution Reaction”, Journal of Catalysis, 2018, 361, 322–330.
(20) Z. L. Chen, Y. Ha, Y. Liu, H. Wang, H. Y. Yang, H. B. Xu, Y. J. Li, and R. B. Wu*, “In Situ Formation of Cobalt Nitrides/Graphitic Carbon Composites as Efficient Bifunctional Electrocatalysts for Overall Water Splitting”, ACS Applied Materials & Interfaces, 2018, 10, 7134–7144.
(21) H. L. Lv, S. S. Dai, H. J. Wu, G. B. Ji, Z. H. Yang*, and R. B. Wu*, “Doping Strategy to Boost the Electromagnetic Wave Attenuation ability of Hollow Carbon Spheres at Elevated Temperatures”, ACS Sustainable Chemistry & Engineering,2018, 6, 1539–1544.
(22) Z. L. Chen, R. B. Wu*, H. Wang, K. H. L. Zhang, Y. Song, F. L. Wu, F. Fang, and D. L. Sun*, “Embedding ZnSe Nanodots in Nitrogen-Doped Hollow Carbon Architectures for Superior Lithium Storage”, Nano Research, 2018,11, 966–978.
(23) H. Wang, Z. L. Chen, Y. Liu, H. B. Xu, L. C. Cao, H. L. Qing, and R. B. Wu*, “Hierarchically Porous-Structured ZnxCo1-xS@C-CNTs Nanocomposites with High-Rate Cycling Performance for Lithium-Ion Batteries”, Journal of Materials Chemistry A, 2017, 5, 23221 – 23227.
(24) Z. L. Chen, R. B. Wu*, M. Liu, H. Wang, Y. Song, F. Fang, X. B. Yu, and D. L. Sun*, “General Synthesis of Dual Carbon-confined Metal Sulfides Quantum Dots Towards High-Performance Anodes for Sodium-Ion Batteries”, Advanced Functional Materials, 2017, 27, 1702046.
(25) Z. L. Chen, R. B. Wu*, Y. K. Jiang, L. Jin, Y. H. Guo, Y. Song, F. Fang*, and D. L. Sun, “Construction of Hybrid Hollow Architectures by In-Situ Rooting Ultrafine ZnS Nanorods Within Porous Carbon Polyhedra for Enhanced Lithium Storage Properties”, Chemical Engineering Journal, 2017, 326, 680–690.
(26) Z. H. Yang*, H. L. Lv,andR. B. Wu*, Rational Constructing Graphene Oxide with MOFs-Derived Porous NiFe@C Nanocubes for High-Performance Microwave Attenuation, Nano Research, 2016, 9, 3671–3682.
(27) R. B. Wu*, Y. H. Xue, B. Liu, K. Zhou*, J. Wei, and S. H. Chan, “Cobalt Selenide Nanoparticles Embedded within Nitrogen-Doped Porous Carbon as Advanced Oxygen Reduction Reaction Electrocatalyst”,Journal of Power Sources, 2016, 330, 132–139.
(28) R. B. Wu, D. P. Wang, K. Zhou*, N. Srikanth, J. Wei, Z. Chen*, “Porous Cobalt Phosphide/Graphitic Carbon Polyhedra Hybrid Composites for Efficient Oxygen Evolution Reactions”, Journal of Materials Chemistry A, 2016, 4, 13742–13745.
(29) R. B. Wu, D. P. Wang, X. H. Rui, B. Liu, K. Zhou, A. W. K. Law, Q. Y. Yan, and Z. Chen, “In-situ Formation of Hollow Hybrids Composed of Cobalt Sulfides Embedded within Porous Carbon Polyhedra/Carbon Nanotubes for High-Performance Lithium-Ion Batteries”, Advanced Materials, 2015, 27, 3038–3044.
(30) R. B. Wu, K. Zhou, C. Y. Yue, J. Wei, and Y. Pan, “Recent Progress in Synthesis, Properties and Potential Applications of SiC nanomaterials”, Progress in Materials Science,2015, 72, 1–60.
(31) R. B. Wu, X. K. Qian, K. Zhou, J. Wei, J. Lou, and P. M. Ajayan, “Porous Spinel ZnxCo3-xO4 Hollow Polyhedra Templated for High-Rate Lithium-ion Batteries”, ACS Nano, 2014, 8, 6297–6303.
(32) R. B. Wu, X. K. Qian, X. H. Rui, H. Liu, B. Yadian, K. Zhou, J. Wei, Q. Y. Yan, X. Q. Feng, Y. Long, L. Y. Wang, and Y. Z. Huang, “Zeolitic Imidazolate Framework 67-Derived High Symmetric Porous Co3O4 Hollow Dodecahedra with Highly Enhanced Lithium Storage Capability”, Small, 2014, 10, 1932–1938.

canlan

2018自然科学基金面上项目-双碳限域的过渡金属单原子/团簇设计及电催化析氧反应性能研究
批准号        51871060        学科分类        ( E010505 )
负责人        吴仁兵        职称                单位名称        复旦大学
资助金额        60万元        项目类别        面上项目        起止年月        2019年01月01日 至 2022年12月31日

jinli

复旦大学吴仁兵研究员等将超薄钴层状双氢氧化物原位转化为2D钴沸石咪唑酯骨架(ZIF-67)纳米片，进而与碳布表面上的3D ZIF-67多面体接枝形成前驱体(2D/3D ZIF-67@CC)，并在Adv. Energy Mater.上发表了题为“Oriented Transformation of Co-LDH into 2D/3D ZIF-67 to Achieve Co-N-C Hybrids for Efficient Overall Water Splitting”的研究论文。在低温热解后，该前驱体可进一步转化为由嵌入2D 氮掺杂碳纳米片和3D 氮掺杂空心碳多面体中的超细钴纳米颗粒组成的复合材料(Co@N-CS/N-HCP@CC)。实验和密度泛函理论计算结果表明，上述复合材料具有活性位点丰富、电荷/质量传递能力良好、组分的协同效应以及最佳的水吸附能量变化等优势。在1.0 M KOH中，所得Co@N-CS/N-HCP@CC催化剂仅需66和248 mV的过电势，即可达到HER和OER的10mA·cm-2的电流密度。值得注意的是，上述催化剂能够在1.545 V的低电池电压下实现电流密度为10 mA·cm-2的碱性电解，优于IrO2@CC || Pt/C@CC (1.592 V)。

超薄钴层

综上所述，作者所制备的Co@N-CS/N-HCP@CC催化剂在碱性溶液中显示出优异的HER和OER活性，优于大多数先前报道的TMs@NC催化剂。此外，上述电催化剂能够在10 mA·cm-2的电流密度、电池电压低至1.545 V的情况下进行碱性全分解水。其优异的性能可归因于整合0D超细Co纳米粒子、1D交织碳纤维、2D 氮掺杂碳纳米片和3D 氮掺杂空心碳多面体的协同效应，从而产生丰富的活性表面积、坚固的形态/结构稳定性、增强的质量传递、加速的电荷转移以及更优的本征催化活性。文中所述的合成策略为开发其他金属-碳基功能材料提供了重要参考。

文献链接：Oriented Transformation of Co-LDH into 2D/3D ZIF-67 to Achieve Co–N–C Hybrids for Efficient Overall Water Splitting (Adv. Energy Mater., 2019, DOI: 10.1002/aenm.201803918)

mangan

2019年11月12日，由共青团中央、中国科协、教育部、中国社科院、全国学联和北京市政府主办的第十六届“挑战杯”全国大学生课外学术科技作品竞赛终审决赛在北京航空航天大学落下帷幕。来自全国300多所高校的5000名师生参加了本届“挑战杯”决赛。复旦大学材料科学系青年研究员吴仁兵老师指导本科生刘洋和徐鸿彬完成的参赛作品《基于掺杂诱导相转变设计高性能锂离子电池负极材料》荣获特等奖。
该作品针对金属硫族化合物导电性较差以及充放电过程中体积变化大等缺点，在前期纳米化和复合化方法的基础上，首次提出了掺杂诱导相转变的策略。实验和理论研究表明，掺杂电负性较弱的阳离子会实现从立方相到正交相二硒化钴的转变。掺杂的正交相二硒化钴相比于初始的立方相二硒化钴，展现出更高的容量和倍率性能。掺杂诱导相转变的策略还有望进一步应用在储钠以及电催化等其他能量存储与转换领域。
这是我系继2013年常煜博士及其团队获“第十三届全国大学生挑战杯”一等奖后，又一次在该赛事获得荣誉。材料科学系近年来不断探索工科人才培养的新机制与新举措，突出创新创业导向。在“三全育人”理念指引下，材料科学系教师积极指导学生参与专业技能、课外科创、创新创业等各类竞赛，在“互联网+”创新创业大赛、“创青春”全国大学生创业大赛、全国失效分析大赛、上海市新材料创新创意大赛等赛事中获得多项荣誉。